Revisiting the location and environment of the central engine in NGC1068

We revisit in this paper the location of the various components observed in the AGN of NGC1068. Discrepancies between previously published studies are explained, and a new measurement for the absolute location of the K-band emission peak is provided. It is found to be consistent with the position of the central engine as derived by Gallimore (1997), Capetti (1997) and Kishimoto (1999). A series of map overlays is then presented and discussed. Model predictions of dusty tori show that the nuclear unresolved NIR-MIR emission is compatible with a broad range of models: the nuclear SED alone does not strongly constrain the torus geometry, while placing reasonable constraints on its size and thickness. The extended MIR emission observed within the ionizing cone is shown to be well explained by the presence of optically thick dust clouds exposed to the central engine radiation and having a small covering factor. Conversely, a distribution of diffuse dust particles within the ionizing cone is discarded. A simple model for the H2 and CO emission observed perpendicularly to the axis of the ionizing cone is proposed. We show that a slight tilt between the molecular disc and the Compton thick central absorber naturally reproduces the observed distribution of H2 of CO emission.Comment: 17 pages, 11 figures, revised version for A&

Variations of the Mid-IR Aromatic Features Inside and Among Galaxies

We present the results of a systematic study of mid-IR spectra of Galactic regions, Magellanic HII regions, and galaxies of various types (dwarf, spiral, starburst), observed by the satellites ISO and Spitzer. We study the relative variations of the 6.2, 7.7, 8.6 and 11.3 micron features inside spatially resolved objects (such as M82, M51, 30 Doradus, M17 and the Orion Bar), as well as among 90 integrated spectra of 50 objects. Our main results are that the 6.2, 7.7 and 8.6 micron bands are essentially tied together, while the ratios between these bands and the 11.3 micron band varies by one order of magnitude. This implies that the properties of the PAHs are remarkably universal throughout our sample, and that the relative variations of the band ratios are mainly controled by the fraction of ionized PAHs. In particular, we show that we can rule out both the modification of the PAH size distribution, and the mid-infrared extinction, as an explanation of these variations. Using a few well-studied Galactic regions (including the spectral image of the Orion Bar), we give an empirical relation between the I(6.2)/I(11.3) ratio and the ionization/recombination ratio G0/ne.Tgas^0.5, therefore providing a useful quantitative diagnostic tool of the physical conditions in the regions where the PAH emission originates. Finally, we discuss the physical interpretation of the I(6.2)/I(11.3) ratio, on galactic size scales.Comment: Accepted by the ApJ, 67 pages, 70 figure

From freshwater to marine aquaponic: new opportunities for marine fish species production

Due to the increasing world population, by 2050 food production should be increased of about 70% to 100%. Tanks to the lowest “carbon footprint”, aquaculture seems to be the most sustainable system for producing food (protein) of animal origin. Despite that, progress can be done for further improving aquaculture sustainability through the “aquaponic” system (IAS). A IAS is based on the bacteria nitrogen cycle which convert fish waste (faeces and uneaten feed) into nitrite and nitrate, this latter absorbed by plants grown in the hydroponic section of the aquaponic system; as a results, water is “depurated” and recycled into the fish tanks. Advantages of this system are the high productivity, the reduced water requirement, the neglectable waste production, the reduced plant disease incidence and pesticides utilization, the modularity of the system which allow its uses for a wide range of purposes (urban agriculture, people resilience in developing countries, marginal land exploitation, etc.); for a contrary, disadvantages are the relevant initial investments, the required high education level of the employees, the “sensitivity” of the systems and some minor others. A relevant future challenge for scientists is to develop “marine aquaponic system” for producing more valuable fish and crops, interesting also for the EU and ‘developed countries’ market

An original interferometric study of NGC 1068 with VISIR BURST mode images

We present 12.8 microns images of the core of NGC 1068 obtained with the BURST mode of the VLT/VISIR. We trace structures under the diffraction limit of one UT and we investigate the link between dust in the vicinity of the central engine of NGC 1068, recently resolved by interferometry with MIDI, and more extended structures. This step is mandatory for a multi-scale understanding of the sources of mid-infrared emission in AGNs. A speckle processing of VISIR BURST mode images was performed to extract very low spatial-frequency visibilities, first considering the full field of VISIR BURST mode images and then limiting it to the mask used for the acquisition of MIDI data. Extracted visibilities are reproduced with a multi-component model. We identify two major sources of emission: one compact < 85 mas, associated with the dusty torus, and an elliptical one, (< 140) mas x 1187 mas at P.A.=-4 degrees from N to E. This is consistent with previous deconvolution processes. The combination with MIDI data reveals the close environment of the dusty torus to contribute to about 83 percent of the MIR flux seen by MIDI. This strong contribution has to be considered in modeling long baseline interferometric data. It must be related to the NS elongated component which is thought to originate from individually unresolved dusty clouds and is located inside the ionization cone. Low temperatures of the dusty torus are not challenged, emphasizing the scenarios of clumpy torus.Comment: 10 pages, 7 figures, accepted for publication in A&

Cobalt-Based Electrolytes for Dye-Sensitized Solar Cells: Recent Advances towards Stable Devices

Redox mediators based on cobalt complexes allowed dye-sensitized solar cells (DSCs) to achieve efficiencies exceeding 14%, thus challenging the emerging class of perovskite solar cells. Unfortunately, cobalt-based electrolytes demonstrate much lower long-term stability trends if compared to the traditional iodide/triiodide redox couple. In view of the large-scale commercialization of cobalt-based DSCs, the scientific community has recently proposed various approaches and materials to increase the stability of these devices, which comprise gelling agents, crosslinked polymeric matrices and mixtures of solvents (including water). This review summarizes the most significant advances recently focused towards this direction, also suggesting some intriguing way to fabricate third-generation cobalt-based photoelectrochemical devices stable over time

Polycyclic Aromatic Hydrocarbon and Emission Line Ratios in Active Galactic Nuclei and Starburst Galaxies

We study the Polycyclic Aromatic Hydrocarbons (PAH) bands, ionic emission lines, and Mid-infrared continuum properties, in a sample of 171 emission line galaxies taken from literature plus 15 new active galactic nuclei (AGN) Spitzer spectra. The continuum shape steeply rises for longer wavelengths and can be fitted with a warm blackbody distribution of T=150-300K. The brightest PAH spectral bands (6.2, 7.7, 8.6, 11.3, and 12.7$\mu$m) and the forbidden emission lines of [Si II] 34.8$\mu$m, [Ar II] 6.9, [S III] 18.7 and 33.4 were detected in all the Starbursts and in ~80% of the Seyfert~2. Taking under consideration only the PAH bands at 7.7$\mu$m, 11.3$\mu$m, and 12.7$\mu$m we find they are present in ~80% of the Seyfert 1, while only half of this type of activity show the 6.2$\mu$m and 8.6 PAH bands. The observed intensities ratios for neutral and ionized PAHs (6.2/7.7 x 11.3/7.7) were compared to theoretical intensity ratios, showing that AGNs have higher ionization fraction and larger PAH (> 180 carbon atoms) than SB galaxies. The ratio between the ionized (7.7) and the neutral PAH bands (8.6 and 11.3) are distributed over different ranges for AGNs and SB galaxies, suggesting that these ratios could depend on the ionization fraction, as well as on the hardness of the radiation field. The ratio between the 7.7 and 11.3 bands is nearly constant with the increase of [Ne III]15.5/[Ne II], indicating that the fraction of ionized to neutral PAH bands does not depend on the hardness of the radiation field. The equivalent width of both PAH features show the same dependence with [Ne III]/[Ne II], suggesting that the PAH, emitting either ionized (7.7) or neutral (11.3) bands, may be destroyed with the increase of the hardness of the radiation field.Comment: Accepted by Ap

Hygrothermal Behaviour of Three Internal Retrofit Prototype Solutions

AbstractAlthough the application of internal insulation to existing perimeter walls poses significant challenges in terms of building physics and loss of habitable space, it is sometimes an inevitable choice because of practical or legislative constraints. Innovative solutions are then required to deliver satisfying performances and reduce nuisance to inhabitants of residential buildings in case they are going to remain in their flats during the retrofit works.Three systems for inner thermal retrofitting purposes have been designed and produced as prototypes. Two of them are composed by silica aerogel containing fibrous material: the first one is a rigid flat laminated panel, the second one is a rollable solution with a fabric finishing layer. The third insulating system is a perlite based board with a hydrophobic layer. All the materials composing the retrofit solutions have been characterized by means of laboratory tests in order to measure their main hygrothermal properties. In fact, some parameters are fundamental for determining the hygrothermal performance of the composite systems: thermal conductivity, at dry and wet state (moisture dependant), water vapour diffusion resistance factor, hygroscopic sorption at isotherm condition and water absorption coefficient. All those measured data were necessary for optimizing the solutions, guaranteeing energy efficiency and vapour open layers to systems that are intended for installation on existing walls

A Multi-Wavelength Infrared Study of NGC 891

We present a multi-wavlength infrared study of the nearby, edge-on, spiral galaxy NGC 891. We have examined 20 independent, spatially resolved IR images of this galaxy, 14 of which are newly reduced and/or previously unpublished images. These images span a wavelength regime from 1.2 microns in which the emission is dominated by cool stars, through the MIR, in which emission is dominated by PAHs, to 850 microns, in which emission is dominated by cold dust in thermal equilibrium with the radiation field. The changing morphology of the galaxy with wavelength illustrates the changing dominant components. We detect extra-planar dust emission in this galaxy, consistent with previously published results, but now show that PAH emission is also in the halo, to a vertical distance of z >= 2.5 kpc. We compare the vertical extents of various components and find that the PAHs (from 7.7 and 8 micron data) and warm dust (24 microns) extend to smaller z heights than the cool dust (450 microns). For six locations in the galaxy for which the S/N was sufficient, we present SEDs of the IR emission, including two in the halo - the first time a halo SED in an external galaxy has been presented. We have modeled these SEDs and find that the PAH fraction is similar to Galactic values (within a factor of two), with the lowest value at the galaxy's center, consistent with independent results of other galaxies. In the halo environment, the fraction of dust exposed to a colder radiation field, is of order unity, consistent with an environment in which there is no star formation. The source of excitation is likely from photons escaping from the disk.Comment: 24 pages, 17 figures, 7 tables, accepted for publication in MNRA

Interstellar C60+

Buckminsterfullerene (C60) was recently detected through its infrared emission bands in the interstellar medium (ISM), including in the proximity of massive stars, where physical conditions could favor the formation of the cationic form, C60+. In addition, C60+ was proposed as the carrier of two diffuse interstellar bands in the near-IR, although a firm identification still awaits for gas-phase spectroscopic data. We examined in details the Spitzer IRS spectra of the NGC 7023 reflection nebula, at a position close (7.5") to the illuminating B star HD 200775, and found four previously unreported bands at 6.4, 7.1, 8.2 and 10.5 \mu m in addition to the classical bands attributed to Polycylic Aromatic Hydrocarbons (PAHs) and neutral C60. These 4 bands are observed only in this region of the nebula, while C60 emission is still present slightly further away from the star, and PAH emission even further away. Based on this observation, on theoretical calculations we perform, and on laboratory studies, we attribute these bands to C60+. The detection of C60+ confirms the idea that large carbon molecules exist in the gas-phase in these environments. In addition, the relative variation of the C60, and C60+, band intensities constitutes a potentially powerful probe of the physical conditions in highly UV-irradiated regions.Comment: Accepted for publication in A&A, v2: minor corrections of typos and language and additional reference include