310 research outputs found

    Greener Solvent-Free Reactions on ZnO

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    The aesthetics of Instagram: Exploring the aesthetics of visual and semantic aspects of Instagram

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    The article presents the results of an aesthetic study of content and visual forms on Instagram, a relatively new social media platform. The study focuses on how the products of digital technology, understood as new artifacts within the postmodern aesthetic framework, have been taken up within the digital culture. The results of the research help us to understand the characteristics of this new social media platform, indicating that Instagram has been highly successful in changing aesthetic criteria and standards and creating new aesthetic forms and content

    A Comparative Study of Sindbad-name and Bakhtiyar-name in term of Contributors Paatern of Narrative

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    This study compares the stories of Sindbad-name and Bakhtiyar-name. The essential grounds for this comparison are the structural similarity between the scripts, as well as the fundamental differences in terms of actions’ modalities, actors’ roles, and the connections between them. The basis for this study is Greimas Theory and the communication model of characters, which assist the study to systematically identify the characters’ contributions in the events, and their motivations, demands and wills in the incidents and actions of the story. The results of this study show that Sindbad-name is the story of active characters and their wills and demands, while Bakhtiyar-name tells the story of fate and its indisputable dominance over the characters’ lives and their connections, in which women are more under the control of fate’s power and men’s role-playing and influence. Accepting the fact that literary scripts, especially folk tales with simple structures and sequence, are the reflections of the social environment of their particular historical era, it needs to be admitted that Bakhtiyar-name belongs to the era of believing in the undisputed power of fate and destiny; the era in which women are marginalized even more than before

    Conjugate heat transfer of laminar mixed convection of a nanofluid through an inclined tube with circumferentially non-uniform heating

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    Laminar mixed convection of a nanofluid consisting of water and Al2O3 in an inclined tube with heating at the top half surface of a copper tube has been studied numerically. The bottom half of the tube wall is assumed to be adiabatic (presenting a tube of a solar collector). Heat conduction mechanism through the tube wall is considered. Three-dimensional governing equations with using two-phase mixture model have been solved to investigate hydrodynamic and thermal behaviours of the nanofluid over wide range of nanoparticle volume fractions. For a given nanoparticle mean diameter the effects of nanoparticle volume fractions on the hydrodynamics and thermal parameters are presented and discussed at different Richardson numbers and different tube inclinations. Significant augmentation on the heat transfer coefficient as well as on the wall shear stress is seen

    Bis(2-hydroxy­benzaldehyde oxime) O,O′-butane-1,4-diyldicarbonyl ether

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    The mol­ecule of the title compound, C20H20N2O6, lies across a crystallographic inversion centre, the asymmetric unit comprising one half-mol­ecule. An intra­molecular O—H⋯N hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Pairs of inter­molecular C—H⋯O hydrogen bonds link neighbouring mol­ecules into a layer with R 2 2(38) ring motif. The crystal structure is further stabilized by the inter­molecular C—H⋯π inter­actions

    The Very Low Frequency of Epstein-Barr JC and BK Viruses DNA in Colorectal Cancer Tissues in Shiraz, Southwest Iran

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    Viruses including Epstein-Barr virus (EBV), JCV and BKV have been reported to be associated with some cancers. The association of these viruses with colorectal cancers remains controversial. Our objective was to investigate their infections association with adenocarcinoma and adenomatous polyps of the colon. Totally, 210 paraffin-embedded tissue specimens encompassing 70 colorectal adenocarcinoma, 70 colorectal adenomatous and 70 colorectal normal tissues were included. The total DNA was extracted, then qualified samples introduced to polymerase chain reaction (PCR). The EBV, JCV and BKV genome sequences were detected using specific primers by 3 different in-house PCR assays. Out of 210 subjects, 98 cases were female and the rest were male. The mean age of the participants was 52 ± 1.64 years. EBV and JCV DNA was detected just in one (1.42%) out of seventy adenocarcinoma colorectal tissues. All adenomatous polyp and normal colorectal tissues were negative for EBV and JCV DNA sequences. Moreover, all the patients and healthy subjects were negative for BKV DNA sequences. The results suggested that EBV and JCV genomes were not detectable in the colorectal tissue of patients with colorectal cancer in our population. Hence, BKV might not be necessitated for the development of colorectal cancer. The findings merit more investigations

    Triangular and prism-shaped gold-zinc oxide plasmonic nanostructures: in situ reduction, assembly and full-range photocatalytic performance

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    Gold-based nanocatalysts have been traditionally selected for multiple homogeneous and heterogeneous reactions of interest involving redox processes. Likewise, greener routes involving more efficient reactors and the use of inexpensive and nature-mimicking excitation sources have boosted the research on photocatalysts able to drive these chemical reactions upon excitation with multiple wavelength sources beyond the UV range. In the present work we report on a multi-step synthesis approach that implies the in situ generation of triangular and prism-shaped gold nanostructures with a localized surface plasmon resonance effect and their direct assembly onto a ZnO nanostructured semiconductor support. Different LED excitation sources in the whole UV-Vis-NIR range have been systematically selected to activate these hybrid materials in the selective reduction of p-nitrophenol (4-NP), a wellknown contaminant by-product. While ZnO becomes preferentially active in the UV window, the anisotropic shape of these gold plasmonic nanostructures helps to broaden the photocatalytic response of ZnO towards the visible and NIR range, being especially active under 460 nm blue light irradiation and expanding their potential application in multiple solar-driven catalytic processes of interest for decontamination and upgrading of toxic chemicals

    Simultaneous estimation of heat flux and heat transfer coefficient in irregular geometries made of functionally graded materials

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    A numerical inverse analysis based on explicit sensitivity coefficients is developed for the simultaneous estimation of heat flux and heat transfer coefficient imposed on different parts of boundary of a general irregular heat conducting body made of functionally graded materials with spatially varying thermal conductivity. It is assumed that the thermal conductivity varies exponentially with position in the body. The body considered in this study is an eccentric hollow cylinder. The heat flux is applied on the cylinder inner surface and the heat is dissipated to the surroundings through the outer surface. The numerical method used in this study consists of three steps: 1) to apply a boundary-fitted grid generation (elliptic) method to generate grid over eccentric hollow cylinder (an irregular shape) and then solve for the steady-state heat conduction equation with variable thermal conductivity to compute the temperature values in the cylinder, 2) to propose a new explicit sensitivity analysis scheme used in inverse analysis, and 3) to apply a gradient-based optimization method (in this study, conjugate gradient method) to minimize the mismatch between the computed temperature on the outer surface of the cylinder and simulated measured temperature distribution. The inverse analysis presented here is not involved with an adjoint equation and all the sensitivity coefficients can be computed in only one direct solution, without the need for the solution of the adjoint equation. The accuracy, efficiency, and robustness of the developed inverse analysis are demonstrated through presenting a test case with different initial guesses

    Synthesis of Ti(SO4)O solid acid nano-catalyst and its application for biodiesel production from used cooking oil

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    A novel solid acid nano-catalyst [Ti(SO4)O] was synthesised and used for the simultaneous esterification and transesterification of free fatty acids in used cooking oil (UCO) to produce biodiesel. The synthesised nano-catalyst was fully characterized by different analytical techniques. The XPS results clearly confirmed that the bidentate sulphate coordinated to the Ti4+ metal in the nano-catalyst product. Obtained d-spacing values from the experimental data of XRD peaks and the SAED pattern of produced nano-catalyst agreed well with the d-spacing values from the JCPDS-ICDD card numbers 04-011-4951 for titanium sulphate oxide or titanium oxysulfate crystal structures.This confirms the sulphate groups were within the crystalline structure rather than on the surface of titania nanoparticles, which has not been previously reported. It has been demonstrated 97.1% yield for the fatty acid methyl ester can be achieved usign the synthetised catalyst under a reaction time of 3 h, catalyst to UCO ration of 1.5 wt% and methanol to UCO ratio of 9:1 at 75 °C reaction temperature. The nano-catalyst showed a good catalytic activity for the feedstock containing ≤6 wt% free fatty acid. Furthermore, the catalytic activity and re-usability of the Ti(SO4)O for the esterification/transesterification of UCO were investigated. XRD results confirmed that the amount of View the MathML source species in the solid acid nano-catalyst slowly decreased with re-use after 8 cycles under optimised conditions, which is higher than the reusability of other functionalised titania reported in the literature. Finally, the biodiesel prodcued from this process satisfied the ASTM and European Norm standards
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