U-Pb geochronology of the El Jadida rhyolite and relation to possible Lower Cambrian recycling (Coastal block, Moroccan Meseta).

The El Jadida (Mazagan) dome, whose existence was reported as early as 1934 by Yovanovitch and Freys, constitutes one of the first outcrops of the Moroccan Meseta where the Precambrian (PIII?)-Paleozoic (Lower Cambrian?) boundary was established (Gigout, 1951; Cornée et al., 1984). Since then, it is listed as one of the few locations where the basement of the Moroccan Variscan belt can be observed (Hoepffner et al.. 2005; Michard et al., 2010).Despite, the absence of geochronological and biostratigraphic precise data to constrain the time interval recorded here, there are stratigraphic similarities that allow a correlation with the Ediacaran-Cambrian geological record of Anti-Atlas belt (Cornée et al., 1984). In this study, we developed a petrographic, geochemical and U-Pb geochronological study using zircon extracted from: (i) the El Jadida rhyolite with the aim of characterizing the magma source and estimate the age of crystallization; (ii) a microbreccia sampled at the base of the El Jadida Dolomitic Formation for determining provenance

Sedimentary provenance of siliciclastic rocks from the Lalla Mouchaa Calcschists Formation (Coastal Block, Western Rehamna): Evidence of denudation of ca. 2 Ga basement in the Moroccan Meseta.

Paleoproterozoic basement rocks (ca. 2Ga) are scarce along the European and North African Paleozoic mountain chains (Fig.1a). In Morocco, ca. 2.2-2Ga granitic rocks (Gasquet et al., 2008; Kouyaté et al., 2013) have been exclusively reported in the Western Anti-Atlas at southwest of the Anti-Atlas Major Fault, (Choubert, 1963). In Eastern and Central Anti-Atlas and in the Moroccan Meseta, the existence of a Paleoproterozoic basement has only been recognized through indirect evidence (Gasquet et al., 2008; Michard et al., 2010). In the Anti- Atlas belt, ca. 2Ga detrital zircon grains are found in the Ediacaran siliciclastic rocks of the Bou Salda, Saghro and Taghdout groups (Abati et al., 2010). In the Moroccan Meseta, Paleoproterozoic (ca. 2Ga) zircon grains were extracted from gneiss and granitic xenoliths found in Triassic lamprophyre dykes, and from Carboniferous granophyric microgranite intrusions of central Jebilet (Dostal et al., 2005, Essaifi et al., 2003). Recently, a porphyritic rhyolite from the Rehamna Massif was dated at ca. 2.05Ga (Pereira et al., 2015), demonstrating for the first time, the exposure of the Eburnian basement in the Western Meseta. These Eburnian arc-related magmatic rocks, which are exposed to the south of the Permian Sebt Brikiyine granite in the core of anticlines from the Lalla Mouchaa Anticlinorium, are allegedly unconformably overlained by transgressive siliciclastic and carbonate beds (Corsini, 1988; Pereira et al., 2015). At north of the Sebt Brikiyine granite the probable Lower Cambrian sequence (Lalla Mouchaa Calcschists Formation; Guezou & Michard, 1976; Corsini, 1988) comprises a basal unit of microbreccias, arkosic sandstones and siltstones (lower member) that pass towards the top to centimeter-thick beds of calcschists interbedded with limestones and dolomites (upper member) that are conformably overlain by the “Paradoxides Shale Formation” composed of siltstone, greywacke and sandstone with Middle Cambrian fauna. In order to study the potential sources of the Lalla Mouchaa Calcschists Formation (probable Lower Cambrian), we have sampled a microbreccia at the Koudiat El Hamra region, for U-Pb geochronology on detrital zircon. This foliated microbreccia is composed of elongated Kfeldspar and quartz phenocrysts surrounded by a fine-grained matrix. Detrital zircon grains gave 206Pb/238Ub ages that in the Probability density plot curve are distributed by two main age peaks at ca. 2.05Ga and ca. 2.03Ga (Fig.1b), yielding a 206Pb/238U age-weighted mean of ca. 2.04Ga (El Houicha et al., 2018). The obtained U-Pb results point to a provenance from a Paleoproterozoic source, suggesting a possible contribution from rocks of the same age of the 2Ga porphyritic rhyolite exposed at south of the Sebt Brikiyine granite. Thus, there is a possibility that the Paleoproterozoic basement extends bellow the Paleozoic and Neoproterozoic sequences of the Rehamna massif

Recycling of the Proterozoic crystalline basement in the Coastal Block (Moroccan Meseta): New insights for understanding the geodynamic evolution of the northern peri-Gondwanan realm

Detrital zircon age spectra from the siliciclastic rocks of the Lalla Mouchaa Calcschists and El Jadida Dolomitic formations (the Coastal Block of the Moroccan Meseta) are dominated by Paleoproterozoic and Ediacaran ages. The provenance of these two formations is a composite Proterozoic crystalline basement. El Jadida rhyolite (584.2 ± 4.8 Ma) represents the Ediacaran crystalline basement of the El Jadida dome. El Jadida rhyolite is unconformably overlain by the microbreccia, arkosic sandstone and dolostone of the El Jadida Dolomitic Formation with a maximum depositional age of ca. 539 Ma (Lower Cambrian). Detrital zircon-age spectra from El Jadida Dolomitic Formation (ca. 583–582 Ma) suggest direct recycling of El Jadida rhyolite as an exclusive original primary source. However, in the Western Rehamna massif, detrital zircon-age spectra from pre-Middle Cambrian microbreccia and arkosic sandstone of the Lalla Mouchaa Calcschists Formation (ca. 2.05–2.03 Ga) indicate exclusive recycling of the ca. 2.05 Ga-aged crystalline basement rocks (original primary source). Detrital zircon contents of the siliciciclastic rocks from these two formations of the Coastal Block are consistent with derivation from either Eburnian (Paleoproterozoic) or Cadomian/Pan-African (Ediacaran) igneous rocks. The discovery of this composite Proterozoic crystalline basement in the Moroccan Meseta stresses that Cadomian/ Pan-African magmatic arcs were built on an Eburnian basement in a paleoposition close to the West African craton, as part of the northern peri-Gondwanan realm

Algebraic tools for the study of quaternionic behavioral systems

In this paper we study behavioral systems whose trajectories are given as solutions of quaternionic difference equations. As happens in the commutative case, it turns out that quaternionic polynomial matrices play an important role in this context. Therefore we pay special attention to such matrices and derive new results concerning their Smith form. Based on these results, we obtain a characterization of system theoretic properties such as controllability and stability of a quaternionic behavior

Light-Front Model of Transition Form-Factors in Heavy Meson Decay

Electroweak transition form factors of heavy meson decays are important ingredients in the extraction of the Cabibbo-Kobayashi-Maskawa (CKM) matrix elements from experimental data. In this work, within a light-front framework, we calculate electroweak transition form factor for the semileptonic decay of $D$ mesons into a pion or a kaon. The model results underestimate in both cases the new data of CLEO for the larger momentum transfers accessible in the experiment. We discuss possible reasons for that in order to improve the model.Comment: Paper with 5 pages and 2 eps figures. To appear to Nuclear Physics B. Talk at Light Cone 2009: Relativistic Hadronic and Particle Physics (LC 2009), Sao Jose dos Campos, S.P, Brazil, 8-13 Jul 2009

Corrosion Damage Analysis and Material Characterization of Sherman and Centaur - The Historic Military Tanks

A study of corrosion damage and material characterization of two historic military tanks, the Sherman and Centaur is reported. Experiments were conducted to analyse surface corrosion and corrosion propagation from surface to sub-surface. Significant surface corrosion was found, this phenomenon was further facilitated by delamination failure mechanisms. Corrosion depth for the Sherman was approximately 110 µm, where sulphide inclusions were detected in the sub-surface analysis. The Centaur’s analysis showed corrosion pits at 100 µm depth. These pits possess random geometrical configurations with evidence of sulfur, sodium and calcium

Stability of methylphenidate under various ph conditions in the presence or absence of gut microbiota

Methylphenidate is one of the most widely used oral treatments for attention-deficit/hyperactivity disorder (ADHD). The drug is mainly absorbed in the small intestine and has low bioavailability. Accordingly, a high interindividual variability in terms of response to the treatment is known among ADHD patients treated with methylphenidate. Nonetheless, very little is known about the factors that influence the drug’s absorption and bioavailability. Gut microbiota has been shown to reduce the bioavailability of a wide variety of orally administered drugs. Here, we tested the ability of small intestinal bacteria to metabolize methylphenidate. In silico analysis identified several small intestinal bacteria to harbor homologues of the human carboxylesterase 1 enzyme responsible for the hydrolysis of methylphenidate in the liver into the inactive form, ritalinic acid. Despite our initial results hinting towards possible bacterial hydrolysis of the drug, up to 60% of methylphenidate is spontaneously hydrolyzed in the absence of bacteria and this hydrolysis is pH-dependent. Overall, our results indicate that the stability of methylphenidate is compromised under certain pH conditions in the presence or absence of gut microbiota

New U-Pb zircon dating of Late Neoproterozoic magmatism in Western Meseta (Morocco)

We present new U-Pb zircon ages from magmatic rocks of the Western Meseta, part of the Moroccan Variscan belt. The Neoproterozoic–Cambrian stratigraphy in the region of Goäida (Aguelmous massif, SE of Moroccan Central Massif) consists of limestones with conglomeratic and felsic volcaniclastic levels, pelites and mafic volcanic rocks assigned to the Cambrian which unconformably overlie rhyolites, andesites and rhyodacites and felsic tuffs associated with the Aguelmous granite of probable Neoproterozoic age. The Neoproterozoic–Cambrian stratigraphy of the region of Sidi Ali is roughly similar and also includes a volcanic-sedimentary complex with limestones, arkoses rhyolites and conglomerates. These conglomerates contain pebbles of granite and rhyolite, whose source may be the Neoproterozoic basement. In order to constrain the age of the Precambrian felsic magmatism we sampled and dated zircons (LA-ICPMS) from the Goäida granite and a pebble of granite included in the conglomeratic levels of the volcanicsedimentary complex at Sidi Ali dome (central Rehamna massif). In the Goäida granite, zircon ages are Ediacaran ranging between ~ 610 Ma and ~ 540 Ma, with a discordia upper intercept age of 598±32 Ma (MSWD=0.04) that could be interpreted as the age of intrusion. However, if we consider only the two youngest ages we obtain a Concordia age of 590±3 Ma (MSWD= 0.34). In the Sidi Ali pebble sample the majority of zircon ages are Cryogenian–Ediacaran in the range ~ 640–600 Ma, with the youngest yielding a Concordia age of 609±2 Ma (MSWD=0.04), indicating the intrusion age of the granite from which the pebble derived. These results support the existence of Cadomian/Pan-African magmatism in the Western Meseta of Morocco, characterized by the intrusion of granites at ~ 609 Ma and ~ 590 Ma. This result is important for studies of sedimentary provenance and to improve paleogeographic reconstructions of the northern margin of Gondwana during the Neoproterozoic

A Graphical Tool and Methods for Assessing Margin Definition From Daily Image Deformations

Estimating the proper margins for the planning target volume (PTV) could be a challenging task in cases where the organ undergoes significant changes during the course of radiotherapy treatment. Developments in image-guidance and the presence of onboard imaging technologies facilitate the process of correcting setup errors. However, estimation of errors to organ motions remain an open question due to the lack of proper software tools to accompany these imaging technological advances. Therefore, we have developed a new tool for visualization and quantification of deformations from daily images. The tool allows for estimation of tumor coverage and normal tissue exposure as a function of selected margin (isotropic or anisotropic). Moreover, the software allows estimation of the optimal margin based on the probability of an organ being present at a particular location. Methods based on swarm intelligence, specifically Ant Colony Optimization (ACO) are used to provide an efficient estimate of the optimal margin extent in each direction. ACO can provide global optimal solutions in highly nonlinear problems such as margin estimation. The proposed method is demonstrated using cases from gastric lymphoma with daily TomoTherapy megavoltage CT (MVCT) contours. Preliminary results using Dice similarity index are promising and it is expected that the proposed tool will be very helpful and have significant impact for guiding future margin definition protocols

Poly[piperazine-1,4-diium [μ4-chlorido-μ3-chlorido-tri-μ2-chlorido-chloridodicadmate(II)] monohydrate]

In the title compound, {(C5H14N2)[Cd2Cl6]·H2O}n, the asymmetric unit contains one piperazinediium cation, one [Cd2Cl6]2− anion and a water mol­ecule. The coordination geometries of the two Cd2+ cations are distorted octa­hedral. Adjacent CdII atoms are inter­connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chains are connected by O—H⋯Cl hydrogen bonds involving the water mol­ecules, forming layers at z = n/2. The crystal packing is further stabilized by inter­molecular N—H⋯Cl and N—H⋯O hydrogen bonds, one of which is bifurcated