12 research outputs found
Removal of tiemonium methylsulfate, from aqueous solutions using activated carbon prepared from date stones
International audienceThe retention of a pharmaceutical compound, tiemonium methylsulfate (TIM), from aqueous solutions by adsorption onto activated carbon prepared from date stones (ACâDS) was investigated. Physical and chemical characteristics of this material were also determined. Results showed that pH 8 was optimal for TIM adsorption. Among the kinetic models considered, the pseudo-second-order model was the most appropriate to describe experimental data. Regarding adsorption isotherms, it was shown that the Sips model accurately describe the sorption of TIM onto ACâDS with a correlation factor R2â>â0.98. The adsorption capacity of ACâDS was found to be 42.2âmgâgâ1 at 10°C and 60.5âmgâgâ1 at 25°C, confirming its efficiency for the removal of this compound from aqueous solutions. The values of ÎG0 and ÎH0 confirmed that the adsorption of TIM onto ACâDS was spontaneous and endothermic in nature and hence more effective at high temperatures. An irregular increase in the randomness was suggested at the ACâDS solution interface during the adsorption process for positive values of ÎS0
Local Materials and Solid Waste (Sawdust) Valorization in the Treatment of Industrial Synthetic Water Field
International audienceThis work dealt with a dual environmental aspect: on the one hand, the valorization of natural by-products (sawdust and dune sand), and, on the other hand, the assessment of the purification efficiency of a bilayer of the two by-products. The effectiveness was evaluated through the monitoring of some parameters, namely, paranitrophenol concentration, BOD5, and COD. Promising results were obtained, and hence further works are in progress regarding the application of this process to other pollutants present in wastewater. © 2021, The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Switzerland AG
Removal of tiemonium methylsulfate, from aqueous solutions using activated carbon prepared from date stones
International audienceThe retention of a pharmaceutical compound, tiemonium methylsulfate (TIM), from aqueous solutions by adsorption onto activated carbon prepared from date stones (ACâDS) was investigated. Physical and chemical characteristics of this material were also determined. Results showed that pH 8 was optimal for TIM adsorption. Among the kinetic models considered, the pseudo-second-order model was the most appropriate to describe experimental data. Regarding adsorption isotherms, it was shown that the Sips model accurately describe the sorption of TIM onto ACâDS with a correlation factor R2â>â0.98. The adsorption capacity of ACâDS was found to be 42.2âmgâgâ1 at 10°C and 60.5âmgâgâ1 at 25°C, confirming its efficiency for the removal of this compound from aqueous solutions. The values of ÎG0 and ÎH0 confirmed that the adsorption of TIM onto ACâDS was spontaneous and endothermic in nature and hence more effective at high temperatures. An irregular increase in the randomness was suggested at the ACâDS solution interface during the adsorption process for positive values of ÎS0
Preparation of Porous Carbons Under Basic Condition by Soft Template Method for Carbon Capture
Activated coke preparation by physical activation of coal and biomass co-carbonized chars
Influence of Pyrolysis Conditions on Surface Characteristics and Methylene Blue Adsorption of Biochar Derived from Date Seed Biomass
Preparation of activated carbons from date (Phoenix dactylifera L.) palm stones and application for wastewater treatments: Review
Agregação de valor Ă resĂduo agroindustrial: remoção de fenol utilizando adsorvente preparado a partir de casca de amendoim
Este trabalho teve como objetivo avaliar a eficiĂȘncia do carvĂŁo ativado com CO2 (CA) produzido a partir da casca de amendoim como adsorvente para remoção de fenol em solução aquosa (100-300 mg.L-1). A caracterização do CA foi realizada pelos mĂ©todos de BET, DRX, TGA, FT-IR e pHpcz, houve a caracterização da casca de amendoim (CS) para fins de comparação. Avaliou-se a influĂȘncia do pH inicial da solução e a dosagem do adsorvente (D.A.). As condiçÔes de trabalho foram definidas com o auxĂlio de um planejamento fatorial 23 (PF) avaliando a influĂȘncia das variĂĄveis: D.A., granulometria (G.) e velocidade de agitação (V.A.) sobre o processo adsortivo, tendo como resposta a capacidade adsortiva q (mg.g-1). Com base nos resultados do PF foram realizados estudos cinĂ©ticos e de equilĂbrio de adsorção. O carvĂŁo foi classificado como mesoporoso e predominantemente amorfo. Na TGA foi observada maior estabilidade do material apĂłs a ativação. Nos espectros de FT-IR foram identificadas bandas referentes a grupos hidroxilas, carboxĂlicos e Ă©steres. O pHpcz foi 10,4 possibilitando a utilização das soluçÔes fenĂłlicas em pH natural da solução. No PF, o maior q foi obtido para o nĂvel 4 g.L-1, G. 0,090 mm e 300 rpm, condição adotada nos estudos cinĂ©ticos e de equilĂbrio. A evolução cinĂ©tica foi rĂĄpida atĂ© 120 minutos, atingindo o equilĂbrio em torno de 480 minutos. O modelo pseudo n ordem foi o que melhor se ajustou aos dados experimentais e foi constatado que o processo Ă© controlado por mais de uma etapa, incluindo difusĂŁo intrapartĂcula. No estudo do equilĂbrio os modelos que melhor se ajustaram aos dados experimentais foram os de Fritz-Schlunder e Redlich-Peterson apresentando qmax de 29,01 Ă 0,96 mg.g-1. Os resultados demonstraram o potencial tĂ©cnico do carvĂŁo em estudo para remoção de fenol presente em solução aquosaPalavras-chave: ativação fĂsica, efluente industrial, resĂduo agroindustrial