162 research outputs found
Vortex corrections to universal scaling of magnetic fluctuations in 2D XY model
The vortex contribution to the probability density function of longitudinal
magnetization fluctuations is examined in finite 2D XY systems close to the
Kosterlitz-Thouless-Berezinskii transition temperature. Within the temperature
range studied their relevance is limited to rare fluctuations, where they
increase the probability of events exceeding four standard deviations below the
mean magnetization.Comment: 6 pages, 4 figures. Refs adde
An electric-field representation of the harmonic XY model
The two-dimensional harmonic XY (HXY) model is a spin model in which the
classical spins interact via a piecewise parabolic potential. We argue that the
HXY model should be regarded as the canonical classical lattice spin model of
phase fluctuations in two-dimensional condensates, as it is the simplest model
that guarantees the modular symmetry of the experimental systems. Here we
formulate a lattice electric-field representation of the HXY model and contrast
this with an analogous representation of the Villain model and the
two-dimensional Coulomb gas with a purely rotational auxiliary field. We find
that the HXY model is a spin-model analogue of a lattice electric-field model
of the Coulomb gas with an auxiliary field, but with a temperature-dependent
vacuum (electric) permittivity that encodes the coupling of the spin vortices
to their background spin-wave medium. The spin vortices map to the Coulomb
charges, while the spin-wave fluctuations correspond to auxiliary-field
fluctuations. The coupling explains the striking differences in the
high-temperature asymptotes of the specific heats of the HXY model and the
Coulomb gas with an auxiliary field. Our results elucidate the propagation of
effective long-range interactions throughout the HXY model (whose interactions
are purely local) by the lattice electric fields. They also imply that global
spin-twist excitations (topological-sector fluctuations) generated by local
spin dynamics are ergodically excluded in the low-temperature phase. We discuss
the relevance of these results to condensate physics.Comment: 13 pages, 10 figure
Topological-sector fluctuations and ergodicity breaking at the Berezinskii-Kosterlitz-Thouless transition
The Berezinskii-Kosterlitz-Thouless (BKT) phase transition drives the
unbinding of topological defects in many two-dimensional systems. In the
two-dimensional Coulomb gas, it corresponds to an insulator-conductor
transition driven by charge deconfinement. We investigate the global
topological properties of this transition, both analytically and by numerical
simulation, using a lattice-field description of the two-dimensional Coulomb
gas on a torus. The BKT transition is shown to be an ergodicity breaking
between the topological sectors of the electric field, which implies a
definition of topological order in terms of broken ergodicity. The breakdown of
local topological order at the BKT transition leads to the excitation of global
topological defects in the electric field, corresponding to different
topological sectors. The quantized nature of these classical excitations, and
their strict suppression by ergodicity breaking in the low-temperature phase,
afford striking global signatures of topological-sector fluctuations at the BKT
transition. We discuss how these signatures could be detected in experiments
on, for example, magnetic films and cold-atom systems.Comment: 11 pages, 6 figure
Phase order in superfluid helium films
Classic experimental data on helium films are transformed to estimate a
finite-size phase order parameter that measures the thermal degradation of the
condensate fraction in the two-dimensional superfluid. The order parameter is
found to evolve thermally with the exponent , a
characteristic, in analogous magnetic systems, of the
Berezinskii-Kosterlitz-Thouless (BKT) phase transition. Universal scaling near
the BKT fixed point generates a collapse of experimental data on helium and
ferromagnetic films, and implies new experiments and theoretical protocols to
explore the phase order. These results give a striking example of experimental
finite-size scaling in a critical system that is broadly relevant to
two-dimensional Bose fluids.Comment: 6 pages, 2 figure
Topological Sector Fluctuations and Curie Law Crossover in Spin Ice
At low temperatures, a spin ice enters a Coulomb phase - a state with
algebraic correlations and topologically constrained spin configurations. In
Ho2Ti2O7, we have observed experimentally that this process is accompanied by a
non-standard temperature evolution of the wave vector dependent magnetic
susceptibility, as measured by neutron scattering. Analytical and numerical
approaches reveal signatures of a crossover between two Curie laws, one
characterizing the high temperature paramagnetic regime, and the other the low
temperature topologically constrained regime, which we call the spin liquid
Curie law. The theory is shown to be in excellent agreement with neutron
scattering experiments. On a more general footing, i) the existence of two
Curie laws appears to be a general property of the emergent gauge field for a
classical spin liquid, and ii) sheds light on the experimental difficulty of
measuring a precise Curie-Weiss temperature in frustrated materials; iii) the
mapping between gauge and spin degrees of freedom means that the susceptibility
at finite wave vector can be used as a local probe of fluctuations among
topological sectors.Comment: 10 pages, 5 figure
Vocal learning in animals and humans
Funding: S.C.V. was supported by a Max Planck Research Group (MPRG), a Human Frontiers Science Program (HFSP) Research grant (grant no. RGP0058/2016) and a UKRI Future Leaders Fellowship (MR/T021985/1).Publisher PDFPeer reviewe
Carbon supported lithium hydride nanoparticles: Impact of preparation conditions on particle size and hydrogen sorption
Nanosizing of light metal hydrides has yielded significant improvements to their hydrogen storage properties. We explored for the first time a procedure for preparing supported LiH nanoparticles. Impregnation of a carbon framework with a butyllithium solution, followed by reaction with gaseous hydrogen yielded LiH particles ranging in size from 2 nm to the micrometer scale. Reducing the reaction temperature from 300 C to 100 C, as well as the use of a t-butyllithium precursor instead of an n-butyllithium precursor, gave significant improvements on the degree of confinement of the LiH particles. The particle size of the LiH has a significant impact on the hydrogen release profile, 11 nm crystallites begin to release hydrogen as low as 100 C under argon flow, a reduction of roughly 400 C on the macrocrystalline system. The hydrogen release is reversible, with hydrogen uptake after desorption as high as 7.0 wt% w.r.t. LiH (0.8 wt% w.r.t the sample) under 0.1 bar of hydrogen at 200 C and full uptake takes place within 5 min at 26 bar. This new preparation procedure for supported light metal hydrides is particularly relevant for the field of hydrogen storage
Developing solid particulate vaccine adjuvants:surface bound antigen favouring a humoural response, whereas entrapped antigen shows a tendency for cell mediated immunity
This present study compares the efficacy of microsphere formulations, and their method of antigen presentation, for the delivery of the TB sub-unit vaccine antigen, Ag85B-ESAT-6. Microspheres based on poly(lactide-co-glycolide) (PLGA) and chitosan incorporating dimethyldioctadecylammonium bromide (DDA) were prepared by either the w/o/w double emulsion method (entrapped antigen) or the o/w single emulsion method (surface bound antigen), and characterised for their physico-chemical properties and their ability to promote an immune response to Ag85B-ESAT-6. The method of preparation, and hence method of antigen association, had a pronounced effect on the type of immune response achieved from the microsphere formulations, with surface bound antigen favouring a humoural response, whereas entrapped antigen favoured a cellular response
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