SIGNIFICAN ENHANCEMENT OF OPTICAL PROPERTIES THROUGH METHYLCELLULOSE (MC) / GADOLINIUM OXIDE COMPOSITES

In the present work, Methylcellulose (MC) with Gd2O3 composite films were prepared to study the optical properties. and investigate the effect of adding Gd2O3 nanoparticles with MC in linear optical investigation.W.I.A. and I.I.N. thank Department, Faculty of Science, Tanta University, for financial support

Characterization of Excessive Sm3+containing Barium Titanate Prepared by Tartrate Precursor Method

The [Formula presented](BST) samples, where (x = zero, 0.05, 0.1, 0.15, 0.2 and 0.3), have been successfully synthesized by tartrate precursor method at annealing temperature of 600°C under atmospheric pressure. The results revealed that the Sm content causes a decrease in both tetragonality and average grain size of BST samples. The electrical resistivity of BST samples is improved by low Sm content, reaching maximum value at x = 0.15 and then decreases with higher Sm content, suggesting that the conduction has two types of polaron hoping and semiconductor band conduction mechanisms at low and at high temperature ranges, respectively. It is demonstrated that the majority of charge carriers are p-type. The dielectric properties varies nonmonotonically with samarium content, showing strongly enhancement in dielectric constant for high Sm doping samples. It is recommended that BST samples are attractive for capacitor and energy storage applications. © 2020 The Author(s).This project was supported financially by the Academy of Scientific Research and Technology (ASRT) Egypt, Grant No. 6550 . ASRT is the 2nd affiliation of this research

Modified Copper Zinc Ferrite Nanoparticles Doped with Zr Ions for Hyperthermia Applications

The problem of the present work is to synthesize a nanomagnetic material with low TC below 45 °C and its particle size below 30 nm to be appropriate material for convert magnetic loss into heat energy. A series of Cu0.4Zn0.6+yZryFe2–2yO4 nanoparticles compositions where y = (0.05, 0.1) were synthesized via citrate sol–gel method. The prepared samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The grains were observed from SEM confirming the crystalline structure of the ferrite which was detected by X-ray diffraction. Magnetic hysteresis loop measurements illustrate that materials exhibit soft magnetic properties at low Zr content, while at higher Zr content all materials behave as superparamagnetically without any saturation magnetization Ms. The initial magnetic permeability (μi) at frequency 10 kHz as a function of temperature was measured. A sudden change in μi appears around Curie temperature, making our samples good candidates for magnetic temperature transducer (MTT) devices. The DC resistivity for sample at y = 0.05, 0.1 was studied. The resistivity decreases linearly with increasing temperature within the given range of temperature up to 666 K for all samples. The dielectric constant of all samples is nearly independent on temperature through the range of 450 to 600 K which is a common character of ferrites. The dielectric loss was found to increase by increasing temperature, which may be related to the increase in AC conductivity. Hyperthermia measurements show the maximum specific power loss and temperature increase were 26 w/gr and 43 °C, respectively, for sample containing Zr = 0.05, after 2 min of measurements. One of the real applications of the material is that it is used as an effective method in tumor treatment by exposing the patient to external magnetic field. © 2022, The Author(s).This project was supported finically by the Academy of Scientific Research and Technology (ASRT), Egypt, Grant No. (6550), which is the 2nd affiliation of this research. Funding. Open access funding provided by The Science, Technology & Innovation Funding Authority (STDF) in cooperation with The Egyptian Knowledge Bank (EKB)

RADIATION SHIELDING PROPERTIES OF METHYLCELLULOSE (MC)/GADOLINIUM OXIDE COMPOSITES

In the present work, the influence of weight percentages of Gd2O3 content (10%-30%) of reinforced MC composites in their photon absorption capabilities for photon energies, ranging from 0.01 to 3 MeV, were investigated. MC with Gd2O3 composite films was prepared via a solution casting method

Docking of COVID-19 main protease and TD-DFT/DMOl3 simulated method, synthesis, and characterization with hybrid nanocomposite thin films and its applications

Using the precipitation polymerization method copolymer poly methyl methacrylate co acrylonitrile was synthesized. Hybrid nanocomposite thin films [P(MMA-co-AN)/ZnO]HNC were prepared using the dip casting method by adding ZnO nanoparticles by the ratios 0.25, 0.20, 0.15, and 0.10 according to the weight of P(MMA-co-AN). Fourier Transform Infrared Spectroscopy (FTIR), UV–Vis optical properties, and laser photoluminescence PL characterization techniques were used to study [P(MMA-co-AN)/ZnO]HNC films. In addition, density functional theory (DFT), optimization via TD-DFTD/Mol3, and Cambridge Serial Total Energy Bundle (TD-FDT/CASTEP) were used to perform the geometrical study. FTIR spectra from [P(MMA-co-AN)/ZnO]HNC indicates the interaction between the copolymer and ZnO nanoparticles. In the wavelength range of 190 – 800 nm, the optical properties of [P(MMA-co-AN)/ZnO]HNC were considered. The direct energy band gap was found to be changed from 4.1 eV for P (MMA – co – AN) to 3.19 eV for 0.25 ZnO, while the concentration of 0.20 ZnO was the highest in the Urbach energy with 0.17 eV. The refractive index nλ=700 ranges from 1.48 to 1.81 for the concentration of 0.15 ZnO. Three emission peaks at 393 nm, 527 nm, and 775 nm were figured in the laser photoluminescence spectra of [P(MMA-co-AN)/ZnO]HNC films. In order to attain the restrained action of studied ligands (hybrid nanocomposite) novel coronavirus (COVID 19) main protest (6LU7) molecular docking studies were performed. The predicted energy gab by TD-DFT/DMOl3 was found to be agreed with the experimental data in a good manner. © 2023 Elsevier B.V

FERROELECTRIC AND DIELECTRIC PROPERTIES OF STRONTIUM TITANATE DOPED WITH BARIUM

The present work aimed to synthesized ferroelectric (perovskite) material. Structural, morphological, electrical and Polarization-Electric field hysteresis loops were investigated.W.I.A. and I.I.N. thank Minobrnauki research project FEUZ-2020-0059 for financial support

Structure, Morphology and Electrical/Magnetic Properties of Ni-Mg Nano-Ferrites from a New Perspective

Using the auto combustion flash method, Ni1−x+2 Mg+2xFe+32O4 (x = 0, 0.2, 0.6, 0.8 and 1) nano-ferrites were synthesized. All samples were thermally treated at 973 K for 3 h. The structural analysis for the synthesized samples was performed using XRD, high-resolution transmission electron microscopy (HRTEM), and FTIR. Scanning electron microscopy (SEM) was undertaken to explore the surface morphology of all the samples. The thermal stability of these samples was investigated using thermogravimetric analysis (TGA). XRD data show the presence of a single spinel phase for all the prepared samples. The intensity of the principal peak of the spinel phase decreases as Mg content increases, showing that Mg delays crystallinity. The Mg content raised the average grain size (D) from 0.084 µm to 0.1365 µm. TGA shows two stages of weight loss variation. The vibrating sample magnetometer (VSM) measurement shows that magnetic parameters, such as initial permeability (µi) and saturation magnetization (Ms), decay with rising Mg content. The permeability and magnetic anisotropy at different frequencies and temperatures were studied to show the samples’ magnetic behavior and determine the Curie temperature (TC), which depends on the internal structure. The electrical resistivity behavior shows the semi-conductivity trend of the samples. Finally, the dielectric constant increases sharply at high temperatures, explained by the increased mobility of charge carriers, and decreases with increasing frequency. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.Princess Nourah Bint Abdulrahman University, PNU: PNURSP2022R28The authors express their gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2022R28), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia

Global economic burden of unmet surgical need for appendicitis

Background: There is a substantial gap in provision of adequate surgical care in many low-and middle-income countries. This study aimed to identify the economic burden of unmet surgical need for the common condition of appendicitis. Methods: Data on the incidence of appendicitis from 170 countries and two different approaches were used to estimate numbers of patients who do not receive surgery: as a fixed proportion of the total unmet surgical need per country (approach 1); and based on country income status (approach 2). Indirect costs with current levels of access and local quality, and those if quality were at the standards of high-income countries, were estimated. A human capital approach was applied, focusing on the economic burden resulting from premature death and absenteeism. Results: Excess mortality was 4185 per 100 000 cases of appendicitis using approach 1 and 3448 per 100 000 using approach 2. The economic burden of continuing current levels of access and local quality was US $92 492 million using approach 1 and$73 141 million using approach 2. The economic burden of not providing surgical care to the standards of high-income countries was $95 004 million using approach 1 and$75 666 million using approach 2. The largest share of these costs resulted from premature death (97.7 per cent) and lack of access (97.0 per cent) in contrast to lack of quality. Conclusion: For a comparatively non-complex emergency condition such as appendicitis, increasing access to care should be prioritized. Although improving quality of care should not be neglected, increasing provision of care at current standards could reduce societal costs substantially

Laparoscopy in management of appendicitis in high-, middle-, and low-income countries: a multicenter, prospective, cohort study.

BACKGROUND: Appendicitis is the most common abdominal surgical emergency worldwide. Differences between high- and low-income settings in the availability of laparoscopic appendectomy, alternative management choices, and outcomes are poorly described. The aim was to identify variation in surgical management and outcomes of appendicitis within low-, middle-, and high-Human Development Index (HDI) countries worldwide. METHODS: This is a multicenter, international prospective cohort study. Consecutive sampling of patients undergoing emergency appendectomy over 6 months was conducted. Follow-up lasted 30 days. RESULTS: 4546 patients from 52 countries underwent appendectomy (2499 high-, 1540 middle-, and 507 low-HDI groups). Surgical site infection (SSI) rates were higher in low-HDI (OR 2.57, 95% CI 1.33-4.99, p = 0.005) but not middle-HDI countries (OR 1.38, 95% CI 0.76-2.52, p = 0.291), compared with high-HDI countries after adjustment. A laparoscopic approach was common in high-HDI countries (1693/2499, 67.7%), but infrequent in low-HDI (41/507, 8.1%) and middle-HDI (132/1540, 8.6%) groups. After accounting for case-mix, laparoscopy was still associated with fewer overall complications (OR 0.55, 95% CI 0.42-0.71, p < 0.001) and SSIs (OR 0.22, 95% CI 0.14-0.33, p < 0.001). In propensity-score matched groups within low-/middle-HDI countries, laparoscopy was still associated with fewer overall complications (OR 0.23 95% CI 0.11-0.44) and SSI (OR 0.21 95% CI 0.09-0.45). CONCLUSION: A laparoscopic approach is associated with better outcomes and availability appears to differ by country HDI. Despite the profound clinical, operational, and financial barriers to its widespread introduction, laparoscopy could significantly improve outcomes for patients in low-resource environments. TRIAL REGISTRATION: NCT02179112

Pooled analysis of WHO Surgical Safety Checklist use and mortality after emergency laparotomy

Background The World Health Organization (WHO) Surgical Safety Checklist has fostered safe practice for 10 years, yet its place in emergency surgery has not been assessed on a global scale. The aim of this study was to evaluate reported checklist use in emergency settings and examine the relationship with perioperative mortality in patients who had emergency laparotomy. Methods In two multinational cohort studies, adults undergoing emergency laparotomy were compared with those having elective gastrointestinal surgery. Relationships between reported checklist use and mortality were determined using multivariable logistic regression and bootstrapped simulation. Results Of 12 296 patients included from 76 countries, 4843 underwent emergency laparotomy. After adjusting for patient and disease factors, checklist use before emergency laparotomy was more common in countries with a high Human Development Index (HDI) (2455 of 2741, 89.6 per cent) compared with that in countries with a middle (753 of 1242, 60.6 per cent; odds ratio (OR) 0.17, 95 per cent c.i. 0.14 to 0.21, P <0001) or low (363 of 860, 422 per cent; OR 008, 007 to 010, P <0.001) HDI. Checklist use was less common in elective surgery than for emergency laparotomy in high-HDI countries (risk difference -94 (95 per cent c.i. -11.9 to -6.9) per cent; P <0001), but the relationship was reversed in low-HDI countries (+121 (+7.0 to +173) per cent; P <0001). In multivariable models, checklist use was associated with a lower 30-day perioperative mortality (OR 0.60, 0.50 to 073; P <0.001). The greatest absolute benefit was seen for emergency surgery in low- and middle-HDI countries. Conclusion Checklist use in emergency laparotomy was associated with a significantly lower perioperative mortality rate. Checklist use in low-HDI countries was half that in high-HDI countries.Peer reviewe