Control of Phragmites communis using low rate glyphosate applications and TopFilm adjuvant

An experiment to test the hypothesis that the addition of TopFilm adjuvant would reduce the effective concentration of glyphosate required to control Phragmites communis, the common reed

Electromagnetic Fields of Separable Space-Times

Carter derived the forms of the metric and the vector potentials of the space-times in which the relativistic Schrodinger equation for the motion of a charged particle separates. Here we show that on each `spheroidal' surface a rotation rate exists such that relative to those rotating axes the electric and magnetic fields are parallel and orthogonal to the spheroid which is thus an equipotential in those axes. All the finite Carter separable systems without magnetic monopoles or gravomagnetic NUT monopoles have the same gyromagnetic ratio as the Dirac electron.Comment: 9 pages; accepted for publication in Class. Quantum Gra

Analysis of the cercosporin polyketide synthase CTB1 reveals a new fungal thioesterase function

The polyketide synthase CTB1 is demonstrated to catalyze pyrone formation thereby expanding the known biosynthetic repertoire of thioesterase domains in iterative, non-reducing polyketide synthases

Healthcare choice: Discourses, perceptions, experiences and practices

Policy discourse shaped by neoliberal ideology, with its emphasis on marketisation and competition, has highlighted the importance of choice in the context of healthcare and health systems globally. Yet, evidence about how so-called consumers perceive and experience healthcare choice is in short supply and limited to specific healthcare systems, primarily in the Global North. This special issue aims to explore how choice is perceived and utilised in the context of different systems of healthcare throughout the world, where choice, at least in policy and organisational terms, has been embedded for some time. The articles are divided into those emphasising: embodiment and the meaning of choice; social processes associated with choice; the uncertainties, risks and trust involved in making choices; and issues of access and inequality associated with enacting choice. These sociological studies reveal complexities not always captured in policy discourse and suggest that the commodification of healthcare is particularly problematic

Mapping the Association of Global Executive Functioning Onto Diverse Measures of Psychopathic Traits

Psychopathic individuals display a callous-coldhearted approach to interpersonal and affective situations and engage in impulsive and antisocial behaviors. Despite early conceptualizations suggesting that psychopathy is related to enhanced cognitive functioning, research examining executive functioning (EF) in psychopathy has yielded few such findings. It is possible that some psychopathic trait dimensions are more related to EF than others. Research using a 2-factor or 4-facet model of psychopathy highlights some dimension-specific differences in EF, but this research is limited in scope. Another complicating factor in teasing apart the EF–psychopathy relationship is the tendency to use different psychopathy assessments for incarcerated versus community samples. In this study, an EF battery and multiple measures of psychopathic dimensions were administered to a sample of male prisoners (N

Do on-farm natural, restored, managed and constructed wetlands mitigate agricultural pollution in Great Britain and Ireland?: a systematic review

Wetlands in agricultural landscapes offer a number of benefits to the landscape function in which they are set, reducing nutrient runoff, providing additional habitat mosaics and offering various ecosystem services. They require careful planning and maintenance in order to perform their optimum design function over a prolonged period of time. They should be treated as functional units of farm infrastructure rather than fit-and-forget systems. A high priority topic within the Department for Environment, Food and Rural Affairs (DEFRA) water quality programme is the mitigation of pollution from agriculture. This programme was set up to meet the requirements of the European Water Framework Directive (WFD) EU (2000). Nutrient loss from agricultural land has been suggested as a major cause of elevated nutrient concentrations in surface waters in the UK. Nitrogen (N) and phosphorus (P) are of particular concern as an excess of either nutrient can lead to eutrophication of freshwater systems and coastal waters. Agriculture has also been identified as a significant source of suspended sediment (SS) concentrations in UK rivers and agriculturally derived sediment has been identified as a source of increased bed-sediment P concentrations in rivers. High bed sediments loads have other negative impacts, such as clogging river gravels reducing fish spawning. There is considerable evidence in the published and grey literature that wetlands have the ability to remove nutrients and sediment and thus reduce the load on receiving waters. Wetlands have also been reported to perform other ecosystem services, such as reducing floods, supporting biodiversity and sequestering carbon. A policy to promote the conservation, management, restoration or construction of wetlands could help to mitigate the impacts of N, P and SS from agriculture delivering requirements of WFD through Catchment Sensitive Farming following an Ecosystem Approach and Catchment Based Approach promoted by Defra. It could also meet other commitments such as implementing the Ramsar and Biodiversity Conventions to which the UK is a signatory. However, the term wetlands covers a wide range of habitat types and it is important that policy makers are provided with accurate, robust and independently reviewed information on the degree to which different types of wetland perform these services under different circumstances, so that policy can most best targeted. This systematic review assesses the available evidence on the performance of various wetland types on farms to reduce nutrient input and suspended sediments to receiving waters. It provides a defensible evidence base on which to base policy. The studies reviewed cover different input loads and the analysis compares performance of these wetland systems in respect of % reduction efficiency. In England and Wales, Defra, working closely with the Environment Agency and Natural England, has commissioned this systematic review on how effective, and what influences the effectiveness of wetlands at mitigating N, P and SS inputs from agriculture to receiving freshwater in the United Kingdom and Ireland

Concerted reductive coupling of an alkyl chloride at Pt(IV)

Oxidation of a doubly cyclometallated platinum(II) complex results in two isomeric platinum(IV) complexes. Whereas the trans isomer is robust, being manipulable in air at room temperature, the cis isomer decomposes at −20 °C and above. Reductive coupling of an alkyl chloride at the cis isomer gives a new species which can be reoxidised. The independence of this coupling on additional halide rules out the reverse of an SN2 reaction, leaving a concerted process as the only sensible reaction pathway

Stellar Mass--Gas-phase Metallicity Relation at 0.5≤z≤0.70.5\leq z\leq0.7: A Power Law with Increasing Scatter toward the Low-mass Regime

We present the stellar mass ($M_{*}$)--gas-phase metallicity relation (MZR) and its scatter at intermediate redshifts ($0.5\leq z\leq0.7$) for 1381 field galaxies collected from deep spectroscopic surveys. The star formation rate (SFR) and color at a given $M_{*}$ of this magnitude-limited ($R\lesssim24$ AB) sample are representative of normal star-forming galaxies. For masses below $10^9 M_\odot$, our sample of 237 galaxies is $\sim$10 times larger than those in previous studies beyond the local universe. This huge gain in sample size enables superior constraints on the MZR and its scatter in the low-mass regime. We find a power-law MZR at $10^{8} M_\odot < M_{*} < 10^{11} M_\odot$: ${12+log(O/H) = (5.83\pm0.19) + (0.30\pm0.02)log(M_{*}/M_\odot)}$. Our MZR shows good agreement with others measured at similar redshifts in the literature in the intermediate and massive regimes, but is shallower than the extrapolation of the MZRs of others to masses below $10^{9} M_\odot$. The SFR dependence of the MZR in our sample is weaker than that found for local galaxies (known as the Fundamental Metallicity Relation). Compared to a variety of theoretical models, the slope of our MZR for low-mass galaxies agrees well with predictions incorporating supernova energy-driven winds. Being robust against currently uncertain metallicity calibrations, the scatter of the MZR serves as a powerful diagnostic of the stochastic history of gas accretion, gas recycling, and star formation of low-mass galaxies. Our major result is that the scatter of our MZR increases as $M_{*}$ decreases. Our result implies that either the scatter of the baryonic accretion rate or the scatter of the $M_{*}$--$M_{halo}$ relation increases as $M_{*}$ decreases. Moreover, our measures of scatter at $z=0.7$ appears consistent with that found for local galaxies.Comment: 18 pages, 10 figures. Accepted by ApJ. Typos correcte

High-frequency water quality monitoring in an urban catchment: hydrochemical dynamics, primary production and implications for the Water Framework Directive

This paper describes the hydrochemistry of a lowland, urbanised river-system, The Cut in England, using in situ sub-daily sampling. The Cut receives effluent discharges from four major sewage treatment works serving around 190,000 people. These discharges consist largely of treated water, originally abstracted from the River Thames and returned via the water supply network, substantially increasing the natural flow. The hourly water quality data were supplemented by weekly manual sampling with laboratory analysis to check the hourly data and measure further determinands. Mean phosphorus and nitrate concentrations were very high, breaching standards set by EU legislation. Though 56% of the catchment area is agricultural, the hydrochemical dynamics were significantly impacted by effluent discharges which accounted for approximately 50% of the annual P catchment input loads and, on average, 59% of river flow at the monitoring point. Diurnal dissolved oxygen data demonstrated high in-stream productivity. From a comparison of high frequency and conventional monitoring data, it is inferred that much of the primary production was dominated by benthic algae, largely diatoms. Despite the high productivity and nutrient concentrations, the river water did not become anoxic and major phytoplankton blooms were not observed. The strong diurnal and annual variation observed showed that assessments of water quality made under the Water Framework Directive (WFD) are sensitive to the time and season of sampling. It is recommended that specific sampling time windows be specified for each determinand, and that WFD targets should be applied in combination to help identify periods of greatest ecological risk. This article is protected by copyright. All rights reserved

The network topology of a potential energy landscape: A static scale-free network

Here we analyze the topology of the network formed by the minima and transition states on the potential energy landscape of small clusters. We find that this network has both a small-world and scale-free character. In contrast to other scale-free networks, where the topology results from the dynamics of the network growth, the potential energy landscape is a static entity. Therefore, a fundamentally different organizing principle underlies this behaviour: The potential energy landscape is highly heterogeneous with the low-energy minima having large basins of attraction and acting as the highly-connected hubs in the network.Comment: 4 pages, 4 figures, revtex