55 research outputs found
The First Use of a ReX Synthon to Modulate Fe Spin Crossover via Supramolecular Halogenâ â â Halogen Interactions
We have added the {ReX} (X=Br, Cl) synthon to a pocketâbased ligand to provide supramolecular design using halogenâ
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halogen interactions within an Fe system that has the potential to undergo spin crossover (SCO). By removing the solvent from the crystal lattice, we âswitch onâ halogenâ
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halogen interactions between neighboring molecules, providing a supramolecular cooperative pathway for SCO. Furthermore, changes to the halogenâbased interaction allow us to modify the temperature and nature of the SCO event
Strong Nebular Line Ratios in the Spectra of z~2-3 Star-forming Galaxies: First Results from KBSS-MOSFIRE
We present initial results of a deep near-IR spectroscopic survey covering
the 15 fields of the Keck Baryonic Structure Survey (KBSS) using MOSFIRE on the
Keck 1 telescope, focusing on a sample of 251 galaxies with redshifts 2.0< z <
2.6, star-formation rates 2 < SFR < 200 M_sun/yr, and stellar masses 8.6 <
log(M*/M_sun) < 11.4, with high-quality spectra in both H- and K-band
atmospheric windows. We show unambiguously that the locus of z~2.3 galaxies in
the "BPT" nebular diagnostic diagram exhibits a disjoint, yet similarly tight,
relationship between the ratios [NII]6585/Halpha and [OIII]/Hbeta as compared
to local galaxies. Using photoionization models, we argue that the offset of
the z~2.3 locus relative to z~ 0 is explained by a combination of harder
ionizing radiation field, higher ionization parameter, and higher N/O at a
given O/H than applies to most local galaxies, and that the position of a
galaxy along the z~2.3 star-forming BPT locus is surprisingly insensitive to
gas-phase oxygen abundance. The observed nebular emission line ratios are most
easily reproduced by models in which the net ionizing radiation field resembles
a blackbody with effective temperature T_eff = 50000-60000 K and N/O close to
the solar value at all O/H. We critically assess the applicability of
commonly-used strong line indices for estimating gas-phase metallicities, and
consider the implications of the small intrinsic scatter in the empirical
relationship between excitation-sensitive line indices and stellar mass (i.e.,
the "mass-metallicity" relation), at z~2.3.Comment: 41 pages, 25 figures, accepted for publication in the Astrophysical
Journal. Version with full-resolution figures available at
http://www.astro.caltech.edu/~ccs/mos_bpt_submit.pd
Supramolecular assemblies involving metal organic ring interactions: Heterometallic Cu(II)-Ln(III) two dimensional coordination polymers
Three isostructural two-dimensional coordination polymers of the general formula [Ln2(CuL)3(H2O)9]$5.5H2O, where Ln is La (1), Nd (2), and Gd (3), have been synthesized and isolated from aqueous solutions and their single-crystal structures determined by X-ray diffraction. The supramolecular interaction between the non-aromatic metallorings plays an important role in stabilizing the structure of these compounds. The thermal stability, reversible solvent uptake, electronic properties and magnetic studies of these compounds are also reported
Galaxy Luminosity Functions to z~1: DEEP2 vs. COMBO-17 and Implications for Red Galaxy Formation
The DEEP2 and COMBO-17 surveys are used to study the evolution of the
luminosity function of red and blue galaxies to . Schechter function
fits show that, since , dims by 1.3 mag per unit redshift
for both color classes, of blue galaxies shows little change, while
for red galaxies has formally nearly quadrupled. At face value, the
number density of blue galaxies has remained roughly constant since ,
whereas that of red galaxies has been rising. Luminosity densities support both
conclusions, but we note that most red-galaxy evolution occurs between our data
and local surveys and in our highest redshift bin, where the data are weakest.
We discuss the implications of having most red galaxies emerge after
from precursors among the blue population, taking into account the properties
of local and distant E/S0s. We suggest a ``mixed'' scenario in which some blue
galaxies have their star-formation quenched in gas-rich mergers, migrate to the
red sequence with a variety of masses, and merge further on the red sequence in
one or more purely stellar mergers. E/S0s of a given mass today will have
formed via different routes, in a manner that may help to explain the
fundamental plane and other local scaling laws.Comment: Submitted to ApJ. 73 pages, 12 figures. Part II of a two-paper
series. The entire paper is available as a single postscript file at:
http://www.ucolick.org/~cnaw/paper2_submitted.ps.g
The DEEP2 Galaxy Redshift Survey: Design, Observations, Data Reduction, and Redshifts
We describe the design and data sample from the DEEP2 Galaxy Redshift Survey,
the densest and largest precision-redshift survey of galaxies at z ~ 1
completed to date. The survey has conducted a comprehensive census of massive
galaxies, their properties, environments, and large-scale structure down to
absolute magnitude M_B = -20 at z ~ 1 via ~90 nights of observation on the
DEIMOS spectrograph at Keck Observatory. DEEP2 covers an area of 2.8 deg^2
divided into four separate fields, observed to a limiting apparent magnitude of
R_AB=24.1. Objects with z < 0.7 are rejected based on BRI photometry in three
of the four DEEP2 fields, allowing galaxies with z > 0.7 to be targeted ~2.5
times more efficiently than in a purely magnitude-limited sample. Approximately
sixty percent of eligible targets are chosen for spectroscopy, yielding nearly
53,000 spectra and more than 38,000 reliable redshift measurements. Most of the
targets which fail to yield secure redshifts are blue objects that lie beyond z
~ 1.45. The DEIMOS 1200-line/mm grating used for the survey delivers high
spectral resolution (R~6000), accurate and secure redshifts, and unique
internal kinematic information. Extensive ancillary data are available in the
DEEP2 fields, particularly in the Extended Groth Strip, which has evolved into
one of the richest multiwavelength regions on the sky. DEEP2 surpasses other
deep precision-redshift surveys at z ~ 1 in terms of galaxy numbers, redshift
accuracy, sample number density, and amount of spectral information. We also
provide an overview of the scientific highlights of the DEEP2 survey thus far.
This paper is intended as a handbook for users of the DEEP2 Data Release 4,
which includes all DEEP2 spectra and redshifts, as well as for the
publicly-available DEEP2 DEIMOS data reduction pipelines. [Abridged]Comment: submitted to ApJS; data products available for download at
http://deep.berkeley.edu/DR4
Far-infrared characterization of an ultra-luminous starburst associated with a massively-accreting black hole at z=1.15
As part of the "All Wavelength Extended Groth Strip International Survey"
(AEGIS), we describe the panchromatic characterization of an X-ray luminous
active galactic nucleus (AGN) in a merging galaxy at z=1.15. This object is
detected at infrared (8mic, 24mic, 70mic, 160mic), submillimeter (850mic) and
radio wavelengths, from which we derive a bolometric luminosity L_bol ~ 9x10^12
Lsol. We find that the AGN clearly dominates the hot dust emission below 40mic
but its total energetic power inferred from the hard X-rays is substantially
less than the bolometric output of the system. About 50% of the infrared
luminosity is indeed produced by a cold dust component that probably originates
from enshrouded star formation in the host galaxy. In the context of a coeval
growth of stellar bulges and massive black holes, this source might represent a
``transition'' object sharing properties with both quasars and luminous
starbursts. Study of such composite galaxies will help address how the star
formation and disk-accretion phenomena may have regulated each other at high
redshift and how this coordination may have participated to the build-up of the
relationship observed locally between the masses of black holes and stellar
spheroids.Comment: Accepted for publication in ApJL (AEGIS Special Edition) - 5 pages, 1
table, 3 figure
The DEEP2 Galaxy Redshift Survey: Design, Observations, Data Reduction, and Redshifts
We describe the design and data analysis of the DEEP2 Galaxy Redshift Survey, the densest and largest high-precision redshift survey of galaxies at z approx. 1 completed to date. The survey was designed to conduct a comprehensive census of massive galaxies, their properties, environments, and large-scale structure down to absolute magnitude MB = 20 at z approx. 1 via approx.90 nights of observation on the Keck telescope. The survey covers an area of 2.8 Sq. deg divided into four separate fields observed to a limiting apparent magnitude of R(sub AB) = 24.1. Objects with z approx. 0.7 to be targeted approx. 2.5 times more efficiently than in a purely magnitude-limited sample. Approximately 60% of eligible targets are chosen for spectroscopy, yielding nearly 53,000 spectra and more than 38,000 reliable redshift measurements. Most of the targets that fail to yield secure redshifts are blue objects that lie beyond z approx. 1.45, where the [O ii] 3727 Ang. doublet lies in the infrared. The DEIMOS 1200 line mm(exp 1) grating used for the survey delivers high spectral resolution (R approx. 6000), accurate and secure redshifts, and unique internal kinematic information. Extensive ancillary data are available in the DEEP2 fields, particularly in the Extended Groth Strip, which has evolved into one of the richest multiwavelength regions on the sky. This paper is intended as a handbook for users of the DEEP2 Data Release 4, which includes all DEEP2 spectra and redshifts, as well as for the DEEP2 DEIMOS data reduction pipelines. Extensive details are provided on object selection, mask design, biases in target selection and redshift measurements, the spec2d two-dimensional data-reduction pipeline, the spec1d automated redshift pipeline, and the zspec visual redshift verification process, along with examples of instrumental signatures or other artifacts that in some cases remain after data reduction. Redshift errors and catastrophic failure rates are assessed through more than 2000 objects with duplicate observations. Sky subtraction is essentially photon-limited even under bright OH sky lines; we describe the strategies that permitted this, based on high image stability, accurate wavelength solutions, and powerful B-spline modeling methods. We also investigate the impact of targets that appear to be single objects in ground-based targeting imaging but prove to be composite in Hubble Space Telescope data; they constitute several percent of targets at z approx. 1, approaching approx. 5%-10% at z > 1.5. Summary data are given that demonstrate the superiority of DEEP2 over other deep high-precision redshift surveys at z approx. 1 in terms of redshift accuracy, sample number density, and amount of spectral information. We also provide an overview of the scientific highlights of the DEEP2 survey thus far
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The DEEP2 Galaxy Redshift Survey: Design, Observations, Data Reduction, and Redshifts
We describe the design and data analysis of the DEEP2 Galaxy Redshift Survey, the densest and largest high-precision redshift survey of galaxies at z ~ 1 completed to date. The survey was designed to conduct a comprehensive census of massive galaxies, their properties, environments, and large-scale structure down to absolute magnitude M_B = â20 at z ~ 1 via ~90 nights of observation on the Keck telescope. The survey covers an area of 2.8 deg^2 divided into four separate fields observed to a limiting apparent magnitude of R_(AB) = 24.1. Objects with z âŸ0.7 are readily identifiable using BRI photometry and rejected in three of the four DEEP2 fields, allowing galaxies with z > 0.7 to be targeted ~2.5 times more efficiently than in a purely magnitude-limited sample. Approximately 60% of eligible targets are chosen for spectroscopy, yielding nearly 53,000 spectra and more than 38,000 reliable redshift measurements. Most of the targets that fail to yield secure redshifts are blue objects that lie beyond z ~ 1.45, where the [Oâii] 3727âĂ
doublet lies in the infrared. The DEIMOS 1200 line mm^(â1) grating used for the survey delivers high spectral resolution (R ~ 6000), accurate and secure redshifts, and unique internal kinematic information. Extensive ancillary data are available in the DEEP2 fields, particularly in the Extended Groth Strip, which has evolved into one of the richest multiwavelength regions on the sky. This paper is intended as a handbook for users of the DEEP2 Data Release 4, which includes all DEEP2 spectra and redshifts, as well as for the DEEP2 DEIMOS data reduction pipelines. Extensive details are provided on object selection, mask design, biases in target selection and redshift measurements, the spec2d two-dimensional data-reduction pipeline, the spec1d automated redshift pipeline, and the zspec visual redshift verification process, along with examples of instrumental signatures or other artifacts that in some cases remain after data reduction. Redshift errors and catastrophic failure rates are assessed through more than 2000 objects with duplicate observations. Sky subtraction is essentially photon-limited even under bright OH sky lines; we describe the strategies that permitted this, based on high image stability, accurate wavelength solutions, and powerful B-spline modeling methods. We also investigate the impact of targets that appear to be single objects in ground-based targeting imaging but prove to be composite in Hubble Space Telescope data; they constitute several percent of targets at z ~ 1, approaching ~5%â10% at z > 1.5. Summary data are given that demonstrate the superiority of DEEP2 over other deep high-precision redshift surveys at z ~ 1 in terms of redshift accuracy, sample number density, and amount of spectral information. We also provide an overview of the scientific highlights of the DEEP2 survey thus far
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