367 research outputs found
Electrical current distribution across a metal-insulator-metal structure during bistable switching
Combining scanning electron microscopy (SEM) and electron-beam-induced
current (EBIC) imaging with transport measurements, it is shown that the
current flowing across a two-terminal oxide-based capacitor-like structure is
preferentially confined in areas localized at defects. As the thin-film device
switches between two different resistance states, the distribution and
intensity of the current paths, appearing as bright spots, change. This implies
that switching and memory effects are mainly determined by the conducting
properties along such paths. A model based on the storage and release of charge
carriers within the insulator seems adequate to explain the observed memory
effect.Comment: 8 pages, 7 figures, submitted to J. Appl. Phy
Use of near infrared reflectance spectroscopy to predict nitrogen uptake by winter wheat within fields with high variability in organic matter
In this study, the ability to predict N-uptake in winter wheat crops using NIR-spectroscopy on soil samples was evaluated. Soil samples were taken in unfertilized plots in one winter wheat field during three years (1997-1999) and in another winter wheat field nearby in one year (2000). Soil samples were analyzed for organic C content and their NIR-spectra. N-uptake was measured as total N-content in aboveground plant materials at harvest. Models calibrated to predict N-uptake were internally cross validated and validated across years and across fields. Cross-validated calibrations predicted N-uptake with an average error of 12.1 to 15.4 kg N ha-1. The standard deviation divided by this error (RPD) ranged between 1.9 and 2.5. In comparison, the corresponding calibrations based on organic C alone had an error from 11.7 to 28.2 kg N ha-1 and RPDs from 1.3 to 2.5. In three of four annual calibrations within a field, the NIR-based calibrations worked better than the organic C based calibrations. The prediction of N-uptake across years, but within a field, worked slightly better with an organic C based calibration than with a NIR based one, RPD = 1.9 and 1.7 respectively. Across fields, the corresponding difference was large in favour of the NIR-calibration, RPD = 2.5 for the NIR-calibration and 1.5 for the organic C calibration. It was concluded that NIR-spectroscopy integrates information about organic C with other relevant soil components and therefore has a good potential to predict complex functions of soils such as N-mineralization. A relatively good agreement of spectral relationships to parameters related to the N-mineralization of datasets across the world suggests that more general models can be calibrated
A CMOS 130nm Evaluation digitzer chip for silicon strips readout
A CMOS 130nm evaluation chip intended to read Silicon strip detectors at the ILC has been designed and successfully tested. Optimized for a detector capacitance of 10 pF, it includes four channels of charge integration, pulse shaping, a 16-deep analogue sampler triggered on input analogue sums, and parallel analogue to digital conversion. Tests results of the full chain are reported, demonstrating the behaviour and performance of the full sampling process and analogue to digital conversion. Each channel dissipates less than one milli-Watt static power
Off-Equilibrium Dynamics in Finite-Dimensional Spin Glass Models
The low temperature dynamics of the two- and three-dimensional Ising spin
glass model with Gaussian couplings is investigated via extensive Monte Carlo
simulations. We find an algebraic decay of the remanent magnetization. For the
autocorrelation function a typical
aging scenario with a scaling is established. Investigating spatial
correlations we find an algebraic growth law of
the average domain size. The spatial correlation function scales with . The sensitivity of the
correlations in the spin glass phase with respect to temperature changes is
examined by calculating a time dependent overlap length. In the two dimensional
model we examine domain growth with a new method: First we determine the exact
ground states of the various samples (of system sizes up to )
and then we calculate the correlations between this state and the states
generated during a Monte Carlo simulation.Comment: 38 pages, RevTeX, 14 postscript figure
A global spectral library to characterize the world's soil
Soil provides ecosystem services, supports human health and habitation, stores carbon and regulates emissions of greenhouse gases. Unprecedented pressures on soil from degradation and urbanization are threatening agro-ecological balances and food security. It is important that we learn more about soil to sustainably manage and preserve it for future generations. To this end, we developed and analyzed a global soil visible-near infrared (vis-NIR) spectral library. It is currently the largest and most diverse database of its kind. We show that the information encoded in the spectra can describe soil composition and be associated to land cover and its global geographic distribution, which acts as a surrogate for global climate variability. We also show the usefulness of the global spectra for predicting soil attributes such as soil organic and inorganic carbon, clay, silt, sand and iron contents, cation exchange capacity, and pH. Using wavelets to treat the spectra, which were recorded in different laboratories using different spectrometers and methods, helped to improve the spectroscopic modelling. We found that modelling a diverse set of spectra with a machine learning algorithm can find the local relationships in the data to produce accurate predictions of soil properties. The spectroscopic models that we derived are parsimonious and robust, and using them we derived a harmonized global soil attribute dataset, which might serve to facilitate research on soil at the global scale. This spectroscopic approach should help to deal with the shortage of data on soil to better understand it and to meet the growing demand for information to assess and monitor soil at scales ranging from regional to global. New contributions to the library are encouraged so that this work and our collaboration might progress to develop a dynamic and easily updatable database with better global coverage. We hope that this work will reinvigorate our community's discussion towards larger, more coordinated collaborations. We also hope that use of the database will deepen our understanding of soil so that we might sustainably manage it and extend the research outcomes of the soil, earth and environmental sciences towards applications that we have not yet dreamed of
Combining visible near-infrared spectroscopy and water vapor sorption for soil specific surface area estimation
Abstract The soil specific surface area (SSA) is a fundamental property governing a range of soil processes relevant to engineering, environmental, and agricultural applications. A method for SSA determination based on a combination of visible nearâinfrared spectroscopy (visâNIRS) and vapor sorption isotherm measurements was proposed. Two models for water vapor sorption isotherms (WSIs) were used: the TullerâOr (TO) and the GuggenheimâAndersonâde Boer (GAB) model. They were parameterized with sorption isotherm measurements and applied for SSA estimation for a wide range of soils (NÂ =Â 270) from 27 countries. The generated visâNIRS models were compared with models where the SSA was determined with the ethylene glycol monoethyl ether (EGME) method. Different regression techniques were tested and included partial least squares (PLS), support vector machines (SVM), and artificial neural networks (ANN). The effect of dataset subdivision based on EGME values on model performance was also tested. Successful calibration models for SSATO and SSAGAB were generated and were nearly identical to that of SSAEGME. The performance of models was dependent on the range and variation in SSA values. However, the comparison using selected validation samples indicated no significant differences in the estimated SSATO, SSAGAB, and SSAEGME, with an average standardized RMSE (SRMSEÂ =Â RMSE/range) of 0.07, 0.06 and 0.07, respectively. Small differences among the regression techniques were found, yet SVM performed best. The results of this study indicate that the combination of visâNIRS with the WSI as a reference technique for visâNIRS models provides SSA estimations akin to the EGME method
Torque magnetometry on single-crystal high temperature superconductors near the critical temperature: a scaling approach
Angular-dependent magnetic torque measurements performed near the critical
temperature on single crystals of HgBa_{2}CuO_{4+y}, La_{2-x}Sr{x}CuO_{4}, and
YBa_{2}Cu_{3}O_{6.93} are scaled, following the 3D XY model, in order to
determine the scaling function dG^{\pm}(z)/dz which describes the universal
critical properties near T_{c}. A systematic shift of the scaling function with
increasing effective mass anisotropy \gamma = (m_{ab}*/m_{c}*)^{1/2} is
observed, which may be understood in terms of a 3D-2D crossover. Further
evidence for a 3D-2D crossover is found from temperature-dependent torque
measurements carried out in different magnetic fields at different field
orientations \delta, which show a quasi 2D "crossing region'' (M*,T*). The
occurrence of this "crossing phenomenon'' is explained in a phenomenological
way from the weak z dependence of the scaling function around a value z = z*.
The "crossing'' temperature T* is found to be angular-dependent. Torque
measurements above T_{c} reveal that fluctuations are strongly enhanced in the
underdoped regime where the anisotropy is large, whereas they are less
important in the overdoped regime.Comment: 9 pages, 10 figures, submitted to PR
Scanning tunneling spectroscopy of high-temperature superconductors
Tunneling spectroscopy played a central role in the experimental verification
of the microscopic theory of superconductivity in the classical
superconductors. Initial attempts to apply the same approach to
high-temperature superconductors were hampered by various problems related to
the complexity of these materials. The use of scanning tunneling
microscopy/spectroscopy (STM/STS) on these compounds allowed to overcome the
main difficulties. This success motivated a rapidly growing scientific
community to apply this technique to high-temperature superconductors. This
paper reviews the experimental highlights obtained over the last decade. We
first recall the crucial efforts to gain control over the technique and to
obtain reproducible results. We then discuss how the STM/STS technique has
contributed to the study of some of the most unusual and remarkable properties
of high-temperature superconductors: the unusual large gap values and the
absence of scaling with the critical temperature; the pseudogap and its
relation to superconductivity; the unprecedented small size of the vortex cores
and its influence on vortex matter; the unexpected electronic properties of the
vortex cores; the combination of atomic resolution and spectroscopy leading to
the observation of periodic local density of states modulations in the
superconducting and pseudogap states, and in the vortex cores.Comment: To appear in RMP; 65 pages, 62 figure
Multiband model of high Tc superconductors
We propose an extension to other high T_{c } compounds of a model introduced
earlier for YBCO. In the ''self-doped'' compounds we assume that the doping
part (namely the BiO, HgO, TlO planes in BSCCO, HBCCO, TBCCO respectively) is
metallic, which leads to a multiband model. This assumption is supported by
band structure calculations. Taking a repulsive pairing interaction between
these doping bands and the CuO_{2} bands leads to opposite signs for the order
parameter on these bands and to nodes whenever the Fermi surfaces of these
bands cross. We show that in BSCCO the low temperature dependence of the
penetration depth is reasonably accounted for. In this case the nodes are not
located near the 45^{o} direction, which makes the experimental determination
of the node locations an important test for our model. The situation in HBCCO
and TBCCO is rather analogous to BSCCO. We consider the indications given by
NMR and find that they rather favor a metallic character for the doping bands.
Finally we discuss the cases of NCCO and LSCO which are not ''self-doped'' and
where our model does not give nodes.Comment: 11 pages, revtex, 1 figure
Valence Fluctuations Revealed by Magnetic Field Scan: Comparison with Experiments in YbXCu_4 (X=In, Ag, Cd) and CeYIn_5 (Y=Ir, Rh)
The mechanism of how critical end points of the first-order valence
transitions (FOVT) are controlled by a magnetic field is discussed. We
demonstrate that the critical temperature is suppressed to be a quantum
critical point (QCP) by a magnetic field. This results explain the field
dependence of the isostructural FOVT observed in Ce metal and YbInCu_4.
Magnetic field scan can lead to reenter in a critical valence fluctuation
region. Even in the intermediate-valence materials, the QCP is induced by
applying a magnetic field, at which the magnetic susceptibility also diverges.
The driving force of the field-induced QCP is shown to be a cooperative
phenomenon of the Zeeman effect and the Kondo effect, which creates a distinct
energy scale from the Kondo temperature. The key concept is that the closeness
to the QCP of the FOVT is capital in understanding Ce- and Yb-based heavy
fermions. It explains the peculiar magnetic and transport responses in CeYIn_5
(Y=Ir, Rh) and metamagnetic transition in YbXCu_4 for X=In as well as the sharp
contrast between X=Ag and Cd.Comment: 14 pages, 9 figures, OPEN SELECT in J. Phys. Soc. Jp
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