Depletion and refertilization of the Tethyan oceanic upper mantle as revealed by the early Jurassic Refahiye ophiolite, NE Anatolia-Turkey

We present new whole-rock major and trace element, Re-Os isotope and mineral chemistry data for the upper mantle peridotites and mafic rocks in the Rehafiye ophiolite in NE Anatolia (Turkey), and discuss their significance for the mantle evolution in Neotethys. The Refahiye peridotites include clinopyroxene (cpx)-rich and cpx-poor harzburgites. Assuming an initial fertile mantle composition, the cpx-rich harzburgites have a limited range of Cr-spl Cr# (33-38), implying 14-18% melt extraction. However, TiO2 contents of the Cr-spl in these rocks are too high (up to 0.24wt.%) to explain their Ti concentrations with a simple melt extraction model in a mid-ocean ridge (MOR) setting, and suggest re-crystallization from an impregnating fertile melt. The interstitial phases of cpx in these samples have high TiO2 (up to 0.40wt.%) and Na2O (up to 0.25wt.%) contents. They also contain interstitial pargasitic amphibole with TiO2 contents varying between 0.69 and 0.88wt.%. These textures and the mineral chemistry data indicate refertilization of the previously depleted, MOR-type peridotites by percolating hydrous melts. The whole-rock REE partial melting modeling is consistent with slightly lower degrees of mantle melting (~12-14%) compared to the melt extraction degrees obtained from the Cr-spl compositions (~15%). Chromian spinel (Cr-spl) phases in the cpx-poor harzburgites show a wider variation of Cr#, ranging between 57 and 75, and reflect 30-40% of partial melting. In contrast, the whole-rock geochemistry of these rocks represents slightly lower degrees of partial melting, varying between 30 and 35%. The enrichment of TiO2 contents of the Cr-spl (up to 0.20wt.%) in some of the cpx-poor harzburgites can be explained by their interaction with Ti-rich hydrous melt formed at supra-subduction (SSZ) tectonic setting. Highly unradiogenic Os isotope composition (0.11956) of a cpx-poor harzburgite sample suggests an ancient melt depletion event experienced by these rocks, whereas its high Re content is a manifestation of subduction enrichment. The mafic units of the Refahiye ophiolite show MORB-like to island arc tholeiite (IAT) geochemical signatures typical of SSZ oceanic crust. A U-Pb zircon age of 183±1Ma obtained from an isotropic gabbro sample suggests that the crystallization of the SSZ-type mafic units in the Refahiye ophiolite is as old as the early Jurassic.Fil: Uysal, Ibrahim. Karadeniz Teknik Üniversitesi; TurquíaFil: Ersoy, E. Yalçin. Dokuz Eylül University; TurquíaFil: Dilek, Yildirim. Miami University; Estados UnidosFil: Escayola, Monica Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Sarıfakıoğlu, Ender. Mineral Research & Exploration. General Directorate. Geological Research Department; TurquíaFil: Saka, Samet. Karadeniz Teknik Üniversitesi; TurquíaFil: Hirata, Takafumi. Kyoto University; Japó

Collision Chronology Along the İzmir‐Ankara‐Erzincan Suture Zone: Insights From the Sarıcakaya Basin, Western Anatolia

International audienceDebate persists concerning the timing and geodynamics of intercontinental collision, style of syncollisional deformation, and development of topography and fold-and-thrust belts along the >1,700-km-long İzmir-Ankara-Erzincan suture zone (İAESZ) in Turkey. Resolving this debate is a necessary precursor to evaluating the integrity of convergent margin models and kinematic, topographic, and biogeographic reconstructions of the Mediterranean domain. Geodynamic models argue either for a synchronous or diachronous collision during either the Late Cretaceous and/or Eocene, followed by Eocene slab breakoff and postcollisional magmatism. We investigate the collision chronology in western Anatolia as recorded in the sedimentary archives of the 90-km-long Sarıcakaya Basin perched at shallow structural levels along the İAESZ. Based on new zircon U-Pb geochronology and depositional environment and sedimentary provenance results, we demonstrate that the Sarıcakaya Basin is an Eocene sedimentary basin with sediment sourced from both the İAESZ and Söğüt Thrust fault to the south and north, respectively, and formed primarily by flexural loading from north-south shortening along the syncollisional Söğüt Thrust. Our results refine the timing of collision between the Anatolides and Pontide terranes in western Anatolia to Maastrichtian-Middle Paleocene and Early Eocene crustal shortening and basin formation. Furthermore, we demonstrate contemporaneous collision, deformation, and magmatism across the İAESZ, supporting synchronous collision models. We show that regional postcollisional magmatism can be explained by renewed underthrusting instead of slab breakoff. This new İAESZ chronology provides additional constraints for kinematic, geodynamic, and biogeographic reconstructions of the Mediterranean domain

Permo-Carboniferous granitoids with Jurassic high temperature metamorphism in Central Pontides, Northern Turkey

In the northern part of the Central Pontides (N Turkey) there are different metamorphic rocks exposed, notably the Devrekani metamorphic rocks. Here, upper amphibolite-lower granulite facies metamorphic rocks contain predominantly paragneiss, orthogneiss and metacarbonate, and to a lesser extent, amphibolite and quartzite, with cross-cutting aplite, pegmatite and granite veins. This is the first report of these rocks and includes new data on the petrochemistry, geochronology and metamorphic evolution of the Devrekani orthogneisses from the Central Pontides. The orthogneisses show five different mineral parageneses with the characteristic mineral assemblage quartz + K-feldspar + plagioclase + biotite ± hornblende ± opaque (± ilmenite and ± magnetite), and accessory minerals (zircon, sphene and apatite). These metamorphic rocks exhibit generally granoblastic, lepidogranoblastic and nematolepidogranoblastic with locally migmatitic and relic micrographic textures. They have well-developed centimeter-spaced gneissic banding and display gneissose structure with symmetric, asymmetric and irregular folds. The petrographic features, mineralogical assemblages and weak migmatization reflect high temperature conditions. Thermometric calculations in the orthogneisses indicate metamorphic temperatures reached 744 ± 33 °C. Field relations, petrography and petrochemistry suggest that the orthogneisses have predominantly granodioritic and some granitic protoliths, that show features of I-type, medium to high-potassic calc-alkaline volcanic arc granitoids. The orthogneisses have high contents of LILEs and low contents of HFSEs with negative Nb and Ti anomalies, which are typical of subduction-related magmas. The orthogneisses also show significant LREE enrichment relative to HREE with negative Eu anomalies (EuN/Eu* = 0.33–1.07) with LaN/LuN = 6.98–20.47 values. Based on U-Pb zircon dating data, the protoliths are related to Permo-Carboniferous (316–252 Ma) magmatism. It is likely that peak metamorphism took place during the Jurassic as reflected by the U-Pb zircon ages (199–158 Ma) and also 40Ar/39Ar from hornblende/biotite (163–152 Ma). The four biotite 40Ar/39Ar average ages from the rock samples are ca. 156 Ma, suggesting that the metamorphic rocks cooled to 350–400 °C at ca. 156 Ma. Conclusively, the Devrekani metamorphic rocks can be ascribed as products of Permo-Carboniferous continental arc magmatism overprinted by Jurassic metamorphism in the northern Central Pontides

Jurassic to Cenozoic Magmatic and Geodynamic Evolution of the Eastern Pontides and Caucasus Belts, and Their Relationship With the Eastern Black Sea Basin Opening

The magmatic arcs of the Eastern Pontides and Lesser Caucasus lie in continuation from one another. A comparison of the subduction related magmatic rocks outcropping throughout this segment of the Northern Tethyan belt exhibits chronological disparities, questioning the common subduction history of the Eastern Pontides and the Lesser Caucasus regions. New data and observations including geochronological and geochemical data, relative to subduction to collision related magmatic rocks argues a novel paleogeographic reconstruction illustrating Mesozoic and Cenozoic evolution of this region. Jurassic to Early Cretaceous arc magmatism runs mainly from the Sochi-Ritsa/Bechasyn regions (Greater Caucasus) towards the south-east to the Alaverdi region and further into the Lesser Caucasus. Late Cretaceous and Cenozoic arc magmatism is evidenced throughout the Eastern Pontides extending through the Bolnisi region to the Lesser Caucasus arc. East to west, Jurassic to Early Cretaceous and Late Cretaceous to Cenozoic portions of arc split to the north and south of the Eastern Black Sea, respectively. Throughout Cretaceous subduction, this segment of the magmatic arc of the Southern Eurasian margin was torn in two due to the oblique opening of the Eastern Black Sea as a back- to intra-arc basin, from west to east. This reconstitution implies that the Jurassic-Early Cretaceous subduction related magmatic rocks of the Greater Caucasus are remnant potions of the Eastern Pontides and Lesser Caucasus arcs. This infers the emplacement of subduction to collision related magmatic rocks throughout the Mesozoic and Cenozoic along the entire Southern Eurasian margin is solely due to a single long-lasting north-dipping subduction

Multiple episodes of partial melting, depletion, metasomatism and enrichment processes recorded in the heterogeneous upper mantle sequence of the Neotethyan Eldivan ophiolite, Turkey

The Eldivan ophiolite along the Izmir-Ankara-Erzincan suture zone in north-central Anatolia represents a remnant of the Neotethyan oceanic lithosphere. Its upper mantle peridotites include three lithologically and compositionally distinct units: clinopyroxene (cpx)-harzburgite and Iherzolite (Group-1), depleted harzburgite (Group-2), and dunite (Group-3). Relics of primary olivine and pyroxene occur in the less refractory harzburgites, and fresh chromian spinel (Cr-spinel) is ubiquitous in all peridotites. The Eldivan peridotites reflect a petrogenetic history evolving from relatively fertile (lherzolite and cpx-harzburgite) toward more depleted (dunite) compositions through time, as indicated by (i) a progressive decrease in the modal cpx distribution, (ii) a progressive increase in the Cr#s [Cr / (Cr + Al)] of Cr-spinel (0.15-0.78), and (iii) an increased depletion in the whole-rock abundances of some magmaphile major oxides (Al2O3, CaO, SiO2 and TiO2) and incompatible trace elements (Zn, Sc, V and Y). The primitive mantle-normalized REE patterns of the Group-1 and some of the Group-2 peridotites display LREE depletions. Higher Yb-N and lower Sm-N/Yb-N ratios of these rocks are compatible with their formation after relatively low degrees (9-25%) of open-system dynamic melting (OSDM) of a Depleted Mid-ocean ridge Mantle (DMM) source, which was then fluxed with small volumes of oceanic mantle-derived melt [fluxing ratio (beta): 0.7-12%1. Accessory Cr-spinel compositions (Cr# = 015-0.53) of these rocks are consistent with their origin as residual peridotites beneath a mid-ocean ridge axis. Part of the Group-2 harzburgites exhibit lower YbN and higher SmN/YbN ratios, LREE-enriched REE patterns, and higher Cr-spinel Cr#s ranging between 0.54 and 0.61. Trace element compositions of these peridotites can be modeled by approximately 15% OSDM of a previously 17% depleted DMM, which was then fluxed (beta: 0.4%) with subduction-influenced melt. The Group-3 dunite samples contain Cr-spinel with elevated Cr#s (0.73-0.78) and low-TiO2 contents (<0.13 wt.%), implying higher degrees of melting (21-24%) of an already depleted DMM that was triggered by infiltration of low-Ti boninite melt with fluxing rates of 0.4-4.0%. The existence of interstitial, idiomorphic Cr-spinel (high Cr# and low Ti) in the Group-3 dunites is consistent with this interpretation. The occurrence of both MOR- and SSZ-type peridotites in the Eldivan ophiolite suggests that its heterogeneous upper mantle was produced as a result of different partial melting and melt -rock reaction processes in different tectonic settings within the Neotethyan realm. (C) 2016 Elsevier B.V. All rights reserved