121 research outputs found
Considerations on data acquisition in laser ablation-inductively coupled plasma-mass spectrometry with low-dispersion interfaces
Shell chemistry of the boreal Campanian bivalve Rastellum diluvianum (Linnaeus, 1767) reveals temperature seasonality, growth rates and life cycle of an extinct Cretaceous oyster
This is the final version. Available from European Geosciences Union (EGU) / Copernicus Publications via the DOI in this record.âŻThe Campanian age (Late Cretaceous) is characterized by a warm greenhouse climate with limited land-ice volume. This makes this period an ideal target for studying climate dynamics during greenhouse periods, which are essential for predictions of future climate change due to anthropogenic greenhouse gas emissions. Well-preserved fossil shells from the Campanian (±78âMa) high mid-latitude (50ââN) coastal faunas of the Kristianstad Basin (southern Sweden) offer a unique snapshot of short-term climate and environmental variability, which complements existing long-term climate reconstructions. In this study, we apply a combination of high-resolution spatially resolved trace element analyses (micro-X-ray fluorescence â ”XRF â and laser ablation inductively coupled plasma mass spectrometry â LA-ICP-MS), stable isotope analyses (IRMS) and growth modeling to study short-term (seasonal) variations recorded in the oyster species Rastellum diluvianum from the Ivö Klack locality. Geochemical records through 12 specimens shed light on the influence of specimen-specific and ontogenetic effects on the expression of seasonal variations in shell chemistry and allow disentangling vital effects from environmental influences in an effort to refine paleoseasonality reconstructions of Late Cretaceous greenhouse climates. Growth models based on stable oxygen isotope records yield information on the mode of life, circadian rhythm and reproductive cycle of these extinct oysters. This multi-proxy study reveals that mean annual temperatures in the Campanian higher mid-latitudes were 17 to 19ââC, with winter minima of âŒ13ââC and summer maxima of 26ââC, assuming a Late Cretaceous seawater oxygen isotope composition of â1ââ° VSMOW (Vienna standard mean ocean water). These results yield smaller latitudinal differences in temperature seasonality in the Campanian compared to today. Latitudinal temperature gradients were similar to the present, contrasting with previous notions of âequable climateâ during the Late Cretaceous. Our results also demonstrate that species-specific differences and uncertainties in the composition of Late Cretaceous seawater prevent trace element proxies (MgâCa, SrâCa, MgâLi and SrâLi) from being used as reliable temperature proxies for fossil oyster shells. However, trace element profiles can serve as a quick tool for diagenesis screening and investigating seasonal growth patterns in ancient shells.Flemish Institute for Science and Technology (IWT)Hercules InfrastructureFWOBelspo BRAIN ProjectCarlsbergfondetVUB Strategic Research
Amorphous alumina in the extended atmosphere of Alpha Orionis
In this paper we study the extended atmosphere of the late-type supergiant
Alpha Orionis. Infrared spectroscopy of red supergiants reveals strong
molecular bands, some of which do not originate in the photosphere but in a
cooler layer of molecular material above it. Lately, these layers have been
spatially resolved by near and mid-IR interferometry. In this paper, we try to
reconcile the IR interferometric and ISO-SWS spectroscopic results on Alpha
Orionis with a thorough modelling of the photosphere, molecular layer(s) and
dust shell. From the ISO and near-IR interferometric observations, we find that
Alpha Orionis has only a very low density water layer close above the
photosphere. However, mid-IR interferometric observations and a narrow-slit
N-band spectrum suggest much larger extra-photospheric opacity close to the
photosphere at those wavelengths, even when taking into account the detached
dust shell. We argue that this cannot be due to the water layer, and that
another source of mid-IR opacity must be present. We show that this opacity
source is probably neither molecular nor chromospheric. Rather, we present
amorphous alumina (Al2O3) as the best candidate and discuss this hypothesis in
the framework of dust-condensation scenarios.Comment: 15 pages, 18 figures, accepted for publication in A&
Homogenizing GPS integrated water vapour time series: methodology and benchmarking the algorithms on synthetic datasets
We would like to thank the COST Action ES1206 GNSS4SWEC for financial support
Performance of various homogenization tools on a synthetic benchmark dataset of GPS and ERA-interim IWV differences
PresentaciĂłn realizada en: IAG-IASPEI 39th Joint Scientific Assembly celebrada en Kobe, JapĂłn, del 30 de julio al 4 de agosto de 2017
Study on homogenization of synthetic GNSS-Retrieved IWV time series and its impact on trend estimates with autoregressive noise
PĂłster presentado en: EGU General Assembly celebrada del 23 al 28 de abril de 2017 en Viena, Austria.A synthetic benchmark dataset of Integrated Water Vapour (IWV) was created within the activity of âData homogenisationâ of sub-working group WG3 of COST ES1206 Action. The benchmark dataset was created basing on the analysis of IWV differences retrieved by Global Positioning System (GPS) International GNSS Service (IGS) stations using European Centre for Medium-Range Weather Forecats (ECMWF) reanalysis data (ERA-Interim). Having analysed a set of 120 series of IWV differences (ERAI-GPS) derived for IGS stations, we delivered parameters of a number of gaps and breaks for every certain station. Moreover, we estimated values of trends, significant seasonalities and character of residuals when deterministic model was removed. We tested five different noise models and found that a combination of white and autoregressive processes of first order describes the stochastic part with a good accuracy. Basing on this analysis, we performed Monte Carlo simulations of 25 years long data with two different types of noise: white as well as combination of white and autoregressive processes. We also added few strictly defined offsets, creating three variants of synthetic dataset: easy, less complicated and fully complicated. The synthetic dataset we present was used as a benchmark to test various statistical tools in terms of homogenisation task. In this research, we assess the impact of the noise model, trend and gaps on the performance of statistical methods to detect simulated change points
Shell chemistry of the boreal Campanian bivalve Rastellum diluvianum (Linnaeus, 1767) reveals temperature seasonality, growth rates and life cycle of an extinct Cretaceous oyster
This is the final version. Available from European Geosciences Union (EGU) / Copernicus Publications via the DOI in this record.âŻThe Campanian age (Late Cretaceous) is characterized by a warm greenhouse climate with limited land-ice volume. This makes this period an ideal target for studying climate dynamics during greenhouse periods, which are essential for predictions of future climate change due to anthropogenic greenhouse gas emissions. Well-preserved fossil shells from the Campanian (±78âMa) high mid-latitude (50ââN) coastal faunas of the Kristianstad Basin (southern Sweden) offer a unique snapshot of short-term climate and environmental variability, which complements existing long-term climate reconstructions. In this study, we apply a combination of high-resolution spatially resolved trace element analyses (micro-X-ray fluorescence â ”XRF â and laser ablation inductively coupled plasma mass spectrometry â LA-ICP-MS), stable isotope analyses (IRMS) and growth modeling to study short-term (seasonal) variations recorded in the oyster species Rastellum diluvianum from the Ivö Klack locality. Geochemical records through 12 specimens shed light on the influence of specimen-specific and ontogenetic effects on the expression of seasonal variations in shell chemistry and allow disentangling vital effects from environmental influences in an effort to refine paleoseasonality reconstructions of Late Cretaceous greenhouse climates. Growth models based on stable oxygen isotope records yield information on the mode of life, circadian rhythm and reproductive cycle of these extinct oysters. This multi-proxy study reveals that mean annual temperatures in the Campanian higher mid-latitudes were 17 to 19ââC, with winter minima of âŒ13ââC and summer maxima of 26ââC, assuming a Late Cretaceous seawater oxygen isotope composition of â1ââ° VSMOW (Vienna standard mean ocean water). These results yield smaller latitudinal differences in temperature seasonality in the Campanian compared to today. Latitudinal temperature gradients were similar to the present, contrasting with previous notions of âequable climateâ during the Late Cretaceous. Our results also demonstrate that species-specific differences and uncertainties in the composition of Late Cretaceous seawater prevent trace element proxies (MgâCa, SrâCa, MgâLi and SrâLi) from being used as reliable temperature proxies for fossil oyster shells. However, trace element profiles can serve as a quick tool for diagenesis screening and investigating seasonal growth patterns in ancient shells.Flemish Institute for Science and Technology (IWT)Hercules InfrastructureFWOBelspo BRAIN ProjectCarlsbergfondetVUB Strategic Research
Homogenization of tropospheric data: evaluating the algorithms under the presence of autoregressive process
PresentaciĂłn realizada en: IX Hotine-Marussi Symposium celebrado en Roma del 18 al 22 de junio de 2018.This research was supported by the Polish National Science Centre,
grant No. UMO-2016/21/B/ST10/02353
Structure of the outer layers of cool standard stars
Context: Among late-type red giants, an interesting change occurs in the
structure of the outer atmospheric layers as one moves to later spectral types
in the Hertzsprung-Russell diagram: a chromosphere is always present, but the
coronal emission diminishes and a cool massive wind steps in.
Aims: Where most studies have focussed on short-wavelength observations, this
article explores the influence of the chromosphere and the wind on
long-wavelength photometric measurements.
Methods: The observational spectral energy distributions are compared with
the theoretical predictions of the MARCS atmosphere models for a sample of 9 K-
and M-giants. The discrepancies found are explained using basic models for flux
emission originating from a chromosphere or an ionized wind.
Results: For 7 out of 9 sample stars, a clear flux excess is detected at
(sub)millimeter and/or centimeter wavelengths. The precise start of the excess
depends upon the star under consideration. The flux at wavelengths shorter than
about 1 mm is most likely dominated by an optically thick chromosphere, where
an optically thick ionized wind is the main flux contributor at longer
wavelengths.
Conclusions: Although the optical to mid-infrared spectrum of the studied K-
and M-giants is well represented by a radiative equilibrium atmospheric model,
the presence of a chromosphere and/or ionized stellar wind at higher altitudes
dominates the spectrum in the (sub)millimeter and centimeter wavelength ranges.
The presence of a flux excess also has implications on the role of these stars
as fiducial spectrophotometric calibrators in the (sub)millimeter and
centimeter wavelength range.Comment: 13 pages, 6 figures, 7 pages of online material, submitted to A&
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