Role of crustal melting in petrogenesis of the Cretaceous Water Island Formation (Virgin Islands, northeast Antilles Island arc)

The latest Aptian to earliest Albian (~115 Ma) Water Island Fm in the Virgin Islands contains some of the oldest known arc-related strata in the Greater Antilles Island Arc. Hence, the unit is of considerable significance in tectonic reconstructions of initial subduction parameters along the long-lived destructive plate margin separating the North American and Caribbean Plates. Exposed Water Island strata are bimodal, consisting predominantly of altered dacite and rhyolite (originally called keratophyre; 65-85% SiO2) and subordinate degraded (spilite; 46-57% SiO2). TiO2 content of Water Island basalt averages approximately 0.5%, resembling borderline intermediate-Ti boninite basalts, consistent with low incompatible element abundances and low normalized light rare earth elements (LREE) with respect to Sm. Trace element patterns of the felsic suite, characterized by pronounced negative normalized anomalies for high field-strength elements (HFSE), low Sr/Y, and low absolute rare earth element (REE) abundances, and relatively flat normalized REE patterns, have analogues in plagiorhyolite suites from bimodal Cenozoic arcs, including the western Aleutians, Izu-Bonin, the Kermadecs, and South Sandwich. Relatively low incompatible element concentrations in plagiorhyolites and contrasting normalized incompatible trace element patterns in basalts preclude an origin of Water Island plagiorhyolite through MORB-type fractional crystallization. Compositions are consistent instead with melting models involving partial fusion of amphibole-bearing gabbro at low pressures (within the stability range of plagioclase) in response to introduction of heat and aqueous flux by arc-related basalt melts and associated hydrothermal fluids during transmission to the surface. Truncation of the basalt fractional crystallization trend at SiO2 = 57% indicates evolved island arc basalt (IAB) crystal fractionates were gradually displaced from crustal magma conduits by more buoyant plagiorhyolite melt, and trapped in underplated, sub-crustal magma chambers. Basalts have low (Ce/Ce*)N (average ˜ 0.78), indicating the presence of significant pelagic sediment (0.5 to 1.5% Atlantic Cretaceous pelagic sediment, AKPS). One subunit of relatively high-HFSE plagiorhyolite has (Ce/Ce*)N near-expected values, but another with low-HFSE has slightly lower than expected (Ce/Ce*)N, consistent with a small sediment component. Absence of intermediate andesite from the Water Island Fm is inconsistent, however, with basaltrhyolite magma mixing processes. Consequently, incorporation of sediment by low-HFSE plagiorhyolite is inferred to have resulted from re-melting of arc-related gabbro

Pre-arc basement complex and overlying early island arc strata, Southwestern Puerto Rico : overview, geologic evolution, and revised data bases

The pre-arc basement complex in southwestern Puerto Rico consists of rocks exposed in the Bermeja complex. The oldest rocks are highly serpentinized peridotites that occur in three belts (Monte del Estado, Río Guanajibo, and Sierra Bermeja). These serpentinites were emplaced into a sequence of Jurassic to mid-Cretaceous pelagic chert (Mariquita chert) that contains abundant rafts and blocks of N-MORB-type amphibolites (Las Palmas amphibolite) and tholeiite and associated trondhjemite fractionates (Lower Cajul MORB) also of N-MORB affinity. The rocks are apparently overlain by a younger sequence of pre-arc plateau basaltic and andesitic lava flows (Upper Cajul Formation) that occur in two distinct geographic sequences, one having E-MORB and the other OIB geochemical characteristics. Overlying these pre-arc rocks in western Puerto Rico are northwest-trending Late Cretaceous to Eocene (85 to 45Ma) island arc strata that chronologically overlap later volcanic phases in central Puerto Rico. These western Puerto Rico arc rocks have elevated incompatible element concentrations together with conspicuously shallow negative Nb-anomalies, slightly positive Zr-Hf anomalies, and exceedingly high OIB-like Nb/Zr, all indicative of enriched source compositions. Trace element patterns are reproduced by multiple component mixing models involving highly depleted spinel peridotite (RMM15 to 20) overprinted by small OIB-type (up to ~2%) and pelagic sediment components. Trace element abundances are too high to qualify Atlantic Cretaceous pelagic sediment as a potential contaminant, but mantle-melting models (f=0.25) are consistent with the incorporation of variable proportions of Caribbean Cretaceous pelagic sediment through northdipping subduction of the Caribbean basin. Anomalous two-pyroxene-bearing andesites with extraordinarily high SiO2/MgO compared with normal mantle basaltic compositions, also indicate the incorporation of Jurassic to Early Cretaceous pelagic chert from the Caribbean. The high degree of source enrichment in western Puerto Rico is inconsistent with regional within-plate plume tectonics. Instead, it is inferred that the younger north-dipping western Puerto Rico arc (dating from ~85Ma) sampled an upper mantle enrichment zone generated in the backarc region of the older (125 to ~85Ma) south-dipping arc system in central Puerto Rico

Cretaceous to Mid-Eocene pelagic sediment budget in Puerto Rico and the Virgin Islands (northeast Antilles Island arc)

Island arc basalts (IAB) in the Greater Antilles, dating between Albian and mid-Eocene time (~112 to 45 Ma), consist of an early low-K, primitive island arc (PIA) basalt series and a later, predominantly intermediate calcalkaline (CA) series. The rocks resemble modern sediment-poor, low-light rare earth element (LREE)/heavy rare earth element (HREE) arc basalts from intra-oceanic tectonic settings and sediment-rich, high-LREE/HREE types from continental margin arcs, respectively. Isotope and incompatible trace element distribution along a 450 km segment of the arc in the northeast Antilles demonstrates that low-LREE/HREE basalts predominate in Albian to Santonian (~85 Ma) stratigraphic sequences in the Virgin Islands (VI) and northeast Puerto Rico (NEPR), while there is a gradual but spectacular increase in both LREE/HREE and absolute abundances of incompatible elements in central Puerto Rico (CPR). Northeastern Antilles basalts have consistently elevated La/Nb and relatively low Nb/Zr, both inconsistent with the presence of a significant ocean island basalt component. Hence, observed differences are interpreted to reflect variation in proportions of pelagic sediment subducted by the south-dipping Antilles arc system as it swept north-eastward across the Caribbean region and eventually approached the Bahama Banks along the south-eastern fringes of the North American Plate. Trace element mixing models indicate sediment proportions in VI and NEPR were limited, averaging considerably below 1.0%. In comparison sediment content in CPR increased from an average slightly above 1.0% in Albian (~112 Ma) basalts to as high as 8% in Cenomanian (100-94 Ma) types. Hypothetical pre-arc pelagic sedimentary facies in the subducted proto-Atlantic (or proto-Caribbean) basin, included 1) a young, centrally located longitudinal ridge-crest facies, with a thin sediment cover, eventually subducted by VI and NEPR, 2) a slightly older basin-margin facies of variable width and moderate sediment thickness, subducted by CPR during Albian time, and 3) a thick, pre-arc continental margin facies in the vicinity of Central America, subducted by CPR during Cenomanian time. Following collision of neighboring Hispaniola with the Bahamas sediment budgets in the northeast Antilles stabilized at moderate levels from 2 to 3%, reflecting widespread subduction of North Atlantic Cretaceous pelagic sediment (AKPS)

Petrogenesis of fertile mantle peridotites from the Monte del Estado massif (Southwest Puerto Rico): a preserved section of Proto-Caribbean lithospheric mantle?

The Monte del Estado massif is the largest and northernmost serpentinized peridotite belt in southwest Puerto Rico. It is mainly composed of spinel lherzolite and minor harzburgite with variable clinopyroxene modal abundances. Mineral and whole rock major and trace element compositions of peridotites coincide with those of fertile abyssal mantle rocks from mid ocean ridges. Peridotites lost 2-14 wt% of relative MgO and variable amounts of CaO by serpentinization and seafloor weathering. HREE contents in whole rock indicate that the Monte del Estado peridotites are residues after low to moderate degrees (2-15%) of fractional partial melting in the spinel stability field. However, very low LREE/HREE and MREE/HREE in clinopyroxene cannot be explained by melting models of a spinel lherzolite source and support that the Monte del Estado peridotites experienced initial low fractional melting degrees (~ 4%) in the garnet stability field. The relative enrichment of LREE in whole rock is not due to alteration processes but probably reflects the capture of percolating fluid/melt fractions or the crystallization of sub-percent amounts of hydrous minerals (e.g., amphibole, phlogopite) along grain boundaries or as microinclusions in minerals. We propose that the Monte del Estado peridotite belt represents a section of ancient Proto-Caribbean (Atlantic) lithospheric mantle originated by seafloor spreading between North and South America in the Late Jurassic- Early Cretaceous. This portion of oceanic lithospheric mantle was subsequently trapped in the forearc region of the Greater Antilles paleo-island arc generated by the northward subduction of the Caribbean plate beneath the Proto-Caribbean ocean. Finally, the Monte del Estado peridotites belt was emplaced in the Early Cretaceous probably as result of the change in subduction polarity of the Greater Antilles paleo-island arc without having been significantly modified by subduction processes

Measurement of the B0-anti-B0-Oscillation Frequency with Inclusive Dilepton Events

The $B^0$-$\bar B^0$ oscillation frequency has been measured with a sample of 23 million \B\bar B pairs collected with the BABAR detector at the PEP-II asymmetric B Factory at SLAC. In this sample, we select events in which both B mesons decay semileptonically and use the charge of the leptons to identify the flavor of each B meson. A simultaneous fit to the decay time difference distributions for opposite- and same-sign dilepton events gives $\Delta m_d = 0.493 \pm 0.012{(stat)}\pm 0.009{(syst)}$ ps$^{-1}$.Comment: 7 pages, 1 figure, submitted to Physical Review Letter

Measurement of the CP-Violating Asymmetry Amplitude sin2β\beta

We present results on time-dependent CP-violating asymmetries in neutral B decays to several CP eigenstates. The measurements use a data sample of about 88 million Y(4S) --> B Bbar decays collected between 1999 and 2002 with the BABAR detector at the PEP-II asymmetric-energy B Factory at SLAC. We study events in which one neutral B meson is fully reconstructed in a final state containing a charmonium meson and the other B meson is determined to be either a B0 or B0bar from its decay products. The amplitude of the CP-violating asymmetry, which in the Standard Model is proportional to sin2beta, is derived from the decay-time distributions in such events. We measure sin2beta = 0.741 +/- 0.067 (stat) +/- 0.033 (syst) and |lambda| = 0.948 +/- 0.051 (stat) +/- 0.017 (syst). The magnitude of lambda is consistent with unity, in agreement with the Standard Model expectation of no direct CP violation in these modes

Role of crustal melting in petrogenesis of the Cretaceous Water Island Formation (Virgin Islands, northeast Antilles Island arc)

The latest Aptian to earliest Albian (~115 Ma) Water Island Fm in the Virgin Islands contains some of the oldest known arc-related strata in the Greater Antilles Island Arc. Hence, the unit is of considerable significance in tectonic reconstructions of initial subduction parameters along the long-lived destructive plate margin separating the North American and Caribbean Plates. Exposed Water Island strata are bimodal, consisting predominantly of altered dacite and rhyolite (originally called keratophyre; 65-85% SiO2) and subordinate degraded (spilite; 46-57% SiO2). TiO2 content of Water Island basalt averages approximately 0.5%, resembling borderline intermediate-Ti boninite basalts, consistent with low incompatible element abundances and low normalized light rare earth elements (LREE) with respect to Sm. Trace element patterns of the felsic suite, characterized by pronounced negative normalized anomalies for high field-strength elements (HFSE), low Sr/Y, and low absolute rare earth element (REE) abundances, and relatively flat normalized REE patterns, have analogues in plagiorhyolite suites from bimodal Cenozoic arcs, including the western Aleutians, Izu-Bonin, the Kermadecs, and South Sandwich. Relatively low incompatible element concentrations in plagiorhyolites and contrasting normalized incompatible trace element patterns in basalts preclude an origin of Water Island plagiorhyolite through MORB-type fractional crystallization. Compositions are consistent instead with melting models involving partial fusion of amphibole-bearing gabbro at low pressures (within the stability range of plagioclase) in response to introduction of heat and aqueous flux by arc-related basalt melts and associated hydrothermal fluids during transmission to the surface. Truncation of the basalt fractional crystallization trend at SiO2 = 57% indicates evolved island arc basalt (IAB) crystal fractionates were gradually displaced from crustal magma conduits by more buoyant plagiorhyolite melt, and trapped in underplated, sub-crustal magma chambers. Basalts have low (Ce/Ce*)N (average ˜ 0.78), indicating the presence of significant pelagic sediment (0.5 to 1.5% Atlantic Cretaceous pelagic sediment, AKPS). One subunit of relatively high-HFSE plagiorhyolite has (Ce/Ce*)N near-expected values, but another with low-HFSE has slightly lower than expected (Ce/Ce*)N, consistent with a small sediment component. Absence of intermediate andesite from the Water Island Fm is inconsistent, however, with basaltrhyolite magma mixing processes. Consequently, incorporation of sediment by low-HFSE plagiorhyolite is inferred to have resulted from re-melting of arc-related gabbro

Pre-arc basement complex and overlying early island arc strata, Southwestern Puerto Rico : overview, geologic evolution, and revised data bases

The pre-arc basement complex in southwestern Puerto Rico consists of rocks exposed in the Bermeja complex. The oldest rocks are highly serpentinized peridotites that occur in three belts (Monte del Estado, Río Guanajibo, and Sierra Bermeja). These serpentinites were emplaced into a sequence of Jurassic to mid-Cretaceous pelagic chert (Mariquita chert) that contains abundant rafts and blocks of N-MORB-type amphibolites (Las Palmas amphibolite) and tholeiite and associated trondhjemite fractionates (Lower Cajul MORB) also of N-MORB affinity. The rocks are apparently overlain by a younger sequence of pre-arc plateau basaltic and andesitic lava flows (Upper Cajul Formation) that occur in two distinct geographic sequences, one having E-MORB and the other OIB geochemical characteristics. Overlying these pre-arc rocks in western Puerto Rico are northwest-trending Late Cretaceous to Eocene (85 to 45Ma) island arc strata that chronologically overlap later volcanic phases in central Puerto Rico. These western Puerto Rico arc rocks have elevated incompatible element concentrations together with conspicuously shallow negative Nb-anomalies, slightly positive Zr-Hf anomalies, and exceedingly high OIB-like Nb/Zr, all indicative of enriched source compositions. Trace element patterns are reproduced by multiple component mixing models involving highly depleted spinel peridotite (RMM15 to 20) overprinted by small OIB-type (up to ~2%) and pelagic sediment components. Trace element abundances are too high to qualify Atlantic Cretaceous pelagic sediment as a potential contaminant, but mantle-melting models (f=0.25) are consistent with the incorporation of variable proportions of Caribbean Cretaceous pelagic sediment through northdipping subduction of the Caribbean basin. Anomalous two-pyroxene-bearing andesites with extraordinarily high SiO2/MgO compared with normal mantle basaltic compositions, also indicate the incorporation of Jurassic to Early Cretaceous pelagic chert from the Caribbean. The high degree of source enrichment in western Puerto Rico is inconsistent with regional within-plate plume tectonics. Instead, it is inferred that the younger north-dipping western Puerto Rico arc (dating from ~85Ma) sampled an upper mantle enrichment zone generated in the backarc region of the older (125 to ~85Ma) south-dipping arc system in central Puerto Rico

Cretaceous to Mid-Eocene pelagic sediment budget in Puerto Rico and the Virgin Islands (northeast Antilles Island arc)

Island arc basalts (IAB) in the Greater Antilles, dating between Albian and mid-Eocene time (~112 to 45 Ma), consist of an early low-K, primitive island arc (PIA) basalt series and a later, predominantly intermediate calcalkaline (CA) series. The rocks resemble modern sediment-poor, low-light rare earth element (LREE)/heavy rare earth element (HREE) arc basalts from intra-oceanic tectonic settings and sediment-rich, high-LREE/HREE types from continental margin arcs, respectively. Isotope and incompatible trace element distribution along a 450 km segment of the arc in the northeast Antilles demonstrates that low-LREE/HREE basalts predominate in Albian to Santonian (~85 Ma) stratigraphic sequences in the Virgin Islands (VI) and northeast Puerto Rico (NEPR), while there is a gradual but spectacular increase in both LREE/HREE and absolute abundances of incompatible elements in central Puerto Rico (CPR). Northeastern Antilles basalts have consistently elevated La/Nb and relatively low Nb/Zr, both inconsistent with the presence of a significant ocean island basalt component. Hence, observed differences are interpreted to reflect variation in proportions of pelagic sediment subducted by the south-dipping Antilles arc system as it swept north-eastward across the Caribbean region and eventually approached the Bahama Banks along the south-eastern fringes of the North American Plate. Trace element mixing models indicate sediment proportions in VI and NEPR were limited, averaging considerably below 1.0%. In comparison sediment content in CPR increased from an average slightly above 1.0% in Albian (~112 Ma) basalts to as high as 8% in Cenomanian (100-94 Ma) types. Hypothetical pre-arc pelagic sedimentary facies in the subducted proto-Atlantic (or proto-Caribbean) basin, included 1) a young, centrally located longitudinal ridge-crest facies, with a thin sediment cover, eventually subducted by VI and NEPR, 2) a slightly older basin-margin facies of variable width and moderate sediment thickness, subducted by CPR during Albian time, and 3) a thick, pre-arc continental margin facies in the vicinity of Central America, subducted by CPR during Cenomanian time. Following collision of neighboring Hispaniola with the Bahamas sediment budgets in the northeast Antilles stabilized at moderate levels from 2 to 3%, reflecting widespread subduction of North Atlantic Cretaceous pelagic sediment (AKPS)