1,087 research outputs found
Remediation of potentially acidified Hanford wastes using tri-n-octyl phosphine oxide extraction chromatographic materials
As the Hanford site undergoes remediation, significant economies could be realized if aluminum and chromium are kept from High Level Waste glass produced at the Hanford Waste Treatment Plant (WTP). An acidic scrub of the Hanford sludge could enhance Al removal, although such treatment could lead to the mobilization of transuranic elements. If mobilization were minor, a chromatographic secondary cleanup of the acidic waste stream may be preferred to allow preconcentration of radionuclides prior to processing through the Hanford WTP. This study examines tri-n-octyl phosphine oxide coated resins as a chromatographic means for the removal of transuranics from a secondary waste stream. Metal uptake kinetics and mechanisms for transuranics and a simulant transuranic (europium) with the developed resin are characterized in both batch and column operation modes. Results indicate up to 99% of the radioactive material present from an acidic sludge leach may be recovered using extraction chromatography providing an effective avenue for high aluminum content tank pre-treatment
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Actinide complexation kinetics: rate and mechanism of dioxoneptunium (V) reaction with chlorophosphonazo III
Rates of complex formation and dissociation in NpO{sub 2}{sup +}- Chlorophosphonazo III (2,7-bis(4-chloro-2-phosphonobenzeneazo)-1,8- dihydroxynapthalene-3,6-disulfonic acid)(CLIII) were investigated by stopped-flow spectrophotometry. Also, limited studies were made of the rates of reaction of La{sup 3+}, Eu{sup 3+}, Dy{sup 3+}, and Fe{sup 3+} with CLIII. Rate determining step in each system is an intramolecular process, the NpO{sub 2}{sup +}-CLIII reaction proceeding by a first order approach to equilibrium in the acid range from 0.1 to 1.0 M. Complex formation occurs independent of acidity, while both acid dependent and independent dissociation pathways are observed. Activation parameters for the complex formation reaction are {Delta}H=46.2{+-}0.3 kJ/m and {Delta}S=7{+-} J/mK (I=1.0 M); these for the acid dependent and independent dissociation pathways are {Delta}H=38.8{+-}0.6 kJ/m, {Delta}S=-96{+-}18 J/mK, {Delta}H=70.0{+-} kJ/m, and {Delta}S=17{+-}1 J/mK, respectively. An isokinetic relationship is observed between the activation parameters for CLIII complex formation with NpO{sub 2}{sup +}, UO{sub 2}{sup 2+}, Th{sup 4+}, and Zr{sup 4+}. Rates of CLIII complex formation reactions for Fe{sup 3+}, Zr{sup 4+}, NpO{sub 2}{sup +}, UO{sub 2}{sup 2+}, Th{sup 4+}, La{sup 3+}, Eu{sup 3+}, and Dy{sup 3+} correlate with cation radius rather than charge/radius ratio
Actinide Complexation Kinetics: Rate and Mechanism of Dioxoneptunium(V) Reaction with Chlorophosphonazo III
Rates of complex formation and dissociation in NpO{sub 2}{sup +}- Chlorophosphonazo III (2,7-bis(4-chloro-2-phosphonobenzeneazo)-1,8- dihydroxynapthalene-3,6-disulfonic acid)(CLIII) were investigated by stopped-flow spectrophotometry. Also, limited studies were made of the rates of reaction of La{sup 3+}, Eu{sup 3+}, Dy{sup 3+}, and Fe{sup 3+} with CLIII. Rate determining step in each system is an intramolecular process, the NpO{sub 2}{sup +}-CLIII reaction proceeding by a first order approach to equilibrium in the acid range from 0.1 to 1.0 M. Complex formation occurs independent of acidity, while both acid dependent and independent dissociation pathways are observed. Activation parameters for the complex formation reaction are {Delta}H=46.2{+-}0.3 kJ/m and {Delta}S=7{+-} J/mK (I=1.0 M); these for the acid dependent and independent dissociation pathways are {Delta}H=38.8{+-}0.6 kJ/m, {Delta}S=-96{+-}18 J/mK, {Delta}H=70.0{+-} kJ/m, and {Delta}S=17{+-}1 J/mK, respectively. An isokinetic relationship is observed between the activation parameters for CLIII complex formation with NpO{sub 2}{sup +}, UO{sub 2}{sup 2+}, Th{sup 4+}, and Zr{sup 4+}. Rates of CLIII complex formation reactions for Fe{sup 3+}, Zr{sup 4+}, NpO{sub 2}{sup +}, UO{sub 2}{sup 2+}, Th{sup 4+}, La{sup 3+}, Eu{sup 3+}, and Dy{sup 3+} correlate with cation radius rather than charge/radius ratio
Malicious Bayesian Congestion Games
In this paper, we introduce malicious Bayesian congestion games as an
extension to congestion games where players might act in a malicious way. In
such a game each player has two types. Either the player is a rational player
seeking to minimize her own delay, or - with a certain probability - the player
is malicious in which case her only goal is to disturb the other players as
much as possible.
We show that such games do in general not possess a Bayesian Nash equilibrium
in pure strategies (i.e. a pure Bayesian Nash equilibrium). Moreover, given a
game, we show that it is NP-complete to decide whether it admits a pure
Bayesian Nash equilibrium. This result even holds when resource latency
functions are linear, each player is malicious with the same probability, and
all strategy sets consist of singleton sets. For a slightly more restricted
class of malicious Bayesian congestion games, we provide easy checkable
properties that are necessary and sufficient for the existence of a pure
Bayesian Nash equilibrium.
In the second part of the paper we study the impact of the malicious types on
the overall performance of the system (i.e. the social cost). To measure this
impact, we use the Price of Malice. We provide (tight) bounds on the Price of
Malice for an interesting class of malicious Bayesian congestion games.
Moreover, we show that for certain congestion games the advent of malicious
types can also be beneficial to the system in the sense that the social cost of
the worst case equilibrium decreases. We provide a tight bound on the maximum
factor by which this happens.Comment: 18 pages, submitted to WAOA'0
The PanCam Instrument for the ExoMars Rover
The scientific objectives of the ExoMars rover are designed to answer several key questions in the search for life on Mars. In particular, the unique subsurface drill will address some of these, such as the possible existence and stability of subsurface organics. PanCam will establish the surface geological and morphological context for the mission, working in collaboration with other context instruments. Here, we describe the PanCam scientific objectives in geology, atmospheric science, and 3-D vision. We discuss the design of PanCam, which includes a stereo pair of Wide Angle Cameras (WACs), each of which has an 11-position filter wheel and a High Resolution Camera (HRC) for high-resolution investigations of rock texture at a distance. The cameras and electronics are housed in an optical bench that provides the mechanical interface to the rover mast and a planetary protection barrier. The electronic interface is via the PanCam Interface Unit (PIU), and power conditioning is via a DC-DC converter. PanCam also includes a calibration target mounted on the rover deck for radiometric calibration, fiducial markers for geometric calibration, and a rover inspection mirror.publishersversionPeer reviewe
Search for supersymmetry with a dominant R-parity violating LQDbar couplings in e+e- collisions at centre-of-mass energies of 130GeV to 172 GeV
A search for pair-production of supersymmetric particles under the assumption
that R-parity is violated via a dominant LQDbar coupling has been performed
using the data collected by ALEPH at centre-of-mass energies of 130-172 GeV.
The observed candidate events in the data are in agreement with the Standard
Model expectation. This result is translated into lower limits on the masses of
charginos, neutralinos, sleptons, sneutrinos and squarks. For instance, for
m_0=500 GeV/c^2 and tan(beta)=sqrt(2) charginos with masses smaller than 81
GeV/c^2 and neutralinos with masses smaller than 29 GeV/c^2 are excluded at the
95% confidence level for any generation structure of the LQDbar coupling.Comment: 32 pages, 30 figure
Riemannian Gauge Theory and Charge Quantization
In a traditional gauge theory, the matter fields \phi^a and the gauge fields
A^c_\mu are fundamental objects of the theory. The traditional gauge field is
similar to the connection coefficient in the Riemannian geometry covariant
derivative, and the field-strength tensor is similar to the curvature tensor.
In contrast, the connection in Riemannian geometry is derived from the metric
or an embedding space. Guided by the physical principal of increasing symmetry
among the four forces, we propose a different construction. Instead of defining
the transformation properties of a fundamental gauge field, we derive the gauge
theory from an embedding of a gauge fiber F=R^n or F=C^n into a trivial,
embedding vector bundle F=R^N or F=C^N where N>n. Our new action is symmetric
between the gauge theory and the Riemannian geometry. By expressing
gauge-covariant fields in terms of the orthonormal gauge basis vectors, we
recover a traditional, SO(n) or U(n) gauge theory. In contrast, the new theory
has all matter fields on a particular fiber couple with the same coupling
constant. Even the matter fields on a C^1 fiber, which have a U(1) symmetry
group, couple with the same charge of +/- q. The physical origin of this unique
coupling constant is a generalization of the general relativity equivalence
principle. Because our action is independent of the choice of basis, its
natural invariance group is GL(n,R) or GL(n,C). Last, the new action also
requires a small correction to the general-relativity action proportional to
the square of the curvature tensor.Comment: Improved the explanations, added references, added 3 figures and an
appendix, corrected a sign error in the old figure 4 (now figure 5). Now 33
pages, 7 figures and 2 tables. E-mail Serna for annimation
Measurement of the B0-anti-B0-Oscillation Frequency with Inclusive Dilepton Events
The - oscillation frequency has been measured with a sample of
23 million \B\bar B pairs collected with the BABAR detector at the PEP-II
asymmetric B Factory at SLAC. In this sample, we select events in which both B
mesons decay semileptonically and use the charge of the leptons to identify the
flavor of each B meson. A simultaneous fit to the decay time difference
distributions for opposite- and same-sign dilepton events gives ps.Comment: 7 pages, 1 figure, submitted to Physical Review Letter
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