6,626 research outputs found
Water formation at low temperatures by surface O2 hydrogenation II: the reaction network
Water is abundantly present in the Universe. It is the main component of
interstellar ice mantles and a key ingredient for life. Water in space is
mainly formed through surface reactions. Three formation routes have been
proposed in the past: hydrogenation of surface O, O2, and O3. In a previous
paper [Ioppolo et al., Astrophys. J., 2008, 686, 1474] we discussed an
unexpected non-standard zeroth-order H2O2 production behaviour in O2
hydrogenation experiments, which suggests that the proposed reaction network is
not complete, and that the reaction channels are probably more interconnected
than previously thought. In this paper we aim to derive the full reaction
scheme for O2 surface hydrogenation and to constrain the rates of the
individual reactions. This is achieved through simultaneous H-atom and O2
deposition under ultra-high vacuum conditions for astronomically relevant
temperatures. Different H/O2 ratios are used to trace different stages in the
hydrogenation network. The chemical changes in the forming ice are followed by
means of reflection absorption infrared spectroscopy (RAIRS). New reaction
paths are revealed as compared to previous experiments. Several reaction steps
prove to be much more efficient (H + O2) or less efficient (H + OH and H2 + OH)
than originally thought. These are the main conclusions of this work and the
extended network concluded here will have profound implications for models that
describe the formation of water in space.Comment: 1 page, 1 figur
Formation of hydrogen peroxide and water from the reaction of cold hydrogen atoms with solid oxygen at 10K
The reactions of cold H atoms with solid O2 molecules were investigated at 10
K. The formation of H2O2 and H2O has been confirmed by in-situ infrared
spectroscopy. We found that the reaction proceeds very efficiently and obtained
the effective reaction rates. This is the first clear experimental evidence of
the formation of water molecules under conditions mimicking those found in cold
interstellar molecular clouds. Based on the experimental results, we discuss
the reaction mechanism and astrophysical implications.Comment: 12 pages, 3 Postscript figures, use package amsmath, amssymb,
graphic
The association between proton pump inhibitors and hyperparathyroidism - a potential mechanism for increased fracture - results of a large observational cohort study
Understanding the decarbonisation of housing: Wales as a case study
International targets requiring UK nations to reduce carbon emissions by at least 80% of 1990 levels by 2050 were made obsolete in 2019. The Climate Change Act now commits UK government to reducing greenhouse gas emissions by at least 100% of 1990 levels by 2050. This includes more stringent emissions targets for the devolved administrations. Welsh Government is responsible for the delivery of decarbonisation in Wales. The Welsh housing stock, among the oldest and least efficient in Europe, produces 21% of national carbon emissions. The CCC report recommends that Wales target no less than a 95% reduction in carbon emissions by 2050. This research explores how policy could deliver this scale of emissions reduction, by predicting the impact of established and emerging 'best practice' retrofit solutions on the existing housing stock. Fourteen recurring dwelling 'types' are identified within the Welsh housing stock (based on physical metrics, condition and tenure) using large data sets. Appropriate retrofit 'narratives' are established and then simulated for each of the fourteen dwelling types. Their impact is measured in terms of capital cost, primary energy use, fuel bills, and carbon emissions. By exploring the impact of a range of approaches to retrofit, and by considering different scenarios for clean energy supply, this research has informed the ongoing development of a route map for delivering decarbonisation targets in Wales
Measurements of the Production, Decay and Properties of the Top Quark: A Review
With the full Tevatron Run II and early LHC data samples, the opportunity for
furthering our understanding of the properties of the top quark has never been
more promising. Although the current knowledge of the top quark comes largely
from Tevatron measurements, the experiments at the LHC are poised to probe
top-quark production and decay in unprecedented regimes. Although no current
top quark measurements conclusively contradict predictions from the standard
model, the precision of most measurements remains statistically limited.
Additionally, some measurements, most notably the forward-backward asymmetry in
top quark pair production, show tantalizing hints of beyond-the-Standard-Model
dynamics. The top quark sample is growing rapidly at the LHC, with initial
results now public. This review examines the current status of top quark
measurements in the particular light of searching for evidence of new physics,
either through direct searches for beyond the standard model phenomena or
indirectly via precise measurements of standard model top quark properties
A search for resonant production of pairs in $4.8\ \rm{fb}^{-1}p\bar{p}\sqrt{s}=1.96\ \rm{TeV}$
We search for resonant production of tt pairs in 4.8 fb^{-1} integrated
luminosity of ppbar collision data at sqrt{s}=1.96 TeV in the lepton+jets decay
channel, where one top quark decays leptonically and the other hadronically. A
matrix element reconstruction technique is used; for each event a probability
density function (pdf) of the ttbar candidate invariant mass is sampled. These
pdfs are used to construct a likelihood function, whereby the cross section for
resonant ttbar production is estimated, given a hypothetical resonance mass and
width. The data indicate no evidence of resonant production of ttbar pairs. A
benchmark model of leptophobic Z \rightarrow ttbar is excluded with m_{Z'} <
900 GeV at 95% confidence level.Comment: accepted for publication in Physical Review D Sep 21, 201
Bone Marrow Transplantation for Feline Mucopolysaccharidosis I
Severe mucopolysaccharidosis type I (MPS I) is a fatal neuropathic lysosomal storage disorder with significant skeletal involvement. Treatment involves bone marrow transplantation (BMT), and although effective, is suboptimal, due to treatment sequelae and residual disease. Improved approaches will need to be tested in animal models and compared to BMT. Herein we report on bone marrow transplantation to treat feline mucopolysaccharidosis I (MPS I). Five MPS I stably engrafted kittens, transplanted with unfractionated bone marrow (6.3 × 107–1.1 × 109 nucleated bone marrow cells per kilogram) were monitored for 13–37 months post-engraftment. The tissue total glycosaminoglycan (GAG) content was reduced to normal levels in liver, spleen, kidney, heart muscle, lung, and thyroid. Aorta GAG content was between normal and affected levels. Treated cats had a significant decrease in the brain GAG levels relative to untreated MPS I cats and a paradoxical decrease relative to normal cats. The α-l-iduronidase (IDUA) activity in the livers and spleens of transplanted MPS I cats approached heterozygote levels. In kidney cortex, aorta, heart muscle, and cerebrum, there were decreases in GAG without significant increases in detectable IDUA activity. Treated animals had improved mobility and decreased radiographic signs of disease. However, significant pathology remained, especially in the cervical spine. Corneal clouding appeared improved in some animals. Immunohistochemical and biochemical analysis documented decreased central nervous system ganglioside storage. This large animal MPS I study will serve as a benchmark of future therapies designed to improve on BMT
Inclusive Search for Anomalous Production of High-pT Like-Sign Lepton Pairs in Proton-Antiproton Collisions at sqrt{s}=1.8 TeV
We report on a search for anomalous production of events with at least two
charged, isolated, like-sign leptons with pT > 11 GeV/c using a 107 pb^-1
sample of 1.8 TeV ppbar collisions collected by the CDF detector. We define a
signal region containing low background from Standard Model processes. To avoid
bias, we fix the final cuts before examining the event yield in the signal
region using control regions to test the Monte Carlo predictions. We observe no
events in the signal region, consistent with an expectation of
0.63^(+0.84)_(-0.07) events. We present 95% confidence level limits on new
physics processes in both a signature-based context as well as within a
representative minimal supergravity (tanbeta = 3) model.Comment: 15 pages, 4 figures. Minor textual changes, cosmetic improvements to
figures and updated and expanded reference
Measurement of and Production in Collisions at = 1.96 TeV
The Standard Model predictions for and production are
tested using an integrated luminosity of 200 pb of \ppbar collision data
collected at the Collider Detector at Fermilab. The cross sections are measured
selecting leptonic decays of the and bosons, and photons with
transverse energy GeV that are well separated from leptons. The
production cross sections and kinematic distributions for the and
are compared to SM predictions.Comment: 7 pages, 4 figures, submitted to PR
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