Evidence from Rb–Sr mineral ages for multiple orogenic events in the Caledonides of Shetland, Scotland

Shetland occupies a unique central location within the North Atlantic Caledonides. Thirty-three new high-precision Rb–Sr mineral ages indicate a polyorogenic history. Ages of 723–702 Ma obtained from the vicinity of the Wester Keolka Shear Zone indicate a Neoproterozoic (Knoydartian) age and preclude its correlation with the Silurian Moine Thrust. Ordovician ages of c. 480–443 Ma obtained from the Yell Sound Group and the East Mainland Succession constrain deformation fabrics and metamorphic assemblages to have formed during Grampian accretionary orogenic events, broadly contemporaneously with orogenesis of the Dalradian Supergroup in Ireland and mainland Scotland. The relative paucity of Silurian ages is attributed to a likely location at a high structural level in the Scandian nappe pile relative to mainland Scotland. Ages of c. 416 and c. 411 Ma for the Uyea Shear Zone suggest a late orogenic evolution that has more in common with East Greenland and Norway than with northern mainland Scotland

Trace element geochemistry of peridotites from the Izu-Bonin-Mariana Forearc, Leg 125

Trace element analyses (first-series transition elements, Ti, Rb, Sr, Zr, Y, Nb, and REE) were carried out on whole rocks and minerals from 10 peridotite samples from both Conical Seamount in the Mariana forearc and Torishima Forearc Seamount in the Izu-Bonin forearc using a combination of XRF, ID-MS, ICP-MS, and ion microprobe. The concentrations of incompatible trace elements are generally low, reflecting the highly residual nature of the peridotites and their low clinopyroxene content (n ratios in the range of 0.05-0.25; several samples show possible small positive Eu anomalies. LREE enrichment is common to both seamounts, although the peridotites from Conical Seamount have higher (La/Ce)n ratios on extended chondrite-normalized plots, in which both REEs and other trace elements are organized according to their incompatibility with respect to a harzburgitic mantle. Comparison with abyssal peridotite patterns suggests that the LREEs, Rb, Nb, Sr, Sm, and Eu are all enriched in the Leg 125 peridotites, but Ti and the HREEs exhibit no obvious enrichment. The peridotites also give positive anomalies for Zr and Sr relative to their neighboring REEs. Covariation diagrams based on clinopyroxene data show that Ti and the HREEs plot on an extension of an abyssal peridotite trend to more residual compositions. However, the LREEs, Rb, Sr, Sm, and Eu are displaced off this trend toward higher values, suggesting that these elements were introduced during an enrichment event. The axis of dispersion on these plots further suggests that enrichment took place during or after melting and thus was not a characteristic of the lithosphere before subduction. Compared with boninites sampled from the Izu-Bonin-Mariana forearc, the peridotites are significantly more enriched in LREEs. Modeling of the melting process indicates that if they represent the most depleted residues of the melting events that generated forearc boninites they must have experienced subsolidus enrichment in these elements, as well as in Rb, Sr, Zr, Nb, Sm, and Eu. The lack of any correlation with the degree of serpentinization suggests that low-temperature fluids were not the prime cause of enrichment. The enrichment in the high-field-strength elements also suggests that at least some of this enrichment may have involved melts rather than aqueous fluids. Moreover, the presence of the hydrous minerals magnesio-hornblende and tremolite and the common resorption of orthopyroxene indicate that this high-temperature peridotite-fluid interaction may have taken place in a water-rich environment in the forearc following the melting event that produced the boninites. The peridotites from Leg 125 may therefore contain a record of an important flux of elements into the mantle wedge during the initial formation of forearc lithosphere. Ophiolitic peridotites with these characteristics have not yet been reported, perhaps because the precise equivalents to the serpentinite seamounts have not been analyzed

Miocene UHT granulites from Seram, eastern Indonesia: a geochronological-REE study of zircon, monazite and garnet

Peer reviewe

Mesozoic Paleo-Pacific Subduction Beneath SW Borneo: U-Pb Geochronology of the Schwaner Granitoids and the Pinoh Metamorphic Group

The Schwaner Mountains in southwestern Borneo form a large igneous province with a complex magmatic history and poorly known tectonic history. Previously it was known that Cretaceous granitoids intruded metamorphic rocks of the Pinoh Metamorphic Group assumed to be of Paleozoic age. Jurassic granitoids had been reported from the southern Schwaner Mountains. Most ages were based on K-Ar dating. We present new geochemistry, zircon U-Pb and 40Ar/39Ar age data from igneous and metamorphic rocks from the Schwaner Mountains to investigate their tectono-magmatic histories. We subdivide the Schwaner Mountains into three different zones which record rifting, subduction-related and post-collisional magmatism. The Northwest Schwaner Zone (NWSZ) is part of the West Borneo Block which in the Triassic was within the Sundaland margin. It records Triassic to Jurassic magmatism during early Paleo-Pacific subduction. In contrast, the North Schwaner Zone (NSZ) and South Schwaner Zone (SSZ) are part of the SW Borneo (Banda) Block that separated from NW Australia in the Jurassic. Jurassic granitoids in the SSZ are within-plate (A-type) granites interpreted to have formed during rifting. The SW Borneo (Banda) Block collided with eastern Sundaland at c. 135 Ma. Following this, large I-type granitoid plutons and arc volcanics formed in the NWSZ and NSZ between c. 90 and 132 Ma, associated with Cretaceous Paleo-Pacific subduction. The largest intrusion is the c. 110 to 120 Ma Sepauk Tonalite. After collision of the East Java-West Sulawesi (Argo) Block, subduction ceased and post-collisional magmatism produced the c. 78 to 85 Ma Sukadana Granite and the A-type 72 Ma Sangiyang Granite in the SSZ. Rocks of the Pinoh Metamorphic Group mainly exposed in the NSZ, previously assumed to represent Paleozoic basement, contain abundant Early Cretaceous (110 to 135 Ma) zircons. They are interpreted as volcaniclastic sediments that formed contemporaneously with subduction-related volcanic rocks of the NSZ subsequently metamorphosed during intrusion of Cretaceous granitoids. There are no igneous rocks older than Cretaceous in the NSZ and older than Jurassic in the SSZ and there is no evidence for a continuation of a Triassic volcanic arc crossing Borneo from Sundaland to the east.This project was funded by the SE Asia Research Group of Royal Holloway University of London, which is supported by a consortium of oil companies

Environmental impact of early palaeometallurgy: pollen and geochemical analysis

International audienceInterdisciplinary research was carried out in mid-level mountain areas in France with the aim of documenting historical mining and smelting activities by means of pollen and geochemical analyses. These investigations were made on cores collected in French peatlands in the Morvan (northern Massif Central), at Mont Lozère (southern Massif Central) and in the Basque Country (Pyrénées). Different periods of mining were recognised from Prehistory to modern times through the presence of anthropogenic lead in peat. Some of these were already known from archaeological dates or historical archives, especially for mediaeval and modern periods. However prehistoric ancient mining activities, as early as the Middle Bronze Age (ca. 1700 b.c.), were also discovered. They had all led to modifications in plant cover, probably related in part to forest clearance necessary to supply energy for mining and smelting