REMOVED: Surface Modification of Mixed Matrix Membranes for the Reduction of Fouling

This article has been removed: please see Elsevier Policy on Article Withdrawal (http://www.elsevier.com/locate/withdrawalpolicy).This article has been removed at the request of the Executive Publisher.This article has been removed because it was published without the permission of the author(s)

Inertial range scaling of the scalar flux spectrum in two-dimensional turbulence

Two-dimensional statistically stationary isotropic turbulence with an imposed uniform scalar gradient is investigated. Dimensional arguments are presented to predict the inertial range scaling of the turbulent scalar flux spectrum in both the inverse cascade range and the enstrophy cascade range for small and unity Schmidt numbers. The scaling predictions are checked by direct numerical simulations and good agreement is observed

Inertial range scaling of scalar flux spectra in uniformly sheared turbulence

A model based on two-point closure theory of turbulence is proposed and applied to study the Reynolds number dependency of the scalar flux spectra in homogeneous shear flow with a cross-stream uniform scalar gradient. For the cross-stream scalar flux, in the inertial range the spectral behavior agrees with classical predictions and measurements. The streamwise scalar flux is found to be in good agreement with the results of atmospheric measurements. However, both the model results and the atmospheric measurements disagree with classical predictions. A detailed analysis of the different terms in the evolution equation for the streamwise scalar flux spectrum shows that nonlinear contributions are governing the inertial subrange of this spectrum and that these contributions are relatively more important than for the cross-stream flux. A new expression for the scalar flux spectra is proposed. It allows us to unify the description of the components in one single expression, leading to a classical K^-7/3 inertial range for the cross-stream component and to a new K^-23/9 scaling for the streamwise component that agrees better with atmospheric measurements than the K^-3 prediction of J. C. Wyngaard and O. R. Cot\'e [Quart. J. R. Met. Soc. 98, 590 (1972)]

Разработка отклонителя для управления направлением скважин при ударно-вращательном бурении

Die Kombination einer Membran mit einer katalytischen Reaktion in einem Membranreaktor ist eines der Konzepte multifunktionaler Reaktoren zur Prozessintensivierung. Eine industriell besonders interessante Anwendung ist dabei die Darstellung von Synthesegas durch partielle Oxidation von Methan zu Kohlenmonoxid und Wasserstoff, wobei der Sauerstoff durch eine gemischtleitende Perowskit-Membran aus Luft zudosiert wird. Es ist gelungen, entsprechende Perowskit-Membranen als Hohlfasern mit einer volumenbezogenen Membranfläche von bis zu 500 m²/m³ durch einen ökonomischen Spinnprozess zu entwickeln. Unter Laborbedingungen konnten langzeitstabil Synthesegas (CO, H₂) mit einer CO-Selektivität von 95 % bei 95 % CH₄-Umsatz erzeugt und die Ergebnisse durch eine detaillierte mathematische Modellierung beschrieben werden. Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim [accessed February 8th 2013

Emerging CO2 capture systems

In 2005, the IPCC SRCCS recognized the large potential for developing and scaling up a wide range of emerging CO2 capture technologies that promised to deliver lower energy penalties and cost. These included new energy conversion technologies such as chemical looping and novel capture systems based on the use of solid sorbents or membrane-based separation systems. In the last 10 years, a substantial body of scientific and technical literature on these topics has been produced from a large number of R&D projects worldwide, trying to demonstrate these concepts at increasing pilot scales, test and model the performance of key components at bench scale, investigate and develop improved functional materials, optimize the full process schemes with a view to a wide range of industrial applications, and to carry out more rigorous cost studies etc. This paper presents a general and critical review of the state of the art of these emerging CO2 capture technologies paying special attention to specific process routes that have undergone a substantial increase in technical readiness level toward the large scales required by any CO2 capture system

Controlled surface functionalization of silica nanospheres by covalent conjugation reactions and preparation of high density streptavidin nanoparticles

Silica nanoparticles with a diameter of 100 nm were covalently modified at their surface by adjustable amounts of amine and carboxyl functional groups. Bioconjugation studies of two proteins, streptavidin and streptactin, with the functional nanoparticles resulted in optimum binding of the proteins to a long-chain carboxyl-terminated linker. The surface functionalization of the nanoparticles was monitored by a variety of independent methods, including zeta-potential measurements, dynamic light scattering (DLS), scanning electron microscopy (SEM), particle charge detection titrations (PCD) and elemental analysis. At the surface of the nanoparticles, a functional surface group density of 1.8 amino groups per nm(2) was realized. The amine functions were quantitatively transferred to carboxyl groups coupled with a linker elongation. Streptavidin was immobilized by covalent binding to the carboxyl linkers and resulted in a protein density at the surface of the nanoparticles that was three times higher than the highest binding densities at nanoparticles published to date. The binding capacity of the streptavidin-covered nanoparticles for ligand biotin was quantified by titration with biotin-4-fluorescein to 2.5 biotin binding sites per 100 nm(2)