Identifying Needs and Implementing Organizational Change to Improve Retention of Early-Career Agents

Retention of agents is important for the growth and stability of Cooperative Extension. A study of early-career agents in Virginia Cooperative Extension identified specific areas in which organizational change could be made to improve agent fit in the organization and long-term retention. As a result, numerous changes have been made, particularly associated with existing agents but also in work with prospective agents. Although this article relates specifically to Virginia, the challenges and solutions identified may be relevant to other programs and to national professional development organizations

Ab initio data-analytics study of carbon-dioxide activation on semiconductor oxide surfaces

The excessive emissions of carbon dioxide (CO2) into the atmosphere threaten to shift the CO2 cycle planet-wide and induce unpredictable climate changes. Using artificial intelligence (AI) trained on high-throughput first principles based data for a broad family of oxides, we develop a strategy for a rational design of catalytic materials for converting CO2 to fuels and other useful chemicals. We demonstrate that an electron transfer to the π-antibonding orbital of the adsorbed molecule and the associated bending of the initially linear molecule, previously proposed as the indicator of activation, are insufficient to account for the good catalytic performance of experimentally characterized oxide surfaces. Instead, our AI model identifies the common feature of these surfaces in the binding of a molecular O atom to a surface cation, which results in a strong elongation and therefore weakening of one molecular C-O bond. This finding suggests using the C-O bond elongation as an indicator of CO2 activation. Based on these findings, we propose a set of new promising oxide-based catalysts for CO2 conversion, and a recipe to find more

Consumer Use of the Small Claims Court in Oklahoma

It is generally agreed that consumers have a right to redress when they are dissatisfied. However, the avenues of legal redress are seldom an object of evaluation. This study is concerned with evaluating consumer use of the small claims courts in Oklahoma. A content analysis of public records of small claims courts is used to determine the rates of use and success in small claims courts by consumers and vendors of goods or services.Housing, Design, and Consumer Resource

Hydrogen induced optically-active defects in silicon photonic nanocavities

This work was supported by Era-NET NanoSci LECSIN project coordinated by F. Priolo, by the Italian Ministry of University and Research, FIRB contract No. RBAP06L4S5 and by the EPSRC UKSp project. Partial financial support by the Norwegian Research Council is also acknowledged.We demonstrate intense room temperature photoluminescence (PL) from optically active hydrogen- related defects incorporated into crystalline silicon. Hydrogen was incorporated into the device layer of a silicon on insulator (SOI) wafer by two methods: hydrogen plasma treatment and ion implantation. The room temperature PL spectra show two broad PL bands centered at 1300 and 1500 nm wavelengths: the first one relates to implanted defects while the other band mainly relates to the plasma treatment. Structural characterization reveals the presence of nanometric platelets and bubbles and we attribute different features of the emission spectrum to the presence of these different kind of defects. The emission is further enhanced by introducing defects into photonic crystal (PhC) nanocavities. Transmission electron microscopy analyses revealed that the isotropicity of plasma treatment causes the formation of a higher defects density around the whole cavity compared to the ion implantation technique, while ion implantation creates a lower density of defects embedded in the Si layer, resulting in a higher PL enhancement. These results further increase the understanding of the nature of optically active hydrogen defects and their relation with the observed photoluminescence, which will ultimately lead to the development of intense and tunable crystalline silicon light sources at room temperature.Publisher PDFPeer reviewe

EMIC Waves in the Outer Magnetosphere: Observations of an Off-Equator Source Region.

Electromagnetic ion cyclotron (EMIC) waves at large L shells were observed away from the magnetic equator by the Magnetospheric MultiScale (MMS) mission nearly continuously for over four hours on 28 October 2015. During this event, the wave Poynting vector direction systematically changed from parallel to the magnetic field (toward the equator), to bidirectional, to antiparallel (away from the equator). These changes coincide with the shift in the location of the minimum in the magnetic field in the southern hemisphere from poleward to equatorward of MMS. The local plasma conditions measured with the EMIC waves also suggest that the outer magnetospheric region sampled during this event was generally unstable to EMIC wave growth. Together, these observations indicate that the bidirectionally propagating wave packets were not a result of reflection at high latitudes but that MMS passed through an off-equator EMIC wave source region associated with the local minimum in the magnetic field

Bandgap narrowing in Mn doped GaAs probed by room-temperature photoluminescence

The electronic band structure of the (Ga,Mn)As system has been one of the most intriguing problems in solid state physics over the past two decades. Determination of the band structure evolution with increasing Mn concentration is a key issue to understand the origin of ferromagnetism. Here we present room temperature photoluminescence and ellipsometry measurements of Ga_{100%-x}Mn_{x}As alloy. The up-shift of the valence-band is proven by the red shift of the room temperature near band gap emission from the Ga_{100%-x}Mn_{x}As alloy with increasing Mn content. It is shown that even a doping by 0.02 at.% of Mn affects the valence-band edge and it merges with the impurity band for a Mn concentration as low as 0.6 at.%. Both X-ray diffraction pattern and high resolution cross-sectional TEM images confirmed full recrystallization of the implanted layer and GaMnAs alloy formation.Comment: 24 pages, 7 figures, accepted at Phys. Rev. B 201

The alternating least-squares algorithm for CDPCA

Clustering and Disjoint Principal Component Analysis (CDP CA) is a constrained principal component analysis recently proposed for clustering of objects and partitioning of variables, simultaneously, which we have implemented in R language. In this paper, we deal in detail with the alternating least-squares algorithm for CDPCA and highlight its algebraic features for constructing both interpretable principal components and clusters of objects. Two applications are given to illustrate the capabilities of this new methodology

Validating Ionospheric Models Against Technologically Relevant Metrics

New, open access tools have been developed to validate ionospheric models in terms of technologically relevant metrics. These are ionospheric errors on GPS 3D position, HF ham radio communications, and peak F-region density. To demonstrate these tools, we have used output from Sami is Another Model of the Ionosphere (SAMI3) driven by high-latitude electric potentials derived from Active Magnetosphere and Planetary Electrodynamics Response Experiment, covering the first available month of operation using Iridium-NEXT data (March 2019). Output of this model is now available for visualization and download via https://sami3.jhuapl.edu. The GPS test indicates SAMI3 reduces ionospheric errors on 3D position solutions from 1.9 m with no model to 1.6 m on average (maximum error: 14.2 m without correction, 13.9 m with correction). SAMI3 predicts 55.5% of reported amateur radio links between 2–30 MHz and 500–2,000 km. Autoscaled and then machine learning “cleaned” Digisonde NmF2 data indicate a 1.0 × 1011 el. m3 median positive bias in SAMI3 (equivalent to a 27% overestimation). The positive NmF2 bias is largest during the daytime, which may explain the relatively good performance in predicting HF links then. The underlying data sources and software used here are publicly available, so that interested groups may apply these tests to other models and time intervals.</p