22 research outputs found

    The Mineralosphere Concept: Mineralogical Control of the Distribution and Function of Mineral-associated Bacterial Communities

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    © 2015 Elsevier Ltd. Soil is composed of a mosaic of different rocks and minerals, usually considered as an inert substrata for microbial colonization. However, recent findings suggest that minerals, in soils and elsewhere, favour the development of specific microbial communities according to their mineralogy, nutritive content, and weatherability. Based upon recent studies, we highlight how bacterial communities are distributed on the surface of, and in close proximity to, minerals. We also consider the potential role of the mineral-associated bacterial communities in mineral weathering and nutrient cycling in soils, with a specific focus on nutrient-poor and acidic forest ecosystems. We propose to define this microbial habitat as the mineralosphere, where key drivers of the microbial communities are the physicochemical properties of the minerals

    Mixed carbon nanomaterial/epoxy resin for electrically conductive adhesives

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    The increasing complexity of printed circuit boards (PCBs) due to miniaturization, increased the density of electronic components, and demanding thermal management during the assembly triggered the research of innovative solder pastes and electrically conductive adhesives (ECAs). Current commercial ECAs are typically based on epoxy matrices with a high load (>60%) of silver particles, generally in the form of microflakes. The present work reports the production of ECAs based on epoxy/carbon nanomaterials using carbon nanotubes (single and multi-walled) and exfoliated graphite, as well as hybrid compositions, within a range of concentrations. The composites were tested for morphology (dispersion of the conductive nanomaterials), electrical and thermal conductivity, rheological characteristics and deposition on a test PCB. Finally, the ECA’s shelf life was assessed by mixing all the components and conductive nanomaterials, and evaluating the cure of the resin before and after freezing for a time range up to nine months. The ECAs produced could be stored at −18 °C without affecting the cure reaction.This research was funded by the Portugal Incentive System for Research and Technological Development,Project in Co-Promotion n◦039479/2019 (Factory of the Future: Smart Manufacturing 2019–202

    Classical or inverted photovoltaic cells: On the importance of the morphology of the organic layers on their power conversion efficiency

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    Novel organic thiophene derivatives, (E)-Bis-1,2-(5,500-Dimethyl-(2,20:30,200-terthiophene)vinylene (BSTV) and (E)-Bis-1,2-(5,500-Dimethyl-(2,20:30,200:30,2000-tetrathiophene)vinylene (BOTV), with different numbers of thiophene units, have been synthesized. They are introduced into organic photovoltaic cells as electron donor. The both organic photovoltaic cell configurations are probed: classical, i.e. with the ITO used as anode, and inverted, i.e. with ITO used as cathode. Whatever the cell configuration, the best results are obtained when a double cathode buffer layer Alq3/Ca is used. Actually, such double cathode buffer layer allows cumulating the advantages of its both constituents. The Alq3 blocks the excitons and protects the organic electron acceptor from cathode diffusion during its deposition, while the low work function of Ca induces a good band matching at the interface electron acceptor/cathode. On the other hand, it is shown that the organic layer surface morphology is decisive whatever the cell efficiency. While the BSTV layers are homogeneous those of BOTV are not. It follows that, in the case of classical organic photovoltaic cells, leakage currents limits the performances of the cells using BOTV, and better performances are obtained with BSTV. This difficulty is overcome in the case of inverted organic photovoltaic cells. This configuration allows limiting the effect of the inhomogeneities of the donor layer and better efficiencies are obtained with BOTV, which was expected due to its smaller band gap value

    Discovery pipelines for marine resources : an ocean of opportunity for biotechnology?

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    This project has received funding from the European Union’s Horizon 2020 research and innovation programme under Grant agreement No 645884. CABI is an international intergovernmental organisation, and we gratefully acknowledge the core financial support from our member countries (and lead agencies) including the United Kingdom (Department for International Development), China (Chinese Ministry of Agriculture), Australia (Australian Centre for International Agricultural Research), Canada (Agriculture and Agri-Food Canada), Netherlands (Directorate-General for International Cooperation),and Switzerland (Swiss Agency for Development and Cooperation). See https://www.cabi.org/about-cabi/who-we-work-with/key-donors/ for full details.Marine microbial diversity offers enormous potential for discovery of compounds of crucial importance in healthcare, food security and bioindustry. However, access to it has been hampered by the difficulty of accessing and growing the organisms for study. The discovery and exploitation of marine bioproducts for research and commercial development requires state-of-the-art technologies and innovative approaches. Technologies and approaches are advancing rapidly and keeping pace is expensive and time consuming. There is a pressing need for clear guidance that will allow researchers to operate in a way that enables the optimal return on their efforts whilst being fully compliant with the current regulatory framework. One major initiative launched to achieve this, has been the advent of European Research Infrastructures. Research Infrastructures (RI) and associated centres of excellence currently build harmonized multidisciplinary workflows that support academic and private sector users. The European Marine Biological Research Infrastructure Cluster (EMBRIC) has brought together six such RIs in a European project to promote the blue bio-economy. The overarching objective is to develop coherent chains of high-quality services for access to biological, analytical and data resources providing improvements in the throughput and efficiency of workflows for discovery of novel marine products. In order to test the efficiency of this prototype pipeline for discovery, 248 rarely-grown organisms were isolated and analysed, some extracts demonstrated interesting biochemical properties and are currently undergoing further analysis. EMBRIC has established an overarching and operational structure to facilitate the integration of the multidisciplinary value chains of services to access such resources whilst enabling critical mass to focus on problem resolution.Publisher PDFPeer reviewe

    Mineral Type and Solution Chemistry Affect the Structure and Composition of Actively Growing Bacterial Communities as Revealed by Bromodeoxyuridine Immunocapture and 16S rRNA Pyrosequencing

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    © 2016, Springer Science+Business Media New York. Understanding how minerals affect bacterial communities and their in situ activities in relation to environmental conditions are central issues in soil microbial ecology, as minerals represent essential reservoirs of inorganic nutrients for the biosphere. To determine the impact of mineral type and solution chemistry on soil bacterial communities, we compared the diversity, composition, and functional abilities of a soil bacterial community incubated in presence/absence of different mineral types (apatite, biotite, obsidian). Microcosms were prepared containing different liquid culture media devoid of particular essential nutrients, the nutrients provided only in the introduced minerals and therefore only available to the microbial community through mineral dissolution by biotic and/or abiotic processes. By combining functional screening of bacterial isolates and community analysis by bromodeoxyuridine DNA immunocapture and 16S rRNA gene pyrosequencing, we demonstrated that bacterial communities were mainly impacted by the solution chemistry at the taxonomic level and by the mineral type at the functional level. Metabolically active bacterial communities varied with solution chemistry and mineral type. Burkholderia were significantly enriched in the obsidian treatment compared to the biotite treatment and were the most effective isolates at solubilizing phosphorous or mobilizing iron, in all the treatments. A detailed analysis revealed that the 16S rRNA gene sequences of the OTUs or isolated strains assigned as Burkholderia in our study showed high homology with effective mineral-weathering bacteria previously recovered from the same experimental site

    Some Observations of the lamellar Morphology in Isotactic Polypropylene Spherulites by SFM

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    The lamellar morphology of intruded bulk samples of isotactic polypropylene has been investigated by scanning force microscopy. It is shown that SFM operated in the tapping mode is a powerful tool to characterize the texture of α\alpha and β\beta spherulites at the lamellar level. Structure, orientation and thickness of the lamellae have been determined in both cases.La microscopie de force atomique a été utilisée pour étudier la structure lamellaire d'échantillons massifs de polypropylène isotactique obtenus par intrusion. La microscopie de force atomique utilisée en tapping mode se révèle être un outil performant pour caractériser la texture des sphérolites α\alpha et β\beta à l'échelle lamellaire. La structure, l'orientation et l'épaisseur des lamelles ont été déterminées dans les deux cas
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