Sinteza i karakterizacija kompleksa cink(II), kadmijum(II), platina(II),i paladijum(II) sa kalijum-3-ditiokarboksi-3-aza-5-aminopentanoatom

Complexes of zinc(lI), cadmium(II). platinum(lI) and palladium(II) with a new poly-dentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap(-)), of the type M(daap)(2).nH(2)O (M = Zn(II), Cd(II), n = 2, or M = Pt(II) Pd(II) n = 0). have been prepared and characterized by elemental analysis. IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode.Reakcijom između cink(II), kadmijum(II), platina(II) i paladijum(II)-soli i kalijum- 3-ditiokarboksi-3-aza-5-aminopentanoata dobijeni su dogovarajući kompleksi tipa M(daap)2.nH2O. Izolovani kompleksi su okarakterisani elementarnom analizom, IR i UV/VIS spektroskopijom kao i merenjem magnetnih susceptibiliteta. Spektri kompleksa sugerišu bidentatnu koordinaciju daap liganda sa navedenim metalnim jonima preko atoma sumpora deprotonovane ditiokarbamato grupe. Kao dokaz navedenog načina koordinacije može poslužiti činjenica da pri istim eksperimentalnim uslovima S-metil estar liganda ne daje komplekse

Management of Massive Hemoptysis: A Single Institution Experience

Introduction: Definition of massive hemoptysis is unclear: criteria range from 100cc /day to 1000cc over a few days. Massive hemoptysis is seen in 1.5 % of all hemoptysis cases. Deaths occurring by exsanguination or asphyxiation from flooding of the alveoli with blood and intractable hypoxemia. The 3 principles of management of hemoptysis consist: 1) maintain airway patency and oxygenation, 2) localize the source of bleeding, 3) control hemorrhage. Consider surgery for lateralized uncontrollable massive hemoptysis unresponsive to other measures or as a definitive therapy in patients whose hemoptysis and general medical condition have stabilized. Objective: Analyses of our experience in treatment of 24 patients with severe hemoptysis for in single thoracic surgery Unit in SU”Shefqet Ndroqi” Tirana, Albania. Material and Methods: In a 5-year period 2009-2013, twenty-four patients were admitted in our hospital with massive hemoptysis. All patients are estimated by: Physical examination, CXR, CT Chest, Bronchoscopy and Arteriography. Fifteen 15 (62%) patients received surgical resection as a definitive therapy. Results: Of twenty-four patients enrolling in the study 18 were males and 6 females, mean age 54.9±13,7 years. The underlying pathology included bronchiectasis (n=5), active tuberculosis (n=9), pneumomycosis (n=7), lung cancer (n=2) and pulmonaryhydatic cyst(n=1). Hemoptysis ceased with conservative management in 9 patients (38%) only. Fifteen 15 (62%) patients received surgical resection. The procedures included lobectomy (n=13), bilobectomy (n=1) and pneumonectomy (n=1). The in-hospital mortality after surgery was 4.1% (1) patient. Redu-thoracotomy and right axillary open window in one patient. Postoperative morbidity occurred in 4 patients, including prolonged ventilatory support, bronchopleural fistulae, empyema and myocardial infarction. Conclusions: The clinical outcome for massive hemoptysis reflects the generalized nature of a destructive disease process involving both lungs and a limited respiratory reserve. Surgery is associated with high risk of morbidity and mortality, and should be performed only in selected patients.Keywords: masive Hemoptysis, Chest, Bronchoscopy and Arteriography, bronchopleural fistulae, empyema and myocardial infarction

Relationship between eruptions of active-region filaments and associated flares and CMEs

To better understand the dynamical process of active-region filament eruptions and associated flares and CMEs, we carried out a statistical study of 120 events observed by BBSO, TRACE, and t(SOHO/EIT) from 1998 to 2007 and combined filament observations with the NOAA's flare reports, MDI magnetograms, and LASCO data, to investigate the relationship between active-region filament eruptions and other solar activities. We found that 115 out of 120 filament eruptions are associated with flares. 56 out of 105 filament eruptions are found to be associated with CMEs except for 15 events without corresponding LASCO data. We note the limitation of coronagraphs duo to geometry or sensitivity, leading to many smaller CMEs that are Earth-directed or well out of the plane of sky not being detected by near-Earth spacecraft. Excluding those without corresponding LASCO data, the CME association rate of active-region filament eruptions clearly increases with X-ray flare class from about 32% for C-class flares to 100% for X-class flares. The eruptions of active-region filaments associated with Halo CMEs are often accompanied by large flares. About 92% events associated with X-class flare are associated with Halo CMEs. Such a result is due to that the Earth-directed CMEs detected as Halo CMEs are often the larger CMEs and many of the smaller ones are not detected because of the geometry and low intensity. The average speed of the associated CMEs of filament eruptions increases with X-ray flare size from 563.7 km/s for C-class flares to 1506.6 km/s for X-class flares. Moreover, the magnetic emergence and cancellation play an important role in triggering filament eruptions. These findings may be instructive to not only in respect to the modeling of active-region filament eruptions but also in predicting flares and CMEs.Comment: 19 Pages, 7 figures, Accepted for publication in MNRA

From bi-layer to tri-layer Fe nanoislands on Cu3Au(001)

Self assembly on suitably chosen substrates is a well exploited root to control the structure and morphology, hence magnetization, of metal films. In particular, the Cu3Au(001) surface has been recently singled out as a good template to grow high spin Fe phases, due to the close matching between the Cu3Au lattice constant (3.75 Angstrom) and the equilibrium lattice constant for fcc ferromagnetic Fe (3.65 Angstrom). Growth proceeds almost layer by layer at room temperature, with a small amount of Au segregation in the early stage of deposition. Islands of 1-2 nm lateral size and double layer height are formed when 1 monolayer of Fe is deposited on Cu3Au(001) at low temperature. We used the PhotoElectron Diffraction technique to investigate the atomic structure and chemical composition of these nanoislands just after the deposition at 140 K and after annealing at 400 K. We show that only bi-layer islands are formed at low temperature, without any surface segregation. After annealing, the Fe atoms are re-aggregated to form mainly tri-layer islands. Surface segregation is shown to be inhibited also after the annealing process. The implications for the film magnetic properties and the growth model are discussed.Comment: Revtex, 5 pages with 4 eps figure

A Parametric Study of Erupting Flux Rope Rotation. Modeling the "Cartwheel CME" on 9 April 2008

The rotation of erupting filaments in the solar corona is addressed through a parametric simulation study of unstable, rotating flux ropes in bipolar force-free initial equilibrium. The Lorentz force due to the external shear field component and the relaxation of tension in the twisted field are the major contributors to the rotation in this model, while reconnection with the ambient field is of minor importance. Both major mechanisms writhe the flux rope axis, converting part of the initial twist helicity, and produce rotation profiles which, to a large part, are very similar in a range of shear-twist combinations. A difference lies in the tendency of twist-driven rotation to saturate at lower heights than shear-driven rotation. For parameters characteristic of the source regions of erupting filaments and coronal mass ejections, the shear field is found to be the dominant origin of rotations in the corona and to be required if the rotation reaches angles of order 90 degrees and higher; it dominates even if the twist exceeds the threshold of the helical kink instability. The contributions by shear and twist to the total rotation can be disentangled in the analysis of observations if the rotation and rise profiles are simultaneously compared with model calculations. The resulting twist estimate allows one to judge whether the helical kink instability occurred. This is demonstrated for the erupting prominence in the "Cartwheel CME" on 9 April 2008, which has shown a rotation of \approx 115 degrees up to a height of 1.5 R_sun above the photosphere. Out of a range of initial equilibria which include strongly kink-unstable (twist Phi=5pi), weakly kink-unstable (Phi=3.5pi), and kink-stable (Phi=2.5pi) configurations, only the evolution of the weakly kink-unstable flux rope matches the observations in their entirety.Comment: Solar Physics, submitte

Multiwavelength studies of MHD waves in the solar chromosphere: An overview of recent results

The chromosphere is a thin layer of the solar atmosphere that bridges the relatively cool photosphere and the intensely heated transition region and corona. Compressible and incompressible waves propagating through the chromosphere can supply significant amounts of energy to the interface region and corona. In recent years an abundance of high-resolution observations from state-of-the-art facilities have provided new and exciting ways of disentangling the characteristics of oscillatory phenomena propagating through the dynamic chromosphere. Coupled with rapid advancements in magnetohydrodynamic wave theory, we are now in an ideal position to thoroughly investigate the role waves play in supplying energy to sustain chromospheric and coronal heating. Here, we review the recent progress made in characterising, categorising and interpreting oscillations manifesting in the solar chromosphere, with an impetus placed on their intrinsic energetics.Comment: 48 pages, 25 figures, accepted into Space Science Review

Assessing the quality of models of the ambient solar wind

In this paper we present an assessment of the status of models of the global Solar Wind in the inner heliosphere. We limit our discussion to the class of models designed to provide solar wind forecasts, excluding those designed for the purpose of testing physical processes in idealized configurations. In addition, we limit our discussion to modeling of the ‘ambient’ wind in the absence of coronal mass ejections. In this assessment we cover use of the models both in forecast mode and as tools for scientific research. We present a brief history of the development of these models, discussing the range of physical approximations in use. We discuss the limitations of the data inputs available to these models and its impact on their quality. We also discuss current model development trends

The Origin, Early Evolution and Predictability of Solar Eruptions

Coronal mass ejections (CMEs) were discovered in the early 1970s when space-borne coronagraphs revealed that eruptions of plasma are ejected from the Sun. Today, it is known that the Sun produces eruptive flares, filament eruptions, coronal mass ejections and failed eruptions; all thought to be due to a release of energy stored in the coronal magnetic field during its drastic reconfiguration. This review discusses the observations and physical mechanisms behind this eruptive activity, with a view to making an assessment of the current capability of forecasting these events for space weather risk and impact mitigation. Whilst a wealth of observations exist, and detailed models have been developed, there still exists a need to draw these approaches together. In particular more realistic models are encouraged in order to asses the full range of complexity of the solar atmosphere and the criteria for which an eruption is formed. From the observational side, a more detailed understanding of the role of photospheric flows and reconnection is needed in order to identify the evolutionary path that ultimately means a magnetic structure will erupt

An Observational Overview of Solar Flares

We present an overview of solar flares and associated phenomena, drawing upon a wide range of observational data primarily from the RHESSI era. Following an introductory discussion and overview of the status of observational capabilities, the article is split into topical sections which deal with different areas of flare phenomena (footpoints and ribbons, coronal sources, relationship to coronal mass ejections) and their interconnections. We also discuss flare soft X-ray spectroscopy and the energetics of the process. The emphasis is to describe the observations from multiple points of view, while bearing in mind the models that link them to each other and to theory. The present theoretical and observational understanding of solar flares is far from complete, so we conclude with a brief discussion of models, and a list of missing but important observations.Comment: This is an article for a monograph on the physics of solar flares, inspired by RHESSI observations. The individual articles are to appear in Space Science Reviews (2011

PROFIL WISATAWAN MUSEUM RADYA PUSTAKA SURAKARTA

Anggit Margaret, C9407031 2011. Profil Wisatawan Museum Radya Pustaka Surakarta. Program Studi Diploma III Usaha Perjalanan Wisata Fakultas Sastra Dan Seni Rupa Universitas Sebelas Maret Surakarta. Penelitian tugas akhir ini mengkaji tentang Profil Wisatawan di Museum Radya Pustaka Surakarta. Tujuan dari penelitian ini adalah untuk mengetahui dari daerah mana saja wisatawan yang berkunjung ke Museum Radya Pustaka, bagaimana ciri-ciri wisatawan yang berkunjung ke Museum Radya Pustaka serta harapan-harapan yang diinginkan wisatawan terhadap Museum Radya Pustaka. Penelitian dilakukan dengan metode kualitatif. Pengumpulan data dilakukan melalui wawancara dengan narasumber wisatawan yang berkujung di Museum Radya Pustaka Surakarta tempat penulis melakukan penelitian, serta studi pustaka dan studi dokumen guna menambah sumber data. Hasil penelitian menunjukkan bahwa (1) Sebagian besar wisatawan yang datang berasal dari Semarang sebesar 32%. (2) Mayoritas wisatawan yang berkunjung ke Museum Radya Pustaka berusia antara 17-25 tahun dan kebanyakan dari mereka adalah pelajar atau mahasiswa dengan prosentase 52%. (3) Sebagian besar wisatawan yang datang ke Museum Radya Pustaka adalah bertujuan untuk melakukan penelitian yaitu sebesar 34%. (4) Harapan wisatawan yang berkunjung terhadap kelangsungan Museum Radya Pustaka sebagian besar adalah agar ditingkatkan lagi pengelolaan dan keamanan museum, agar kejadian hilangnya benda-benda koleksi museum tidak terulang lagi dikemudian hari. Kesimpulan dari hasil penelitian ini bahwa wisatawan yang berkujung ke Museum Radya Pustaka Surakarta mayoritas berasal dari Semarang, mayoritas berusia 17-25 tahun dan kebanyakan dari mereka adalah berprofesi sebagai pelajar dan mahasiswa. Kebanyakan wisatawan yang datang bertujuan untuk melakukan penelitian, serta harapan wisatawan terhadap Museum Radya Pustaka adalah supaya lebih ditingkatkan lagi pengelolaan dan keamanan museum