The Eleonore Sø and Målebjerg foreland windows, East Greenland Caledonides, and the demise of the ‘stockwerke’ concept

Recognition of the Eleonore Sø and Målebjerg foreland windows during the 1997–1998 regional mapping expeditions to the East Greenland Caledonides provided critical evidence for largescale, westward-directed thrusting in the Kong Oscar Fjord region (72°–75°N), a revelation that dealt a final blow to the ‘stockwerke’ concept of an in situ highly mobile infrastructure characterised by rising fronts of Caledonian migmatisation and metasomatism. This paper reviews earlier investigations in both the Eleonore Sø and Målebjerg areas, and the misinterpretations of rock units that initially obscured recognition of their foreland affinity. The Eleonore Sø and Målebjerg windows can now be placed in context, as part of the lowest structural level of the foreland-propagating thrust pile of the Kong Oscar Fjord region

The Neoproterozoic Rivieradal Group of Kronprins Christian Land, eastern North Greenland

The Rivieradal Group, formally defined here, is confined to the Vandredalen thrust sheet of the Caledonian orogen in Kronprins Christian Land, eastern North Greenland. It comprises a succession of Neoproterozoic siliciclastic sediments that represent the fill of a half-graben basin. The syn-rift Rivieradal Group is overlain by post-rift sediments of the Hagen Fjord Group. The latter succession is present in both the thrust sheet and the Caledonian foreland to the west. In the foreland, where the Rivieradal Group is not represented, the Hagen Fjord Group disconformably overlies Palaeoproterozoic–Mesoproterozoic sandstones of the Independence Fjord Group

Greenland from Archaean to Quaternary, Descriptive text to the 1995 Geological Map of Greenland 1:2 500 000, 2nd edition

The geological development of Greenland spans a period of nearly 4 Ga, from Eoarchaean to the Quaternary. Greenland is the largest island on Earth with a total area of 2 166 000 km2, but only c. 410 000 km2 are exposed bedrock, the remaining part being covered by a major ice sheet (the Inland Ice) reaching over 3 km in thickness. The adjacent offshore areas underlain by continental crust have an area of c. 825 000 km2. Greenland is dominated by crystalline rocks of the Precambrian shield, which formed during a succession of Archaean and Palaeoproterozoic orogenic events and stabilised as a part of the Laurentian shield about 1600 Ma ago. The shield area can be divided into three distinct types of basement provinces: (1) Archaean rocks (3200–2600 Ma old, with local older units up to >3800Ma) that were almost unaffected by Proterozoic or later orogenic activity; (2) Archaean terrains reworked during the Palaeoproterozoic around 1900–1750 Ma ago; and (3) terrains mainly composed of juvenile Palaeoproterozoic rocks (2000–1750 Ma in age).Subsequent geological developments mainly took place along the margins of the shield. During the Proterozoic and throughout the Phanerozoic major sedimentary basins formed, notably in North and North-East Greenland, in which sedimentary successions locally reaching 18 km in thickness were deposited. Palaeozoic orogenic activity affected parts of these successions in the Ellesmerian fold belt of North Greenland and the East Greenland Caledonides; the latter also incorporates reworked Precambrian crystalline basement complexes. Late Palaeozoic and Mesozoic sedimentary basins developed along the continent–ocean margins in North, East and West Greenland and are now preserved both onshore and offshore. Their development was closely related to continental break-up with formation of rift basins. Initial rifting in East Greenland in latest Devonian to earliest Carboniferous time and succeeding phases culminated with the opening of the North Atlantic Ocean in the late Paleocene. Sea-floor spreading was accompanied by extrusion of Palaeogene (early Tertiary) plateau basalts in both central West and central–southern East Greenland. During the Quaternary Greenland was almost completely covered by ice, and the present day Inland Ice is a relic from the Pleistocene ice ages. Vast amounts of glacially eroded detritus were deposited on the continental shelves around Greenland. Mineral exploitation in Greenland has so far encompassed cryolite, lead-zinc, gold, olivine and coal. Current prospecting activities in Greenland are concentrated on gold, base metals, platinum group elements, molybdenum, iron ore, diamonds and lead-zinc. Hydrocarbon potential is confined to the major Phanerozoic sedimentary basins, notably the large basins offshore North-East and West Greenland. While reserves of oil or gas have yet to be found, geophysical data com bined with discoveries of oil seeps onshore have revealed a considerable potential for offshore oil and gas

Equivariant cohomology over Lie groupoids and Lie-Rinehart algebras

Using the language and terminology of relative homological algebra, in particular that of derived functors, we introduce equivariant cohomology over a general Lie-Rinehart algebra and equivariant de Rham cohomology over a locally trivial Lie groupoid in terms of suitably defined monads (also known as triples) and the associated standard constructions. This extends a characterization of equivariant de Rham cohomology in terms of derived functors developed earlier for the special case where the Lie groupoid is an ordinary Lie group, viewed as a Lie groupoid with a single object; in that theory over a Lie group, the ordinary Bott-Dupont-Shulman-Stasheff complex arises as an a posteriori object. We prove that, given a locally trivial Lie groupoid G and a smooth G-manifold f over the space B of objects of G, the resulting G-equivariant de Rham theory of f boils down to the ordinary equivariant de Rham theory of a vertex manifold relative to the corresponding vertex group, for any vertex in the space B of objects of G; this implies that the equivariant de Rham cohomology introduced here coincides with the stack de Rham cohomology of the associated transformation groupoid whence this stack de Rham cohomology can be characterized as a relative derived functor. We introduce a notion of cone on a Lie-Rinehart algebra and in particular that of cone on a Lie algebroid. This cone is an indispensable tool for the description of the requisite monads.Comment: 47 page

Experimental and Computational Studies of Single-Molecule Conductance of Ru(II) and Pt(II) trans-Bis(acetylide) Complexes

The single-molecule conductance of metal complexes of the general forms trans-Ru(C≡CArC≡CY)2(dppe)2 and trans-Pt(C≡CArC≡CY)2(PPh3)2 (Ar = 1,4-C6H2-2,5-(OC6H13)2; Y = 4-C5H4N, 4-C6H4SMe) have been determined using the STM I(s) technique. The complexes display high conductance (Y = 4-C5H4N, M = Ru (0.4 ± 0.18 nS), Pt (0.8 ± 0.5 nS); Y = 4-C6H5SMe, M = Ru (1.4 ± 0.4 nS), Pt (1.8 ± 0.6 nS)) for molecular structures of ca. 3 nm in length, which has been attributed to transport processes arising from tunneling through the tails of LUMO state

Disordered Type-II Superconductors: A Universal Phase Diagram for Low-Tc_c Systems

A universal phase diagram for weakly pinned low-T$_c$ type-II superconductors is revisited and extended with new proposals. The low-temperature ``Bragg glass'' phase is argued to transform first into a disordered, glassy phase upon heating. This glassy phase, a continuation of the high-field equilibrium vortex glass phase, then melts at higher temperatures into a liquid. This proposal provides an explanation for the anomalies observed in the peak effect regime of 2H-NbSe$_2$ and several other low-T$_c$ materials which is independent of the microscopic mechanisms of superconductivity in these systems.Comment: 23 pages, 9 figure

Conductance behavior of tetraphenyl-Aza-Bodipys

We studied the electrical conductance of single-molecule junctions formed from molecular wires with four anchor groups. Three tetraphenyl-aza-BODIPYs with four or two thiomethyl anchor groups were synthesized, and their single-molecule conductance was measured using break-junction-STM. Using DFT based calculations these compounds were shown to display a combination of a high and low conductance, depending on the molecule's connectivity in the junction. A scissor correction is employed to obtain the corrected HOMO-LUMO gaps and a tight binding model (TBM) is used to highlight the role of transport through the pi system of the tetraphenyl-aza-BODIPY central unit. The three higher-conductance geometries follow the sequence 3 > 4 > 2, which demonstrates that their conductances are correlated with the number of anchors