10 research outputs found

    The Goli d'Aget Member: Early Permian volcanoclastic and volcanic rocks within the Briançonnais Grand St-Bernard Nappe (Valais, Switzerland)

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    Abstract.: The well-preserved sedimentary structures of the Goli d'Aget Member (Early Permian) allow to distinguish four successive environments of deposition: 1) An alluvial plain with important channeling and evidence of volcanic activity; 2) A shallow lacustrine environment with a low water level, deposition of massive carbonates and an increasing contribution of volcanic materials; 3) A fluviatile plain with the deposition of volcanic tuffs; 4) A deltaic to lacustrine environment occasionally covered by pyroclastic flows. An ignimbritic rhyolite from the upper part of the Goli d'Aget Member has an age of 267-282 Ma (U-Pb on zircon). Major and trace elements, as well as zircon typology point to a calc-alkaline and volcanic-arc affinity for that high-silica rhyolite. The Goli d'Aget Member may be the best-preserved unit among the Permian units from the Swiss Penninic Western Alps. This series provides an important point of comparison with other local Permian units (Dent de Nendaz and Cleuson Members) and with similar series in the Western Alps including the Melogno porphyroids in the Ligurian Alps and the Rochachille Series near Briançon (France

    The Goli d’Aget Member: Early Permian volcanoclastic and volcanic rocks within the Briançonnais Grand St-Bernard Nappe (Valais, Switzerland)

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    The well-preserved sedimentary structures of the Goli d’Aget Member (Early Permian) allow to distinguish four successive environments of deposition: 1) An alluvial plain with important channeling and evidence of volcanic activity; 2) A shallow lacustrine environment with a low water level, deposition of massive carbonates and an increasing contribution of volcanic materials; 3) A fluviatile plain with the deposition of volcanic tuffs; 4) A deltaic to lacustrine environment occasionally covered by pyroclastic flows. An ignimbritic rhyolite from the upper part of the Goli d’Aget Member has an age of 267-282 Ma (U-Pb on zircon). Major and trace elements, as well as zircon typology point to a calc-alkaline and volcanic-arc affinity for that high-silica rhyolite. The Goli d’Aget Member may be the best-preserved unit among the Permian units from the Swiss Penninic Western Alps. This series provides an important point of comparison with other local Permian units (Dent de Nendaz and Cleuson Members) and with similar series in the Western Alps including the Melogno porphyroids in the Ligurian Alps and the Rochachille Series near Briançon (France)

    The 500 Ma-old Thy on metagranite: a new A-type granite occurrence in the western Penninic Alps (Wallis, Switzerland)

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    The Thyon metagranite is located in the frontal part of the Siviez-Mischabel Nappe, in the western Penninic Alps. It is intrusive in a polymetamorphic banded volcanic complex as leucocratic concordant sills with pseudoaplitic rims. A distinct metamorphic schistosity is defined by dark-green Fe-rich biotite. Abundant mesoperthites, chess-board albite and low microcline are presumably related to magmatic stages and/or greenschist-facies metamorphic retrogression. Major, trace element and REE geochemistry, zircon typology, Y and Nb-bearing accessory minerals such as fergusonite and euxenite, all point to a metaluminous to peraluminous alkaline A-type granite. High-precision U-Pb zircon dating yielded a sub-concordant age of 500 +3/-4 Ma. The Thyon metagranite is the third record of a Cambro-Ordovician alkaline magmatic activity in the Alps. As A-type granitic magmatism is common in post-orogenic to anorogenic extensional tectonic regime, the Thyon intrusion could mark the transition between the Cadomian and the Caledonian orogenies

    Self-association of double-hydrophilic copolymers of acrylic acid and poly(ethylene oxide) macromonomer

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    Poly(ethylene oxide) (PEO) end-capped by a methacrylate unsaturation was copolymerized with acrylic acid by RAFT with dibenzyltrithiocarbonate as a chain transfer agent. Tapered triblock copolymers consisting of a poly(acrylic acid) (PAA) inner block and comb-like outer blocks of PEO macromomers were formed as result of the comonomers reactivity ratios. Composition of these copolymers and length of the PEO branches were varied. Dynamic light scattering (DLS) was used to characterize the aggregates formed in water and to investigate their response to stimuli, such as pH, temperature and ionic strength. In parallel, the morphology of the aggregates was directly observed by transmission electron microscopy (TEM). Well-defined aggregates were formed in the 58 as consequence of the complete ionization of the PAA block

    Humusica 1, article 4 : Terrestrial humus systems and forms-Specific terms and diagnostic horizons

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    Knowledge of a little number of specific terms is necessary to investigate and describe humipedons. This "new vocabulary" allows individuating and circumscribing particular diagnostic horizons, which are the fundamental bricks of the humipedon. Few "components" defined by specific terms characterize a specific "humipedon horizon"; few "humipedon horizons" compose a given "humus form" and some similar "humus forms" are grouped in a functional "humus system". In this article, specific terms and humus horizons are listed and explained one by one. Field difficulties are illustrated and resolved. The aim of the article is to present in a manner as simple as possible how to distinguish in the field the soil structures allowing a morpho-functional classification of terrestrial (aerated, not submerged) humipedons

    Aspects of Disorders of the Kynurenine Pathway of Tryptophan Metabolism in Man

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