Aromatic polymers obtained by precipitation polycondensation: 4*. Synthesis of poly(ether ketone ketone)s

High molecular weight aromatic poly(ether ketone ketone)s were synthesized by the Friedel-Crafts polyacylation condensation of iso- and terephthaloyl chlorides with diphenyl ether, 1,4- and 1,3-bis(4- phenoxybenzoyl)benzenes. Depending on the monomers used for polycondensation, polyketones of regular structure with different iso-/tereisomer repeating unit ratio (100/0, 50/50, 0/100) in the main chain were obtained. Polymers of each repeating isomer unit were prepared in two different ways. All the polymer syntheses were performed as precipitation polycondensations and the resulting polymers were obtained in particle form. The influence of reaction conditions and preparation route on the polymer properties were examined. The monomer concentration and monomer stoichiometric ratio were found to affect the polymer viscosity. The size and shape of the polyketone particles obtained were also found to be governed by reaction conditions and preparation route.Peer reviewe

An Analysis of the Chemical Composition of the Atmosphere of Venus on an AMS of the Venera-12 Using a Gas Chromatograph

Eight analyses of the atmosphere of Venus were made beginning at an altitude of 42 km right down to the surface of the planet. The following were detected in the atmosphere of Venus: nitrogen in concentrations of 2.5 plus or minus 0.5 volumetric %, argon ir concentrations (4 plus or minus 2) x 10 to the minus 3 power volumetric %, CO--(2.8 plus or minus 1.4) x 10 to the minus 3 power volumetric % and SO2 in concentrations (1.3 plus or minus 0.6) x 10 to the minus 2 power volumetric %. The upper limits were estimated for the content of oxygen and water equal to 2 x 10 to the minus 3 power and 10 to the minus 2 power volumetric %, respectively

Ultraviolet photometry of Venus: Scattering layer above the absorbing clouds

Experimental measurements by ultraviolet photometers aboard Venera-9 and -10 are presented, discussed, and compared with various theoretical models of the ultraviolet structure of the atmosphere of Venus. The model in best agreement with observation provides for a finely dispersed, 8 km thick Rayleigh scattering layer above the primary cloud cover. Dark contrast details are considered to be breaks or areas of lower optical thickness in the upper scattering layer

Experimental study on the effect of rock pressure on sandstone permeability

The results of laboratory studies to determine the effect of effective stress on the permeability of sandstone are presented. During the test, the samples were subjected to a stepwise increase or decrease of the effective stress (at a constant pore pressure) in a specified step. The values of rock permeability at different values of effective stress were determined, and the influence of the grain size of the reservoir rock matrix on the character of the change in the sandstone permeability coefficient was also established. During the test, a decrease in permeability was observed with an increase in effective stress. It was found that as a result of gradual loading/unloading of the sandstone sample, the original permeability values were not restored, which indicates the beginning of the formation of residual strains in the rock. This effect should be taken into account when modeling field development because in the process of reserves extraction the effective stress acting on the reservoir rock skeleton changes, which results in a significant chang in rock permeability. The results of laboratory studies showed that the deviation of permeability in medium-grained sandstones relative to the initial value was greater than in medium- and fine-grained sandstones. The pressure sensitivity coefficient and constant of material, which are used in empirical relationships between permeability and effective stress, were numerically estimated. At the same time, the constant of material showed no such convergence, which indicates that the values of this parameter are individual for each rock

Mass Transfer Mechanism in Real Crystals by Pulsed Laser Irradiation

The dynamic processes in the surface layers of metals subjected activity of a pulsing laser irradiation, which destroyed not the crystalline structure in details surveyed. The procedure of calculation of a dislocation density generated in bulk of metal during the relaxation processes and at repeated pulse laser action is presented. The results of evaluations coincide with high accuracy with transmission electron microscopy dates. The dislocation-interstitial mechanism of laser-stimulated mass-transfer in real crystals is presented on the basis of the ideas of the interaction of structure defects in dynamically deforming medium. The good compliance of theoretical and experimental results approves a defining role of the presented mechanism of mass transfer at pulse laser action on metals. The possible implementation this dislocation-interstitial mechanism of mass transfer in metals to other cases of pulsing influences is justifiedComment: 10 pages, 2 figures, Late

The XMM-Newton serendipitous survey. VII. The third XMM-Newton serendipitous source catalogue

Thanks to the large collecting area (3 x ~1500 cm$^2$ at 1.5 keV) and wide field of view (30' across in full field mode) of the X-ray cameras on board the European Space Agency X-ray observatory XMM-Newton, each individual pointing can result in the detection of hundreds of X-ray sources, most of which are newly discovered. Recently, many improvements in the XMM-Newton data reduction algorithms have been made. These include enhanced source characterisation and reduced spurious source detections, refined astrometric precision, greater net sensitivity and the extraction of spectra and time series for fainter sources, with better signal-to-noise. Further, almost 50\% more observations are in the public domain compared to 2XMMi-DR3, allowing the XMM-Newton Survey Science Centre (XMM-SSC) to produce a much larger and better quality X-ray source catalogue. The XMM-SSC has developed a pipeline to reduce the XMM-Newton data automatically and using improved calibration a new catalogue version has been produced from XMM-Newton data made public by 2013 Dec. 31 (13 years of data). Manual screening ensures the highest data quality. This catalogue is known as 3XMM. In the latest release, 3XMM-DR5, there are 565962 X-ray detections comprising 396910 unique X-ray sources. For the 133000 brightest sources, spectra and lightcurves are provided. For all detections, the positions on the sky, a measure of the quality of the detection, and an evaluation of the X-ray variability is provided, along with the fluxes and count rates in 7 X-ray energy bands, the total 0.2-12 keV band counts, and four hardness ratios. To identify the detections, a cross correlation with 228 catalogues is also provided for each X-ray detection. 3XMM-DR5 is the largest X-ray source catalogue ever produced. Thanks to the large array of data products, it is an excellent resource in which to find new and extreme objects.Comment: 23 pages, version accepted for publication in A&

FAVOR (FAst Variability Optical Registration) -- A Two-telescope Complex for Detection and Investigation of Short Optical Transients

An astronomical complex intended to detect optical transients (OTs) in a wide field and follow them up with high time resolution investigation is described.Comment: 4 pages, 3 figures. To be published in "Il Nuovo Cimento", Proceedings of the 4th Rome Workshop on Gamma-Ray Bursts in the Afterglow Era, eds. L. Piro, L. Amati, S. Covino, B. Gendr

ELM triggering conditions for the integrated modeling of H-mode plasmas

Recent advances in the integrated modeling of ELMy H-mode plasmas are presented. A model for the H-mode pedestal and for the triggering of ELMs predicts the height, width, and shape of the H-mode pedestal and the frequency and width of ELMs. Formation of the pedestal and the L-H transition is the direct result of ExB flow shear suppression of anomalous transport. The periodic ELM crashes are triggered by either the ballooning or peeling MHD instabilities. The BALOO, DCON, and ELITE ideal MHD stability codes are used to derive a new parametric expression for the peeling-ballooning threshold. The new dependence for the peeling-ballooning threshold is implemented in the ASTRA transport code. Results of integrated modeling of DIII-D like discharges are presented and compared with experimental observations. The results from the ideal MHD stability codes are compared with results from the resistive MHD stability code NIMROD.Comment: 12th International Congress on Plasma Physics, 25-29 October 2004, Nice (France

Aerodynamic investigations of ventilated brake discs.

The heat dissipation and performance of a ventilated brake disc strongly depends on the aerodynamic characteristics of the flow through the rotor passages. The aim of this investigation was to provide an improved understanding of ventilated brake rotor flow phenomena, with a view to improving heat dissipation, as well as providing a measurement data set for validation of computational fluid dynamics methods. The flow fields at the exit of four different brake rotor geometries, rotated in free air, were measured using a five-hole pressure probe and a hot-wire anemometry system. The principal measurements were taken using two-component hot-wire techniques and were used to determine mean and unsteady flow characteristics at the exit of the brake rotors. Using phase-locked data processing, it was possible to reveal the spatial and temporal flow variation within individual rotor passages. The effects of disc geometry and rotational speed on the mean flow, passage turbulence intensity, and mass flow were determined. The rotor exit jet and wake flow were clearly observed as characterized by the passage geometry as well as definite regions of high and low turbulence. The aerodynamic flow characteristics were found to be reasonably independent of rotational speed but highly dependent upon rotor geometry