Autonomous marine hyperspectral radiometers for determining solar irradiances and aerosol optical properties

We have developed two hyperspectral radiometer systems which require no moving parts, shade rings or motorised tracking, making them ideally suited for autonomous use in the inhospitable remote marine environment. Both systems are able to measure direct and diffuse hyperspectral irradiance in the wavelength range 350–1050 nm at 6 nm (Spectrometer 1) or 3.5 nm (Spectrometer 2) resolution. Marine field trials along a 100� transect (between 50� N and 50� S) of the Atlantic Ocean resulted in close agreement with existing commercially available instruments in measuring (1) photosynthetically available radiation (PAR), with both spectrometers giving regression slopes close to unity (Spectrometer 1: 0.960; Spectrometer 2: 1.006) and R2 �0.96; (2) irradiant energy, with R2�0.98 and a regression slope of 0.75 which can be accounted for by the difference in wavelength integration range; and (3) hyperspectral irradiance where the agreement on average was between 2 and 5 %. Two long duration land-based field campaigns of up to 18 months allowed both spectrometers to be well calibrated. This was also invaluable for empirically correcting for the wider field of view (FOV) of the spectrometers in comparison with the current generation of sun photometers (�7.5� compared with �1�). The need for this correction was also confirmed and independently quantified by atmospheric radiative transfer modelling and found to be a function of aerosol optical depth (AOD) and solar zenith angle. Once Spectrometer 2 was well calibrated and the FOV effect corrected for, the RMSE in retrievals of AOD when compared with a CIMEL sun photometer were reduced to �0.02–0.03 with R2 > 0.95 at wavelengths 440, 500, 670 and 870 nm. Corrections for the FOV as well as ship motion were applied to the data from the marine field trials. This resulted in AOD500 nm ranging between 0.05 in the clear background marine aerosol regions and �0.5 within the Saharan dust plume. The RMSE between the handheld Microtops sun photometer and Spectrometer 2 was between 0.047 and 0.057 with R2 > 0.94

A survey of owners' perceptions of fear of fireworks in a sample of dogs and cats in New Zealand

AIMS: To establish reliable information regarding the behavioural responses of dogs and cats to fireworks in New Zealand; record interventions used by owners, and their perceived efficacies; and establish the prevalence of firework-related injury, and quantify owners' attitudes towards fireworks. METHODS: A questionnaire targeting dog and cat owners was distributed via the Auckland Society for the Prevention of Cruelty to Animals (SPCA) Animals Voice magazine and 25 veterinary clinics. The questionnaire covered demographics of animals, fear of fireworks, severity of the fear, and behaviours exhibited. Also included were treatments tried, source and perceived efficacy, prevalence of injury, and owners' attitudes towards the sale of fireworks for private use. RESULTS: From a total of 8,966 questionnaires distributed, 1,007 valid questionnaires were returned, representing 3,527 animals. Of these 1,635 (46%) animals displayed a level of fear of fireworks recognisable to their owners. Owners of dogs identified a significantly higher fear response than owners of cats but the duration of these fear responses did not differ between species. Fear of fireworks frequently resulted in dogs exhibiting active fear behaviours, whereas cats were more likely to exhibit hiding and cowering behaviours. A significantly increased severity and duration of fear response over time in dogs and cats was associated with owners who comforted them when they displayed a fearful response. Only 141/890 (15.8%) of owners sought professional treatment from a veterinarian, animal behaviourist or animal trainer for their animals, with variable efficacy. Six percent (51/923) of animals had received physical injuries from fireworks. The majority (837/1,007; 83%) of respondents, regardless of whether they owned a fearful animal or not, supported a ban on the sale of fireworks for private use. CONCLUSIONS: The results provide valuable information that is, as yet, unsubstantiated in New Zealand, although potential biases exist due to the non-random selection of respondents. Differences between dogs and cats were likely due to differing responses to fear-provoking stimuli between the species. Owner-reported increase in fearful response over time for comforted animals may indicate a negative impact on the longer-term psychological welfare of their animal. CLINICAL RELEVANCE: The greater the awareness of effective treatment plans for animals that suffer from a fear of fireworks, the greater the possibility that this fear can be reduced. Wider dissemination of effective owner behaviour and treatment programmes for firework fears is needed to improve levels of professional treatment for dogs and cats

Study of the correlation between columnar aerosol burden, suspended matter at ground and chemical components in a background European environment

Although routinely monitored by ground based air quality networks, the particulate matter distribution could be eventually better described with remote sensing techniques. However, valid relationships between ground level and columnar ground based quantities should be known beforehand. In this study we have performed a comparison between particulate matter measurements at ground level at different cut sizes (10, 2.5 and 1.0 mm), and the aerosol optical depth obtained by means of a ground based sunphotometer during a multiinstrumental field campaign held in El Arenosillo (Huelva, Spain) from 28 June to 4 July 2006. All the PM fractions were very well correlated with AOD with correlation coefficients that ranged from 0.71 to 0.81 for PM10, PM2.5 and PM1. Furthermore, the influence of the mixing layer height in the correlations was explored. The improvement in the correlation when the vertical distribution is taken into account was significant for days with a homogeneous mixing layer. Moreover, the chemical analysis of the individual size fractions allowed us to study the origin of the particulate matter. Secondary components were the most abundant and also well correlated in the three size fractions; but for PM10 fraction, chemical species related to marine origin were best correlated. Finally, we obtained a relationship between MODIS L3 AOD from collection 5.1 and the three PM cut sizes. In spite of being a relatively clean environment, all the techniques were able to capture similar day to day variations during this field campaign.Peer ReviewedPostprint (published version

Comparación de modelos simples para el estudio de la radiación eritemática global sobre planos inclinados

Ponencia presentada en: XXX Jornadas Científicas de la AME y el IX Encuentro Hispano Luso de Meteorología celebrado en Zaragoza, del 5 al 7 de mayo de 2008

Coarse-mode mineral dust size distributions, composition and optical properties from AER-D aircraft measurements over the tropical eastern Atlantic

Mineral dust is an important component of the climate system, affecting the radiation balance, cloud properties, biogeochemical cycles, regional circulation and precipitation, as well as having negative effects on aviation, solar energy generation and human health. Dust size and composition has an impact on all these processes. However, changes in dust size distribution and composition during transport, particularly for coarse particles, are poorly understood and poorly represented in climate models. Here we present new in situ airborne observations of dust in the Saharan Air Layer (SAL) and the marine boundary layer (MBL) at the beginning of its transatlantic transport pathway, from the AERosol Properties - Dust (AER-D) fieldwork in August 2015, within the peak season of North African dust export. This study focuses on coarse-mode dust properties, including size distribution, mass loading, shape, composition, refractive indices and optical properties. Size distributions from 0.1 to 100 µm diameter (d) are presented, fully incorporating the coarse and giant modes of dust. Within the MBL, mean effective diameter (deff) and volume median diameter (VMD) were 4.6 and 6.0 µm respectively, giant particles with a mode at 20-30 µm were observed, and composition was dominated by quartz and alumino-silicates at d > 1 µm. Within the SAL, particles larger than 20 µm diameter were always present up to 5 km altitude, in concentrations over 10−5 cm−3, constituting up to 40 % of total dust mass. Mean deff and VMD were 4.0 and 5.5 µm respectively. Larger particles were detected in the SAL than can be explained by sedimentation theory alone. Coarse-mode composition was dominated by quartz and alumino-silicates; the accumulation mode showed a strong contribution from sulfate-rich and sea salt particles. In the SAL, measured single scattering albedos (SSAs) at 550 nm representing d < 2.5 µm were 0.93 to 0.98 (mean 0.97). Optical properties calculated for the full size distribution (0.1 < d < 100 µm) resulted in lower SSAs of 0.91-0.98 (mean 0.95) and mass extinction coefficients of 0.27-0.35 m2 g−1 (mean 0.32 m2 g−1). Variability in SSA was mainly controlled by variability in dust composition (principally iron) rather than by variations in the size distribution, in contrast with previous observations over the Sahara where size is the dominant influence. It is important that models are able to capture the variability and evolution of both dust composition and size distribution with transport in order to accurately represent the impacts of dust on climate. These results provide a new SAL dust dataset, fully representing coarse and giant particles, to aid model validation and development

Monoclonal anti-β1-adrenergic receptor antibodies activate G protein signaling in the absence of β-arrestin recruitment

Thermostabilized G protein-coupled receptors used as antigens for in vivo immunization have resulted in the generation of functional agonistic anti-β1-adrenergic (β1AR) receptor monoclonal antibodies (mAbs). The focus of this study was to examine the pharmacology of these antibodies to evaluate their mechanistic activity at β1AR. Immunization with the β1AR stabilized receptor yielded five stable hybridoma clones, four of which expressed functional IgG, as determined in cell-based assays used to evaluate cAMP stimulation. The antibodies bind diverse epitopes associated with low nanomolar agonist activity at β1AR, and they appeared to show some degree of biased signaling as they were inactive in an assay measuring signaling through β-arrestin. In vitro characterization also verified different antibody-receptor interactions reflecting the different epitopes on the extracellular surface of β1AR to which the mAbs bind. The anti-β1AR mAbs only demonstrated agonist activity when in dimeric antibody format, but not as the monomeric Fab format, suggesting that agonist activation may be mediated through promoting receptor dimerization. Finally, we have also shown that at least one of these antibodies exhibits in vivo functional activity at a therapeutically-relevant dose producing an increase in heart rate consistent with β1AR agonism

Diseño, aplicación y valoración de actividades destinadas al trabajo y evaluación de múltiples competencias transversales en grupos numerosos de máster en ingeniería, empleando el aprendizaje basado en proyectos

Society requires graduates to acquire cross-curricular skills during their education since this type of skills is better valued by employers than even degree-specific skills. Active methodologies to develop skills have been successfully implemented in small groups. In contrast,working and objectively evaluating cross-curricular skills in large groups presents a number of additional difficulties such as excessive workload for teachers, which generates resistance to change and lack of experience. The aim of this study is to design, apply and assess training activities with a large number of engineering students, more specifically 288, who were taking a compulsory subject. These training activities used project-based learning and portfolios to work and evaluate multiple cross-curricular skills. The results show that it is feasible to design and develop training activities applicable in large groups that promote the acquisition of multiple cross-curricular skills, allowing for a significant improvement in the knowledge level of the students, without assuming an excessive workload for students and teachers. The results also show that the extent to which students acquired cross-curricular skills after the activities depends mainly on their previous level, and not so much on the time they devoted to the project. However, time reveals itself as an important factor when it comes to the mastery of skills. Finally, 86% of the students have a positive perception of the methodology employed, indicating that it provides a more applied understanding of the subject.La sociedad requiere de los egresados la formación en las competencias transversales que incluso son mejor valoradas por los empleadores que las competencias específicas del grado. Las metodologías activas para desarrollar las competencias se han implantado con éxito en grupos reducidos. En cambio, trabajar y evaluar objetivamente las competencias transversales en grupos numerosos presenta una serie de dificultades añadidas como una excesiva carga de trabajo para el profesorado, con la subsiguiente resistencia al cambio y falta de experiencias. El objetivo de este trabajo es valorar una propuesta formativa que emplea la metodología de aprendizaje basado en proyectos y el portafolio como método para trabajar y evaluar múltiples competencias transversales en grupos numerosos de estudiantes de ingeniería. Los resultados muestran que es factible diseñar y desarrollar actividades formativas aplicables en grupos numerosos, que favorezcan la adquisición de múltiples competencias transversales. Además, han permitido obtener una mejora significativa en el nivel de dominio de las mismas, sin suponer una carga de trabajo adicional excesiva ni para el alumnado ni para el profesorado. Asimismo, los resultados muestran que el nivel de dominio de las competencias transversales alcanzado por el alumno tras las actividades depende principalmente del nivel de dominio previo, y no tanto del tiempo de dedicación al proyecto. No obstante éste último es un factor importante en la mejora en el nivel de dominio de las competencias. Finalmente, el 86% de los alumnos valoran positivamente la metodología empleada, indicando que proporciona una visión más aplicada de la asignatura

Intercomparison of spectroradiometers and Sun photometers for the determination of the aerosol optical depth during the VELETA-2002 field campaign

[ 1] In July 2002 the VELETA-2002 field campaign was held in Sierra Nevada ( Granada) in the south of Spain. The main objectives of this field campaign were the study of the influence of elevation and atmospheric aerosols on measured UV radiation. In the first stage of the field campaign, a common calibration and intercomparison between Licor-1800 spectroradiometers and Cimel-318 Sun photometers was performed in order to assess the quality of the measurements from the whole campaign. The intercomparison of the Licor spectroradiometers showed, for both direct and global irradiances, that when the comparisons were restricted to the visible part of the spectrum the deviations were within the instruments' nominal accuracies which allows us to rely on these instruments for measuring physical properties of aerosols at the different measurement stations. A simultaneous calibration on AOD data was performed for the Cimel-318 Sun photometers. When a common calibration and methodology was applied, the deviation was lowered to much less than 0.01 for AOD. At the same time an intercomparison has been made between the AOD values given by the spectroradiometers and the Sun photometers, with deviations obtained from 0.01 to 0.03 for the AOD in the visible range, depending on the channel. In the UVA range, the AOD uncertainty was estimated to be around 0.02 and 0.05 for Cimel and Licor respectively. In general the experimental differences were in agreement with this uncertainty estimation. In the UVB range the AOD measurements should not be used due to maximum instrumental uncertainties

Agglomerations and firm performance: who benefits and how much?

[EN] Agglomerations and firm performance: who benefits and how much? Regional Studies. Agglomeration can generate gains. If it does, how does it work and how are those gains distributed across agglomerated firms? The paper examines the effect of localization externalities on innovation. Localization externalities are measured as industry specialization or a firm s colocation in a relatively high own-industry employment region. By analyzing a large dataset of 6697 firms integrated with another regional agglomeration-related dataset, results show that (1) co-location in an agglomeration has a positive influence on a firm s innovative performance; and (2) firms benefit heterogeneously from agglomerations, with benefits being distributed asymmetrically. Agglomeration gains exist but not all firms benefit equally.Financial support was provided by the Spanish Ministry of Economics, Industry and Competitiveness [research grant ECO:2015-63645-R] (Mineco/Feder), Open Innovation in Clusters.Hervás Oliver, JL.; Sempere-Ripoll, F.; Rojas Alvarado, RJ.; Estelles Miguel, S. (2018). Agglomerations and firm performance: who benefits and how much?. Regional Studies. 52(3):338-349. https://doi.org/10.1080/00343404.2017.1297895S33834952