The Potential for Abiotic Methane in Arctic Gas Hydrates

Most methane enclosed in gas hydrates is biotic in origin, formed by microbial degradation of sedimentary organic matter. Increasingly, there is evidence that substantial gas hydrate may also be sourced from thermogenic decomposition of organic matter and subsequent migration of this gas into the gas hydrate stability zone. In addition, there is a third potential source of methane that does not involve organic matter at all— abiotic methane, which can be generated by magmatic processes or gaswater- rock reactions in the crust and upper mantle

Norwegian margin outer shelf cracking: a consequence of climate-induced gas hydrate dissociation?

A series of en echelon cracks run nearly parallel to the outer shelf edge of the mid-Norwegian margin. The features can be followed in a *60-km-long and *5-km-wide zone in which up to 10-m-deep cracks developed in the seabed at 400–550 m water depth. The time of the seabed cracking has been dated to 7350 14C years BP (8180 cal years BP), which corresponds with the main Storegga Slide event (8100 ± 250 cal. years BP). Reflection seismic data suggest that the cracks do not appear to result from deep-seated faults, but it cannot be ruled out completely that tension crevices were created in relation to past movements on the headwall of the Storegga slide. The cracking zone corresponds well to the zone where the base of the hydrate stability zone (BHSZ) outcrops. Evidence of fluid release in the BHSZ outcrop zone comes from an extensive pockmark field. We suggest that post-glacial ocean warming triggered the dissociation of gas hydrates while the interplay between dissociation, overpressure, and sediment fracturing on the outer shelf remains to be understood.publishedVersio

Role of tectonic stress in seepage evolution along the gas hydrate‐charged Vestnesa Ridge, Fram Strait

Methane expulsion from the world ocean floor is a broadly observed phenomenon known to be episodic. Yet the processes that modulate seepage remain elusive. In the Arctic offshore west Svalbard, for instance, seepage at 200–400 m water depth may be explained by ocean temperature‐controlled gas hydrate instabilities at the shelf break, but additional processes are required to explain seepage in permanently cold waters at depths \u3e1000 m. We discuss the influence of tectonic stress on seepage evolution along the ~100 km long hydrate‐bearing Vestnesa Ridge in Fram Strait. High‐resolution P‐Cable 3‐D seismic data revealed fine‐scale (\u3e10 m width) near‐vertical faults and fractures controlling seepage distribution. Gas chimneys record multiple seepage events coinciding with glacial intensification and active faulting. The faults document the influence of nearby tectonic stress fields in seepage evolution along this deepwater gas hydrate system for at least the last ~2.7 Ma

Microseismicity linked to gas migration and leakage on the western Svalbard shelf

Source at: http://doi.org/10.1002/2017GC007107The continental margin off Prins Karls Forland, western Svalbard, is characterized by widespread natural gas seepage into the water column at and upslope of the gas hydrate stability zone. We deployed an ocean bottom seismometer integrated into the MASOX (Monitoring Arctic Seafloor-Ocean Exchange) automated seabed observatory at the pinch-out of this zone at 389 m water depth to investigate passive seismicity over a continuous 297 day period from 13 October 2010. An automated triggering algorithm was applied to detect over 220,000 short duration events (SDEs) defined as having a duration of less than 1 s. The analysis reveals two different types of SDEs, each with a distinctive characteristic seismic signature. We infer that the first type consists of vocal signals generated by moving mammals, likely finback whales. The second type corresponds to signals with a source within a few hundred meters of the seismometer, either due east or west, that vary on short (tens of days) and seasonal time scales. Based on evidence of prevalent seafloor seepage and subseafloor gas accumulations, we hypothesize that the second type of SDEs is related to subseafloor fluid migration and gas seepage. Furthermore, we postulate that the observed temporal variations in microseismicity are driven by transient fluid release and due to the dynamics of thermally forced, seasonal gas hydrate decomposition. Our analysis presents a novel technique for monitoring the duration, intensity, and periodicity of fluid migration and seepage at the seabed and can help elucidate the environmental controls on gas hydrate decomposition and release

Empirical Studies on Foster Care: Review and Assessment

This is a selected review and critique of twenty articles which investigate psychosocial characteristics of children in foster care. Each article represents an effort to describe the foster care population and/or to test hypotheses about issues in foster care. Articles were selected within the time frame of 1974 to 1989. Data are presented in summary tabular form. Discussion focuses upon behavioral characteristics and emotional/health problems of the children. A general methodological critique of research is provided. Policy recommendations incorporate those variables/factors most frequently studied and suggest direction for further research

The Postglacial response of Arctic Ocean gas hydrates to climatic amelioration

Seafloor methane release due to the thermal dissociation of gas hydrates is pervasive across the continental margins of the Arctic Ocean. Furthermore, there is increasing awareness that shallow hydrate-related methane seeps have appeared due to enhanced warming of Arctic Ocean bottom water during the last century. Although it has been argued that a gas hydrate gun could trigger abrupt climate change, the processes and rates of subsurface/atmospheric natural gas exchange remain uncertain. Here we investigate the dynamics between gas hydrate stability and environmental changes from the height of the last glaciation through to the present day. Using geophysical observations from offshore Svalbard to constrain a coupled ice sheet/gas hydrate model, we identify distinct phases of subglacial methane sequestration and subsequent release on ice sheet retreat that led to the formation of a suite of seafloor domes. Reconstructing the evolution of this dome field, we find that incursions of warm Atlantic bottom water forced rapid gas hydrate dissociation and enhanced methane emissions during the penultimate Heinrich event, the B?lling and Aller?d interstadials, and the Holocene optimum. Our results highlight the complex interplay between the cryosphere, geosphere, and atmosphere over the last 30,000 y that led to extensive changes in subseafloor carbon storage that forced distinct episodes of methane release due to natural climate variability well before recent anthropogenic warmingauthorsversionPeer reviewe

Particle sources and downward fluxes in the eastern Fram strait under the influence of the west Spitsbergen current

Accepted manuscript version. Published version available at https://doi.org/10.1016/j.dsr.2015.06.002. Licensed CC BY-NC-ND 4.0.The carbon cycle of the Arctic Ocean is tightly regulated by land–atmosphere–cryosphere–ocean interactions. Characterizing these environmental exchanges and feedbacks is critical to facilitate projections of the carbon cycle under changing climate conditions. The environmental drivers of sinking particles including organic carbon (OC) to the deep-sea floor are investigated with four moorings including sediment traps and currentmeters at the Arctic gateway in the eastern Fram Strait, which is the area where warm anomalies are transported northwards to the Arctic. Particles fluxes were collected over one year (July 2010–July 2011) and have been analysed to obtain the content of the lithogenic fraction, calcium carbonate, OC and its stable isotopes, opal, and the grain size. Records of near bottom current speed and temperature along with satellite observations of sea ice extent and chlorophyll-a concentration have been used for evaluation of the environmental conditions. We found increased lithogenic fluxes (up to 9872 mg m−2 d−1) and coarsening grain size of settling particles in late winter–early spring. At the same time, intensifications of the northward flowing west Spitsbergen current (WSC) were recorded. The WSC was able to resuspend and transport northwards sediments that were deposited at the outlet of Storfjordrenna and on the upper slope west of Spitsbergen. The signal of recurrent winnowing of fine particles was also detected in the top layer of surface sediments. In addition, an increased arrival of sea ice transported ice rafted detritus (>414 detrital carbonate mineral grains larger than 1 mm per m2) from the southern Spitsbergen coast along with terrestrial organic matter was observed beyond 1000 m of water depth during winter months. Finally, the downward particle fluxes showed typical temporal variability of high latitudes, with high percentages of the biogenic compounds (opal, organic carbon and calcium carbonate) linked to the phytoplankton bloom in spring–summer. However, on an annual basis local planktonic production was a secondary source for the downward OC, since most of the OC was advected laterally by the WSC. Overall, these observations demonstrated the sensitivity of the downward flux of particles to environmental conditions such as hydrodynamics, sea ice rafting, and pelagic primary production. Future alteration of the patterns of natural drivers due to climate change is thus expected to cause major shifts in the downward flux of particles, including carbon, to the deep sea ecosystems.</p

Ocean temperature variability for the past 60 years on the Norwegian-Svalbard margin influences gas hydrate stability on human time scales

The potential impact of future climate change on methane release from oceanic gas hydrates is the subject of much debate. We analyzed World Ocean Database quality controlled data on the Norwegian‐Svalbard continental margin from the past 60 years to evaluate the potential effect of ocean temperature variations on continental margin gas hydrate reservoirs. Bottom water temperatures in the Norwegian‐Svalbard margin were subject to significant cooling until 1980 (by ∼2°C offshore NW‐Svalbard and in the Barents Sea) followed by a general bottom water temperature increase until 2010 (∼0.3°C in deep‐water areas offshore NW‐Svalbard and mid‐Norwegian margin and ∼2°C in the shallow areas of the Barents Sea and Prins Karls Forland). Bottom water warming in the shallow outer shelf areas triggered the Gas Hydrate Stability Zone (GHSZ) retreat toward upper continental slope areas, potentially increasing methane release due to gas hydrate dissociation. GHSZ responses to temperature changes on human time scales occur exclusively in shallow water and only if near‐surface gas hydrates exist. The responses are associated with a short time lag of less than 1 year. Temperatures in the bottom water column seem to be partly regulated by the North Atlantic Oscillation (NAO), with positive NAO associated with warm phases. However, cooling events in the surface water offshore NW‐Svalbard might be associated with El Niño events of 1976–1977, 1986–1987 and 1997–1998 in the Pacific. Such ocean cooling, if long enough, may delay ocean temperature driven gas hydrate dissociation and potential releases of methane to the ocean

Modeling the evolution of climate-sensitive Arctic subsea permafrost in regions of extensive gas expulsion at the West Yamal shelf

Thawing subsea permafrost controls methane release from the Russian Arctic shelf having a considerable impact on the climate-sensitive Arctic environment. Expulsions of methane from shallow Russian Arctic shelf areas may continue to rise in response to intense degradation of relict subsea permafrost. Here we show modeling of the permafrost evolution from the Late Pleistocene to present time at the West Yamal shelf. Modeling results suggest a highly dynamic permafrost system that directly responds to even minor variations of lower and upper boundary conditions, e.g., geothermal heat flux from below and/or bottom water temperature changes from above permafrost. Scenarios of permafrost evolution show a potentially nearest landward modern extent of the permafrost at the West Yamal shelf limited by ~17 m isobaths, whereas its farthest seaward extent coincides with ~100 m isobaths. The model also predicts seaward tapering of relict permafrost with a maximal thickness of 275–390 m near the shoreline. Previous field observations detected extensive emissions of free gas into the water column at the transition zone between today's shallow water permafrost (20 m). The model adapts well to corresponding heat flux and ocean temperature data, providing crucial information about the modern permafrost conditions. It shows current locations of upper and lower permafrost boundaries and evidences for possible release of methane from the seabed to the hydrosphere in a warming Arctic

High-resolution 3D seismic exhibits new insights into the middle-late Pleistocene stratigraphic evolution and sedimentary processes of the Bear Island trough mouth fan

Arctic Ocean trough mouth fans (TMFs) represent a valuable archive of glacial-interglacial sedimentary processes that are especially important when reconstructing pre-Weichselian glaciations that may lack distinct imprints on the shelves. In 2011, we acquired the first high-resolution 3D seismic cube (~3 m vertical and 6 m horizontal resolution) on the continental slope of the SW Barents Sea by use of a P-Cable 3D system, to study in detail the seismic stratigraphy and glacial depositional history of the Bear Island Trough Mouth Fan. This technology provides data with a resolution that, for the first time on the western Barents Sea slope, enables detailed mapping of deposits of different glacial cycles. The dataset provides entire spatially coverage, allowing us to reconcile multiple generations of glacigenic deposits and channel systems. High-resolution 3D seismic data is crucial to describe buried channels, glacial units, as well as low relief landforms such as sediment waves accurately. The 30 km2 seismic cube is located at the southern flank of the Bear Island TMF at water depths from 592 to 660 m where sandwaves dominate the present seafloor. The data covers the glacially derived stratigraphy in the uppermost ~700 m below the seafloor. We establish a robust stratigraphic framework by interpreting seismic reflectors along 2D tie-in lines to previously well-constrained seismic and well data. We find that our data provide a record of progradation of glacigenic debris flows (GDFs) since MIS 12 (0.5 Ma) to present. Horizon slices reveal a range of gullies and channels at different depths overlying the GDFs. We describe the paleoenvironment and sedimentary processes throughout this time-span (that covers seven glacial cycles) and discuss the impact of the Barents Sea Ice Sheet waxing and waning on erosion, sedimentation, and deposition along the continental slope. Abundant buried gullies were hitherto unknown at the Bear Island TMF, with previous work describing this succession as a debris-flow dominated unit where meltwater-related features are lacking, and interpreting this to represent low average temperatures. By use of the relatively small high-resolution 3D seismic dataset, we provide new evidence for the presence of gullies and channels indicating that periods of ice sheet melting and meltwater runoff existed throughout the middle-late Pleistocene succession. The work offers new insight into the stratigraphic evolution of a continental margin dominated by GDFs and demonstrates the value of high-resolution seismic, such as the P-Cable system, in resolving important details of paleo-slope-environments