Changing eruptive styles and textural features from phreatomagmatic to strombolian activity of basaltic littoral cones: Los Erales cinder cone, Tenerife, Canary Islands

Montaña Los Erales is a 70 m high Quaternary cinder cone in the Bandas del Sur region, south Tenerife. Field observations on excavated sections and SEM analysis of tephra samples from the cone suggest that the eruption style of this vent changed progressively from an initial hydrovolcanic phase, through a transitional stage, to one that was entirely strombolian. Clast sizes increase from ≤1 cm angular lapilli in hydrovolcanic samples to 15 cm bombs in strombolian samples. Vesicles also increase in size from 0.5 mm to 1.2 mm, becoming more rounded in the strombolian samples. Palagonitization, extensive in the hydrovolcanic deposits, becomes less noticeable in strombolian deposits. To investigate the causes for and the nature of these changes in eruptive style, products from each major unit were analysed for their morphology, using scanning electron microscopy with both SE and BSE imaging as tephra morphologies are known to reflect the eruptive regime and degree of explosivity at the time of eruption. SEM imaging of hydrovolcanic samples illustrate angular fragments that have been rapidly quenched and contain high levels of palagonitisation and zeolitisation, whereas strombolian samples appear to be less altered and display larger clast sizes and vesicles. Our results confirm that the initial phase of activity was largely driven by magma-water (coolant) interaction, where magma may have interacted with a lens of fresh ground or surface water, causing intense fragmentation of the magma. With proceeding eruptive activity the water became exhausted, giving rise to an entirely strombolian eruptive style. Additionally, fossil diatoms were found in hydrovolcanic samples, further emphasising the influence of a, probably fluvial, water source during the early phase of emplacement.La Montaña de Los Erales es un cono de cínder del Cuaternario de 70 m de altura situado en la zona de las Bandas del Sur, en el litoral meridional de la isla de Tenerife. Observaciones de campo en secciones excavadas en los flancos del cono y análisis SEM de las muestras de tefra sugieren que el estilo eruptivo de este aparato volcánico cambió progresivamente durante la erupción de una fase inicial hidrovolcánica a una final enteramente estromboliana, con estadios intermedios transicionales. El tamaño de los clastos aumenta de ≤1 cm de lapilli angular en las muestras hidrovolcánicas a bombas de 15 cm en las estrombolianas. Las vesículas también aumentan en tamaño desde 0,5 mm a 1,2 mm, volviéndose más redondeadas en las muestras estrombolianas. Los intensos procesos de palagonitización de los depósitos hidrovolcánicos son menos significativos en las fases estrombolianas. Con objeto de investigar la naturaleza y las causas de estos cambios se analizó la morfología de los productos de las principales fases. Se han utilizado para ello imágenes de microscopía electrónica (SE y BSE), ya que se sabe que las diferentes morfologías de estos piroclastos reflejan el régimen eruptivo y el grado de explosividad durante la erupción. Las imágenes SEM de las muestras hidrovolcánicas presentan fragmentos angulares que se han enfriado rápidamente y con elevado grado de palagonitización y zeolitización. Las estrombolianas, en cambio, aparecen menos alteradas y muestran mayor tamaño de clastos y vesículas. Los resultados obtenidos indican que la fase inicial de la erupción se caracteriza por una importante interacción magma-agua (refrigerante), probablemente relacionada con una cantidad limitada de agua superficial o freática que produjo la intensa fragmentación del magma. En el transcurso de la erupción la fuente de agua se agotó, dando lugar a las fases finales de carácter enteramente estromboliano. Fósiles de diatomeas, que se han encontrado asociados a las muestras hidrovolcánicas, refuerzan la posibilidad de que el agua fuera de origen superficial, probablemente el cauce de un barranco

Floating stones off El Hierro, Canary Islands: xenoliths of pre-island sedimentary origin in the early products of the October 2011 eruption

The eruption that started off the south coast of El Hierro, Canary Islands, in October 2011 has emitted intriguing eruption products found floating in the sea. These specimens appeared as floating volcanic "bombs" that have in the meantime been termed "restingolites" (after the close-by village of La Restinga) and exhibit cores of white and porous pumice-like material. Currently the nature and origin of these "floating stones" is vigorously debated among researchers, with important implications for the interpretation of the hazard potential of the ongoing eruption. The "restingolites" have been proposed to be either (i) juvenile high-silica magma (e.g. rhyolite), (ii) remelted magmatic material (trachyte), (iii) altered volcanic rock, or (iv) reheated hyaloclastites or zeolite from the submarine slopes of El Hierro. Here, we provide evidence that supports yet a different conclusion. We have collected and analysed the structure and composition of samples and compared the results to previous work on similar rocks found in the archipelago. Based on their high silica content, the lack of igneous trace element signatures, and the presence of remnant quartz crystals, jasper fragments and carbonate relicts, we conclude that "restingolites" are in fact xenoliths from pre-island sedimentary rocks that were picked up and heated by the ascending magma causing them to partially melt and vesiculate. They hence represent messengers from depth that help us to understand the interaction between ascending magma and crustal lithologies in the Canary Islands as well as in similar Atlantic islands that rest on sediment/covered ocean crust (e.g. Cape Verdes, Azores). The occurrence of these "restingolites" does therefore not indicate the presence of an explosive high-silica magma that is involved in the ongoing eruption

Petrology and geochemistry of Cardeña-Virgen de La Cabeza pluton (batholith of Los Pedroches)

[Resumen] El plutón de Cardeña-Virgen de La Cabeza es uno de los cuerpos intrusivos que integran la unidad granítica del batolito de Los Pedroches. Dentro de este plutón, se ha establecido el emplazamiento sucesivo en el tiempo de: 1) adamellitas biotíticas, 2) granitos biotíticos porfídicos ± cordierita, 3) leucogranitos ± cordierita. Las adamellitas biotíticas muestran localmente paso gradual hacia las facies granodioríticas del batolito. Existe además un importante complejo filoniano que se intruye posteriormente, formado por diques riodacíticos de dirección NO-SE, lamprófidos, aplitas, pegmatitas y filones mineralizados· de cuarzo. Geoquímicamente, la adamellita y el granito biotítico porfídico constituyen una asociación alumino-cafémica de carácter calcoalcalino. Los enclaves anfibólicos (términos cafémicos) poseen carácter metaaluminoso. Los leucogranitos se desvían de la tendencia general definiendo una asociación aluminosa y leucocrática. Los diagramas de variación para elementos mayores, menores, trazas y tierras.raras de adamellitas, granitos biotíticos porfídicos y de granodioritas, rocas, estas últimas, con las que se encuentran íntimamente relacionadas, son compatibles con procesos de diferenciación magmática por cristalización fraccionada a partir de un magma inicial de composición granodiorítica más básico[Abstract] The Cardeña-Virgen de La Cabeza intrusion belongs to the granitic unit of the Los Pedroches batholith. the chronology of the intrusion of the different rocktypes that make up the pluton is as follows: 1) biotitic adamellite, 2) porphyritic, cordierite-bearing, biotitic granite. 3) cordierite bearing leucogranite. The biotitic adamellite locally shows a transition to the granodioritic facies of the batholith. A great amount ofNW-SW oriented dikes with rhyodacitic composition intruded subsequently. Lampophyres, aplites, pegmatites and ore-bearing quartz veins complete the dike complexo Adamellite and biotitic ganite define an aluminous-cafemic association with calcalkaline affinity. The amphibole-bearing enclaves represent the cafemic terms of the series and have a metaaluminous character.The leucogranite deviates from the general trend defining and aluminous, leucocratic association. Variation diagrams for major, minor and trace elements, including REE, of adamallite, porphyritic biotitic granite and granodiorite of the main pluton (which is intimately associated with the Cardeña-Virgen de La Cabeza intrusion) suggest a process of magmatic differentiation through fractional crystallization starting from a slightly more basic granodioritic magma

Lanthanides in granulometric fractions of Mediterranean soils. Can they be used as fingerprints of provenance?

Highlights Are lanthanides from fine sand and clay genetically related to the geological materials? Lanthanide concentrations of fine sand and clay fit chronofunctions Pearson's r of lanthanide couples decreases when separation increases in the periodic table Free forms of clay are scavengers of lanthanides and concentrate HREE and ceriumSample preparation and chemical analysis were conducted by Emma Humphreys-Williams and Stanislav Strekopytov (Imaging and Analysis Centre, Natural History Museum, London, UK). This work was supported by a grant from Ministerio de Economía, Industria y Competitividad de España (‘Tipologías de Suelos Mediterráneos versus Cuarzo. En la frontera del conocimiento edafogenético’; Ref. CGL2016-80308-P). The authors thank Professor Margaret A. Oliver, an anonymous editor and two anonymous reviewers for helpful comments and suggestions that improved the final manuscript. We also thank Robert Abrahams (Bsc) for revising the English language.There is geochemical interest in the lanthanides because they behave like a group that is closely related to the parent materials during surface processes, although they also undergo fractionation as a result of supergene dynamics. We analysed lanthanide concentrations (ICPms) in the granulometric fractions fine sand, clay and free forms of clay (FFclay‐CDB and FFclay‐Ox: extracted with citrate‐dithionite‐sodium bicarbonate and with ammonium oxalate, respectively) from a soil chronosequence of Mediterranean soils. There was a relative enrichment of heavy rare earth elements (HREE) in the clay fraction and its free forms with respect to fine sand. The clay free forms behaved as scavengers of lanthanides, and oxidative scavenging of cerium (Ce) in FFclay‐CDB was also detected. Lanthanide concentrations (lanthanum to gadolinium in fine sand; terbium to lutetium in clay) varied with soil age, and chronofunctions were established. There was a strong positive collinearity between most of the lanthanide concentrations. Furthermore, the value of the correlation index (Pearson's r ) of the concentrations between couples of lanthanides (r CLC) decreased significantly with increasing separation between the elements in the periodic table; this has never been described in soils. Several geochemical properties and indices in the fine sand and clay soil fractions and in the geological materials of the Guadalquivir catchment showed, on the one hand, a genetic relation between them all, enabling the lanthanides to be used as fingerprints of provenance; on the other hand, fractionation between fine sand and clay showed these are actively involved in soil lanthanide dynamics.Secretaría de Estado de Investigación, Desarrollo e Innovación. Grant Number: CGL2016‐80308‐

La gran erupción de hace 4.2 ka cal en Cerro Blanco, Zona Volcánica Central, Andes: nuevos datos sobre los depósitos eruptivos holocenos en la Puna sur y regiones adyacentes

The eruption of the Cerro Blanco Volcanic Complex, in the southern Puna, NW Argentina dated at 4410–4150 a cal BP, was investigated to produce new information on stratigraphy, geomorphology, physical volcanology, radiocarbon dating, petrography, and geochemistry. Identification of pre–, syn–, and post–caldera products allowed us to estimate the distribution of the Plinian fallout during the paroxysmal syn–caldera phase of the eruption. The new results provide evidence for a major rhyolitic explosive eruption that spread volcanic deposits over an area of ~500,000 km2, accumulating > 100 km3 of tephra (bulk volume). This last value exceeds the lower threshold of Volcanic Explosive Index (VEI) of 7. Ash-fall deposits mantled the region at distances > 400 km from source and thick pyroclastic-flow deposits filled neighbouring valleys up to 35 km away. This eruption is the largest documented during the past five millennia in the Central Volcanic Zone of the Andes, and is probably one of the largest Holocene explosive eruptions in the world. We have also identified two additional rhyolitic eruptions in the region from two other eruptive sources: one during the Early–Holocene and another in the Late–Holocene. The identification and characterisation of these significant volcanic events provide new constraints into regional Holocene geological and archaeological records, and offer extensive regional chronostratigraphic markers over a wide geographical area of South America.La erupción del Complejo Volcánico Cerro Blanco en el sur de la Puna, noroeste de Argentina (4410–4150 a BP) se investigó para obtener nueva información sobre estratigrafía, geomorfología, volcanología física, dataciones por radiocarbono, petrografía y geoquímica. La caracterización de los productos en relación a la evolución de la caldera de Cerro Blanco permitió estimar la distribución de los depósitos de ceniza de la fase paroxísmica Plineana de la erupción. Estos novedosos resultados evidencian una gran erupción explosiva riolítica que generó depósitos cineríticos en un área de aproximadamente 500.000 km2, acumulando > 100 km3 de tefra (volumen total). Este último valor supera el umbral inferior del Índice de Explosividad Volcánica (IEV) de 7. Los depósitos de caída de ceniza cubrieron la región, llegando a más de 400 km desde el Complejo Volcánico de Cerro Blanco, y los potentes depósitos de flujos piroclásticos rellenaron los valles vecinos alcanzando una distancia de 35 km. Esta erupción es la más grande documentada durante los últimos cinco milenios en la Zona Volcánica Central de los Andes y es probablemente una de las mayores erupciones explosivas holocenas del mundo. Además, se han identificado otras dos erupciones riolíticas en la región procedentes de otros dos centros eruptivos: una durante el Holoceno temprano y otra en el Holoceno tardío. La identificación y caracterización de estos grandes eventos volcánicos proporcionan nuevas guías para los registros geológicos y arqueológicos regionales del Holoceno, siendo marcadores cronostratigráficos de aplicación a una extensa área geográfica de América del Sur

Three novel mutations in the CFTR gene identified in Galician patients

AbstractWe report three novel CFTR missense mutations detected in Spanish patients from Galicia (North West of Spain). In the first case, a patient homozygous for a novel S1045Y mutation died due to pulmonary problems. In the other two cases, both heterozygous for novel mutations combined with the F508del mutation, clinical symptoms were different depending on the mutation, detected as M595I and A107V

The long-lived Type IIn SN 2015da: Infrared echoes and strong interaction within an extended massive shell star star star

In this paper we report the results of the first similar to four years of spectroscopic and photometric monitoring of the Type IIn supernova SN 2015da (also known as PSN J13522411+3941286, or iPTF16tu). The supernova exploded in the nearby spiral galaxy NGC 5337 in a relatively highly extinguished environment. The transient showed prominent narrow Balmer lines in emission at all times and a slow rise to maximum in all bands. In addition, early observations performed by amateur astronomers give a very well-constrained explosion epoch. The observables are consistent with continuous interaction between the supernova ejecta and a dense and extended H-rich circumstellar medium. The presence of such an extended and dense medium is difficult to reconcile with standard stellar evolution models, since the metallicity at the position of SN 2015da seems to be slightly subsolar. Interaction is likely the mechanism powering the light curve, as confirmed by the analysis of the pseudo bolometric light curve, which gives a total radiated energy greater than or similar to 10(51) erg. Modeling the light curve in the context of a supernova shock breakout through a dense circumstellar medium allowed us to infer the mass of the prexisting gas to be similar or equal to 8 M-circle dot, with an extreme mass-loss rate for the progenitor star similar or equal to 0.6 M-circle dot yr(-1), suggesting that most of the circumstellar gas was produced during multiple eruptive events. Near- and mid-infrared observations reveal a fluxexcess in these domains, similar to those observed in SN 2010jl and other interacting transients, likely due to preexisting radiatively heated dust surrounding the supernova. By modeling the infrared excess, we infer a mass greater than or similar to 0.4 x 10(-3) M-circle dot for the dustSpanish MICINN gran

A genetic case-control study confirms the implication of SMAD7 and TNF locus in the development of proliferative vitreoretinopathy

PURPOSE: Proliferative vitreoretinopathy (PVR) is still the major cause of failure of retinal detachment (RD) surgery and although the risk for developing this complication is associated with some clinical characteristics, the correlation is far from absolute, raising the possibility of genetic susceptibility. The objective of this study was to analyze the genetic contribution to PVR in patients undergoing RD surgery, the Retina 4 Project. METHODS: A candidate gene association study was conducted in 2006 in a Spanish population of 450 patients suffering from primary rhegmatogenous RD. Replication was carried out in a larger population undergoing RD surgery at several European centers among 546 new patients. Single nucleotide polymorphism (SNP) of 30 genes known to be involved with inflammation were analyzed. For replication stage, those genes previously detected as significantly associated with PVR were genotyped. Distribution of allelic and haplotypic frequencies in case and control group were analyzed. Single and haplotypic analysis were assessed. The Rosenberg two-stage method was used to correct for single and multiple analyses. RESULTS: After correction for multiple comparisons, four genes were significantly associated with PVR: SMAD7 (P = 0.004), PIK3CG (P = 0.009), TNF locus (P = 0.0005), and TNFR2 (P = 0.019) In the European sample, replication was observed in SMAD7 (P = 0.047) and the TNF locus (P = 0.044). CONCLUSIONS: These results confirm the genetic contribution to PVR and the implication of SMAD7 and TNF locus in the development of PVR. This finding may have implications for understanding the mechanisms of PVR and could provide a potential new therapeutic target for PVR prophylaxis

The helicase HAGE prevents interferon-a-induced PML expression in ABCB5+ malignant melanoma-initiating cells by promoting the expression of SOCS1

The tumour suppressor PML (promyelocytic leukaemia protein) regulates several cellular pathways involving cell growth, apoptosis, differentiation and senescence. PML also has an important role in the regulation of stem cell proliferation and differentiation. Here, we show the involvement of the helicase HAGE in the transcriptional repression of PML expression in ABCB5 + malignant melanoma-initiating cells (ABCB5 + MMICs), a population of cancer stem cells which are responsible for melanoma growth, progression and resistance to drug-based therapy. HAGE prevents PML gene expression by inhibiting the activation of the JAK-STAT (janus kinase-signal transducers and activators of transcription) pathway in a mechanism which implicates the suppressor of cytokine signalling 1 (SOCS1). Knockdown of HAGE led to a significant decrease in SOCS1 protein expression, activation of the JAK-STAT signalling cascade and a consequent increase of PML expression. To confirm that the reduction in SOCS1 expression was dependent on the HAGE helicase activity, we showed that SOCS1, effectively silenced by small interfering RNA, could be rescued by re-introduction of HAGE into cells lacking HAGE. Furthermore, we provide a mechanism by which HAGE promotes SOCS1 mRNA unwinding and protein expression in vitro