Strain-driven elastic and orbital-ordering effects on thickness-dependent properties of manganite thin films

We report on the structural and magnetic characterization of (110) and (001) La2/3Ca1/3MnO3 (LCMO) epitaxial thin films simultaneously grown on (110) and (001)SrTiO3 substrates, with thicknesses t varying between 8 nm and 150 nm. It is found that while the in-plane interplanar distances of the (001) films are strongly clamped to those of the substrate and the films remain strained up to well above t=100 nm, the (110) films relax much earlier. Accurate determination of the in-plane and out-of-plane interplanar distances has allowed concluding that in all cases the unit cell volume of the manganite reduces gradually when increasing thickness, approaching the bulk value. It is observed that the magnetic properties (Curie temperature and saturation magnetization) of the (110) films are significantly improved compared to those of (001) films. These observations, combined with 55Mn-nuclear magnetic resonance data and X-ray photoemission spectroscopy, signal that the depression of the magnetic properties of the more strained (001)LCMO films is not caused by an elastic deformation of the perovskite lattice but rather due to the electronic and chemical phase separation caused by the substrate-induced strain. On the contrary, the thickness dependence of the magnetic properties of the less strained (110)LCMO films are simply described by the elastic deformation of the manganite lattice. We will argue that the different behavior of (001) and (110)LCMO films is a consequence of the dissimilar electronic structure of these interfaces.Comment: 16 pages, 15 figure

Tunable dipolar magnetism in high-spin molecular clusters

We report on the Fe17 high-spin molecular cluster and show that this system is an exemplification of nanostructured dipolar magnetism. Each Fe17 molecule, with spin S=35/2 and axial anisotropy as small as D=-0.02K, is the magnetic unit that can be chemically arranged in different packing crystals whilst preserving both spin ground-state and anisotropy. For every configuration, molecular spins are correlated only by dipolar interactions. The ensuing interplay between dipolar energy and anisotropy gives rise to macroscopic behaviors ranging from superparamagnetism to long-range magnetic order at temperatures below 1K.Comment: Replaced with version accepted for publication in Physical Review Letter

Exciton effects in a scaling theory of intermediate valence and Kondo systems

An interplay of the Kondo scattering and exciton effects (d-f Coulomb interaction) in the intermediate valence systems and Kondo lattices is demonstrated to lead to an essential change of the scaling behavior in comparison with the standard Anderson model. In particular, a marginal regime can occur where characteristic fluctuation rate is proportional to flow cutoff parameter. In this regime the "Kondo temperature" itself is strongly temperature dependent which may give a key to the interpretation of controversial experimental data for heavy fermion and related systems.Comment: 4 pages, 4 figure

Inhomogeneous structure and magnetic properties of granular Co10Cu90 alloys

Granular Co10Cu90 alloys displaying giant magnetoresistance have been obtained by melt spinning followed by an appropriate heat treatment in the range 0-700 degreesC. Their structural and magnetic properties have been studied on a microscopic scale using Co-59 NMR technique and thermoremanent magnetization measurements. The study reveals that in the as-quenched samples Co is involved in two main structural components: small, irregular, strained Co particles (60% of the entire Co population) and a composition modulated CoCu alloy. A high modulation amplitude of the concentration profile in the alloy subdivides the latter in two parts with distinctly different properties. One part consists of ferromagnetic alloy (average Cu concentration of about 20%) with a blocking temperature of about 35 K (involving 6% of the entire Co population in a sample). The other part, containing the remaining 34% of the entire Co population, is a paramagnetic alloy with a blocking temperature below 4.2 K. The ferromagnetic alloy is magnetically soft-its transverse susceptibility is lower by a factor of 7 than the transverse susceptibility of the quenched-in Co particles. The latter population has a blocking temperature of about 150-200 K. During the heat treatment, each of the two main structural components undergoes respective decomposition processes: both of them display two temperature regimes. One process consists in dissolving the quenched-in Co particles after annealing at around 400 degreesC, followed at higher temperatures by a nucleation and growth of the more regular in shape Co particles. The other process resembles a spinodal decomposition of the quenched-in CoCu alloy, resulting in sharpening of the concentration profile and eventually leading to Co cluster formation in samples annealed above 450 degreesC. Both processes end at about T-ap = 700 degreesC, in formation of large, pure Co clusters that are ferromagnetic at least up to 400 K.63

Investigation of the thermal stability of Mg/Co periodic multilayers for EUV applications

We present the results of the characterization of Mg/Co periodic multilayers and their thermal stability for the EUV range. The annealing study is performed up to a temperature of 400\degree C. Images obtained by scanning transmission electron microscopy and electron energy loss spectroscopy clearly show the good quality of the multilayer structure. The measurements of the EUV reflectivity around 25 nm (~49 eV) indicate that the reflectivity decreases when the annealing temperature increases above 300\degreeC. X-ray emission spectroscopy is performed to determine the chemical state of the Mg atoms within the Mg/Co multilayer. Nuclear magnetic resonance used to determine the chemical state of the Co atoms and scanning electron microscopy images of cross sections of the Mg/Co multilayers reveal changes in the morphology of the stack from an annealing temperature of 305\degreee;C. This explains the observed reflectivity loss.Comment: Published in Applied Physics A: Materials Science \& Processing Published at http://www.springerlink.com.chimie.gate.inist.fr/content/6v396j6m56771r61/ 21 page

Electronic self-doping of Mo-states in A2FeMoO6 (A=Ca, Sr and Ba) half-metallic ferromagnets - a Nuclear Magnetic Resonance study

A systematic study of (A,A')2FeMoO6 (A,A'=Ca, Sr, Ba) ferromagnetic oxides with double perovskite structure has been performed using 95,97Mo and 57Fe NMR spectroscopy. These oxides are isoelectronic but have substantially different Curie temperatures. The NMR analysis provides clear evidence that the magnetic moment at Mo sites is not constant but varies sensitively with the ionic size of the alkaline ions. The 95,97Mo frequency, and thus the electronic charge at Mo ions, is found to be smaller in Ba and Ca than in Sr-based oxides. The charge release from Mo sites is accompanied by an uptake at Fe sites, and thus a self-doping Fe-Mo process is observed. This process is controlled by relevant structural parameters: the Fe-O-Mo bond length and bending. A clear relationship between the Curie temperature and the magnetic moment and thus electron density at Mo sites has been disclosed. The relevance of these findings for the understanding of ferromagnetic coupling in double perovskites is discussed.Comment: 26 pages, 8 figure

2D to 3D crossover of the magnetic properties in ordered arrays of iron oxide nanocrystals

The magnetic 2D to 3D crossover behavior of well-ordered arrays of monodomain gamma-Fe2O3 spherical nanoparticles with different thicknesses has been investigated by magnetometry and Monte Carlo (MC) simulations. Using the structural information of the arrays obtained from grazing incidence small-angle X-ray scattering and scanning electron microscopy together with the experimentally determined values for the saturation magnetization and magnetic anisotropy of the nanoparticles, we show that MC simulations can reproduce the thickness-dependent magnetic behavior. The magnetic dipolar particle interactions induce a ferromagnetic coupling that increases in strength with decreasing thickness of the array. The 2D to 3D transition in the magnetic properties is mainly driven by a change in the orientation of the magnetic vortex states with increasing thickness, becoming more isotropic as the thickness of the array increases. Magnetic anisotropy prevents long-range ferromagnetic order from being established at low temperature and the nanoparticle magnetic moments instead freeze along directions defined by the distribution of easy magnetization directions

N. M. R. STUDIES OF Ni CONCENTRATED ALLOYS NEAR THE MAGNETIC CRITICAL CONCENTRATION

Dans cet article, nous présentons de nouvelles mesures de R. M. N. dans les alliages concentrés NicCu (Ccr ~ 46 %) et NicV (Ccr ~ 87,5 %) qui montrent l'importance des effets d'environnement dans les alliages concentrés proches de la transition de l'état paramagnétique à l'état ferromagnétique. Nous montrons que la différence quantitative entre les valeurs de la concentration critique (Ccr) dans ces deux types d'alliages entraîne des différences notables entre les propriétés du cuivre et du vanadium : les atomes de vanadium (statistiquement isolés ou en paires, dans leur majorité) sont beaucoup plus sensibles aux interactions avec les atomes magnétiques que les atomes de cuivre qui statistiquement ont, en majorité, 5, 6 ou 7 atomes de cuivre premiers voisins (dans la zone critique de transition). En particulier, le Knight shift et la largeur de raie du V51 varient avec la température comme (T – θ)-1 où θ est très proche de la température de Curie de l'alliage, tandis que la température caractéristique des variations en (T – θ)-1 des propriétés du cuivre est négative et sans relation avec la température d'ordre de l'alliage. Nous analysons ces effets d'environnement local dans les alliages NicV en séparant les contributions, au spectre R. M. N. de V51, des atomes isolés, des paires isolées et des atomes inclus dans de plus gros amas de vanadium : nous montrons alors que la susceptibilité locale d'un atome de vanadium décroît fortement lorsque le nombre d'atomes de vanadium augmente dans son voisinage.In this paper we present new N. M. R. measurements in NicCu (Ccr ~ 46 %) and NicV (Ccr ~ 87.5 %) which show the importance of the environment effects in concentrated alloys near the paramagnetic-ferromagnetic transition. We show that in these two types of alloys the V and Cu properties are quite different from the different values of the critical concentration (Ccr) : namely, the V atoms (most probably isolated or paired in the Ccr range) are much more sensitive to the interactions with magnetic atoms than Cu atoms which have statistically about 5, 6 or 7 Cu nearest neighbours in the Ccr range. Particularly, the temperature dependences of the V51 Knight shift and line width are Curie Weiss like with a characteristic temperature close to the Curie temperature of the alloys ; on the contrary the characteristic temperature of the Curie Weiss temperature variations of the Cu properties is negative and is not related to the ordering temperature. We analyse such local environment effects in the NiV alloys by separating the contributions to the V51 N. M. R. line of the isolated V atom, of the isolated V pairs and of the V atoms embedded in larger V groups : the local susceptibility of a V atom is shown to decrease strongly when the number of V nearest neighbours increases