Assessment of mapping exposed ferrous and ferric iron compounds using Skylab-EREP data

The author has identified the following significant results. The S190B color photography is as useful as LANDSAT data for the mapping of color differences in the rocks and soils of the terrain. An S192 ratio of 0.79 - 0.89 and 0.93 - 1.05 micron bands produced an apparently successful delineation of ferrous, ferric, and other materials, in agreement with theory and ratio code studies. From an analysis of S191 data, basalt and dacite were separated on the basis of differences in spectral emissivity in the 8.3 - 12 micron region

Surface compositional mapping by spectral ratioing of ERTS-1 MSS data in the Wind River Basin and Range, Wyoming

The author has identified the following significant results. ERTS data collected in August and October 1972 were processed on digital and special purpose analog recognition computers using ratio enhancement and pattern recognition. Ratios of band-averaged laboratory reflectances of some minerals and rock types known to be in the scene compared favorably with ratios derived from the data by ratio normalization procedures. A single ratio display and density slice of the visible channels of ERTS MSS data, Channel 5/Channel 4 (R5,4), separated the Triassic Chugwater formation (redbeds) from other formations present and may have enhanced iron oxide minerals present at the surface in abundance. Comparison of data sets collected over the same area at two different times of the year by digital processing indicated that spectral variation due to environmental factors was reduced by ratio processing

Elastic constants of beta-eucryptite: A density functional theory study

The five independent elastic constants of hexagonal $\beta$-eucryptite have been determined using density functional theory (DFT) total energy calculations. The calculated values agree well, to within 15%, with the experimental data. Using the calculated elastic constants, the linear compressibility of $\beta$-eucryptite parallel to the c-axis, $\chi_c$, and perpendicular to it, $\chi_a$, have been evaluated. These values are in close agreement to those obtained from experimentally known elastic constants, but are in contradiction to the direct measurements based on a three-terminal technique. The calculated compressibility parallel to the c-axis was found to positive as opposed to the negative value obtained by direct measurements. We have demonstrated that $\chi_c$ must be positive and discussed the implications of a positive $\chi_c$ in the context of explaining the negative bulk thermal expansion of $\beta$-eucryptite.Comment: 3 eps figures, submitted for publicatio

Understanding and predicting metallic whisker growth and its effects on reliability : LDRD final report.

Tin (Sn) whiskers are conductive Sn filaments that grow from Sn-plated surfaces, such as surface finishes on electronic packages. The phenomenon of Sn whiskering has become a concern in recent years due to requirements for lead (Pb)-free soldering and surface finishes in commercial electronics. Pure Sn finishes are more prone to whisker growth than their Sn-Pb counterparts and high profile failures due to whisker formation (causing short circuits) in space applications have been documented. At Sandia, Sn whiskers are of interest due to increased use of Pb-free commercial off-the-shelf (COTS) parts and possible future requirements for Pb-free solders and surface finishes in high-reliability microelectronics. Lead-free solders and surface finishes are currently being used or considered for several Sandia applications. Despite the long history of Sn whisker research and the recently renewed interest in this topic, a comprehensive understanding of whisker growth remains elusive. This report describes recent research on characterization of Sn whiskers with the aim of understanding the underlying whisker growth mechanism(s). The report is divided into four sections and an Appendix. In Section 1, the Sn plating process is summarized. Specifically, the Sn plating parameters that were successful in producing samples with whiskers will be reviewed. In Section 2, the scanning electron microscopy (SEM) of Sn whiskers and time-lapse SEM studies of whisker growth will be discussed. This discussion includes the characterization of straight as well as kinked whiskers. In Section 3, a detailed discussion is given of SEM/EBSD (electron backscatter diffraction) techniques developed to determine the crystallography of Sn whiskers. In Section 4, these SEM/EBSD methods are employed to determine the crystallography of Sn whiskers, with a statistically significant number of whiskers analyzed. This is the largest study of Sn whisker crystallography ever reported. This section includes a review of previous literature on Sn whisker crystallography. The overall texture of the Sn films was also analyzed by EBSD. Finally, a short Appendix is included at the end of this report, in which the X-Ray diffraction (XRD) results are discussed and compared to the EBSD analyses of the overall textures of the Sn films. Sections 2, 3, and 4 have been or will be submitted as stand-alone papers in peer-reviewed technical journals. A bibliography of recent Sandia Sn whisker publications and presentations is included at the end of the report

Assessment of listing and categorisation of animal diseases within the framework of the Animal Health Law (Regulation (EU) No 2016/429): bluetongue

Non peer reviewe

Not all cows are epidemiologically equal:quantifying the risks of bovine viral diarrhoea virus (BVDV) transmission through cattle movements

International audienceMany economically important cattle diseases spread between herds through livestock movements. Traditionally, most transmission models have assumed that all purchased cattle carry the same risk of generating outbreaks in the destination herd. Using data on bovine viral diarrhoea virus (BVDV) in Scotland as a case example, this study provides empirical and theoretical evidence that the risk of disease transmission varies substantially based on the animal and herd demographic characteristics at the time of purchase. Multivariable logistic regression analysis revealed that purchasing pregnant heifers and open cows sold with a calf at foot were associated with an increased risk of beef herds being seropositive for BVDV. Based on the results from a dynamic within-herd simulation model, these findings may be partly explained by the age-related probability of animals being persistently infected with BVDV as well as the herd demographic structure at the time of animal introductions. There was also evidence that an epidemiologically important network statistic, "betweenness centrality" (a measure frequently associated with the potential for herds to acquire and transmit disease), was significantly higher for herds that supplied these particular types of replacement beef cattle. The trends for dairy herds were not as clear, although there was some evidence that open heifers and open lactating cows were associated with an increased risk of BVDV. Overall, these findings have important implications for developing simulation models that more accurately reflect the industry-level transmission dynamics of infectious cattle diseases

Electrodeposition of High Magnetostrictive Cobalt Iron Alloy Films for Smart Tags and Sensor Applications

Magnetostrictive CoFe films were investigated for use as magnetoelastic tags or sensors. The ability to electrodeposit these films enables batch fabrication processes to pattern a variety of geometries while controlling the film stoichiometry and crystallography. In current research looking at CoFe, improved magnetostriction was achieved using a co-sputtering, annealing, and quenching method1. Other current research has reported electrodeposited CoFe films using a sulfate based chemistry resulting in film compositions that are Fe rich in the range of Co0.3-0.4Fe0.7-0.6 and have problems of co-deposition of undesirables that can have a negative impact on magnetic properties2, 3. The research presented here focused on maximizing magnetostriction at the optimal stoichiometry range of Co0.7-0.75Fe0.3-0.25, targeting the (fcc+bcc)/bcc phase boundary, and using a novel chemistry and plating parameters to deposit films without being limited to line of sight\u27 deposition1. To obtain the desired compositional range, a chemistry was selected to allow for a higher ratio of Co while maintaining stability and limiting the oxidation of the Fe2+ to Fe3+. As suggested by Osaka et al., Fe(OH)3 is formed and included into the film resulting in a decrease of the saturation magnetic flux density (Bs) value as the Fe cation is oxidized2. This led to a deviation from the traditional sulfate based chemistry used to deposit CoFe alloy thin films and the inclusion of additives acting as oxygen scavengers to stabilize deposition. The characteristics of the deposited films were controlled through the additives, temperature, agitation, concentrations, current density, and duty cycle of the pulsing regime. After initial chemistry characterization to determine the kinetics and mass transfer limitations, samples were plated across a range of current densities and duty cycles onto copper tuning fork substrates that enabled magnetic testing to be performed. The samples were then analyzed with EDS to determine the composition. Magnetic testing was performed using super conducting quantum interference device measurements (SQUID), as well as visual inspection of the displacement on a deposit stress analyzer as a magnetic field was applied to the films. The magnetostriction was then correlated to stoichiometry and the plating parameters to characterize magnetostriction performance. Electrochemical studies were conducted to examine the kinetic rate for the reduction of the cobalt iron alloy as a function of additive concentrations. The oxygen scavenger additives were found to increase the kinetics while anodically shifting the reduction peak for the alloy. The leveling and brightening agents shifted the reduction peak cathodically and decreased the standard rate constant. Adjusting the concentration of ascorbic acid minimized the cathodic shift and decrease in the kinetic rate caused by the brightening additives.\u2

It’s All About M.E. (Motivation through (self) Evaluation)

Middle school is a paradox. Students want nothing more than autonomy, while classrooms become more structured and demanding. With the increased structure, however, are increased expectations for the students to determine what to do and when to do it, on their own. This rapid increase in personal responsibility creates confusion in an already tumultuous time in their lives, and a common retaliation, out of fear, apathy, or simply not knowing, is to do nothing. It is a given that students differ in their motivation to learn, and tapping each one of those sources becomes, in effect, a quest for the academic holy grail. Knowing that students are prone to confusion and certain gaps in their transitioning thought processes in middle school, and that kids respond readily to their own ideas, why not utilize a process of self-evaluation which lays out guidelines, but requires the responsibility to assess and improve their own work? This was the basis of my research. Utilizing portfolios, rubrics, and the multiple ability levels of my students, I wanted to see if this sort of guidance and awareness would effectively increase their intrinsic motivation