Titan's lakes chemical composition: sources of uncertainties and variability

Between 2004 and 2007 the instruments of the CASSINI spacecraft discovered hydrocarbon lakes in the polar regions of Titan. We have developed a lake-atmosphere equilibrium model allowing the determination of the chemical composition of these liquid areas. The model is based on uncertain thermodynamic data and precipitation rates of organic species predicted to be present in the lakes and seas that are subject to spatial and temporal variations. Here we explore and discuss the influence of these uncertainties and variations. The errors and uncertainties relevant to thermodynamic data are simulated via Monte-Carlo simulations. Global Circulation Models (GCM) are also employed in order to investigate the possibility of chemical asymmetry between the south and the north poles, due to differences in precipitation rates. We find that mole fractions of compounds in the liquid phase have a high sensitivity to thermodynamic data used as inputs, in particular molar volumes and enthalpies of vaporization. When we combine all considered uncertainties, the ranges of obtained mole fractions are rather large (up to ~8500%) but the distributions of values are narrow. The relative standard deviations remain between 10% and ~300% depending on the compound considered. Compared to other sources of uncertainties and variability, deviation caused by surface pressure variations are clearly negligible, remaining of the order of a few percent up to ~20%. Moreover no significant difference is found between the composition of lakes located in north and south poles. Because the theory of regular solutions employed here is sensitive to thermodynamic data and is not suitable for polar molecules such as HCN and CH3CN, our work strongly underlines the need for experimental simulations and the improvement of Titan's atmospheric models.Comment: Accepted in Planetary and Space Scienc

Titan's diverse landscapes as evidenced by Cassini RADAR's third and fourth looks at Titan

International audienceCassini's third and fourth radar flybys, T7 and T8, covered diverse terrains in the high southern and equatorial latitudes, respectively. The T7 synthetic aperture radar (SAR) swath is somewhat more straightforward to understand in terms of a progressive poleward descent from a high, dissected, and partly hilly terrain down to a low flat plain with embayments and deposits suggestive of the past or even current presence of hydrocarbon liquids. The T8 swath is dominated by dunes likely made of organic solids, but also contain somewhat enigmatic, probably tectonic, features that may be partly buried or degraded by erosion or relaxation in a thin crust. The dark areas in T7 show no dune morphology, unlike the dark areas in T8, but are radiometrically warm like the dunes. The Huygens landing site lies on the edge of the T8 swath; correlation of the radar and Huygens DISR images allows accurate determination of its coordinates, and indicates that to the north of the landing site sit two large longitudinal dunes. Indeed, had the Huygens probe trajectory been just 10 km north of where it actually was, images of large sand dunes would have been returned in place of the fluvially dissected terrain actually seen?illustrating the strong diversity of Titan's landscapes even at local scales

Are Titan's Lakes Liquid-filled?

SAR imagery obtained during Cassini's T16 Titan fly-by revealed numerous radar-dark features at > ~70° N, interpreted to be lakes [1] on the basis of their low radar reflectivity, morphology and consistency with predictions [2]. Later fly-bys revealed more lakes, and also overlapped with previous scenes, facilitating multi-angle, multi-temporal studies, with several more such opportunities over the coming months. Here we introduce our efforts to understand the nature of the lakes using such studies, focusing on one anomalous lake in particular, and address the issue of whether the observed lakes are liquid-filled or dry

The north polar lakes of Titan as observed by Cassini Radar

Over the course of a year, Cassini RADAR obtained Synthetic Aperture Radar images covering 69 percent of Titan's polar region north of 65 degrees; the region being 1.4E6 km3 in extent, greater than double the land area of the USA. We observe several hundred lakes with a range of morphological expression, including areally massive and morphologically distinctive "seas", covering ~15% of the polar region. Lakes are extremely radar dark, consistent with a lossy liquid hydrocarbon. Preliminary laboratory estimates suggest that loss tangents in the range 10E4 to 2x10E3 are reasonable, which implies that one can see through at least a few to many tens of m of liquids before the noise floor is reached, consistent with observed brightening towards many lake shores. North polar lake volumes are most likely in the 8E3 - 1.4E6 km3 range. Uncertainties will be reduced as more data, both image-based and experimental, are obtained but we can conclude with a high degree of confidence that hydrocarbon lakes on Titan are more voluminous than known terrestrial oil reserves; current estimates range from 2248 - 3896 billion barrels of oil (J. Hakes, 2000, Long Term World Oil Supply, Meeting of the Am. Ass. Pet. Geol., 18th April 2000, New Orleans, LA, http://www.eia.doe.gov/pub/oil_gas/petroleum/presentations/2000/long_term_supply.), hence 357 - 619 km3 . Small lakes often occupy steep-sided depressions, and although thermal and cryovolcanic origins cannot be completely ruled out, we are seeing growing geomorphologic evidence for dissolution chemistry, indicative of karst-like geology. The dichotomy between small lakes over slightly more than one half of the region, and seas on the other half, may be best explained by a topographic anomaly causing sub-surface flow of materials from the lakes to the seas. This may also explain observations by the Cassini ISS team (E. Turtle et al., in prep.) of a putative massive sea extending considerably further south than other observed north polar lakes

Varied Geologic Terrains at Titan's South Pole: First Results from T39

The Cassini RADAR pass T39 of the south polar region reveals extremely varied and in some cases complex surface morphologies, indicating that a range of geologic processes have operated, and are operating, in the region

The Case of Titan's Mysterious New Island: Analysis of Anomalously Bright Features Observed in the Cassini T92 SAR Pass Over Titan's Ligeia Mare

Anomalous features were detected in Ligeia Mare that were not in any preceding nor subsequent observations. They are unique on Titan or transient in nature