Deuteration as an evolutionary tracer in massive-star formation

Theory predicts, and observations confirm, that the column density ratio of a molecule containing D to its counterpart containing H can be used as an evolutionary tracer in the low-mass star formation process. Since it remains unclear if the high-mass star formation process is a scaled-up version of the low-mass one, we investigated whether the relation between deuteration and evolution can be applied to the high-mass regime. With the IRAM-30m telescope, we observed rotational transitions of N2D+ and N2H+ and derived the deuterated fraction in 27 cores within massive star-forming regions understood to represent different evolutionary stages of the massive-star formation process. Results. Our results clearly indicate that the abundance of N2D+ is higher at the pre-stellar/cluster stage, then drops during the formation of the protostellar object(s) as in the low-mass regime, remaining relatively constant during the ultra-compact HII region phase. The objects with the highest fractional abundance of N2D+ are starless cores with properties very similar to typical pre-stellar cores of lower mass. The abundance of N2D+ is lower in objects with higher gas temperatures as in the low-mass case but does not seem to depend on gas turbulence. Our results indicate that the N2D+-to-N2H+ column density ratio can be used as an evolutionary indicator in both low- and high-mass star formation, and that the physical conditions influencing the abundance of deuterated species likely evolve similarly during the processes that lead to the formation of both low- and high-mass stars.Comment: Accepted by A&AL, 4 pages, 2 figures, 2 appendices (one for Tables, one for additional figures

Search for massive protostellar candidates in the southern hemisphere: I. Association with dense gas

(Abridged) We have observed CS and C17O lines, and 1.2 mm cont. emission towards a sample of 130 high-mass protostellar candidates with DEC<-30 deg. This is the first step of the southern extension of a project started more than a decade ago aimed at the identification of massive protostellar candidates. We selected from the IRAS PSC 429 sources which potentially are compact molecular clouds. The sample is divided into two groups: the 298 sources with [25-12]>0.57 and [60-12]>1.30 we call 'High' sources, the remaining 131 we call 'Low' sources. In this paper, we check the association with dense gas and dust in 130 'Low' sources. We find a detection rate of ca. 85% in CS, demonstrating a tight association with dense molecular clumps. Among the sources detected in CS, ca. 76% have also been detected in C17O and ca. 93% in the 1.2 mm cont. Mm-cont. maps show the presence of clumps with diameters 0.2-2 pc and masses from a few Msun to 10^5 Msun; H2 volume densities lie between ca. 10^{4.5} and 10^{5.5} cm^{-3}. The L(bol) are 10^3-10^6 Lsun, consistent with embedded high-mass objects. Based on our results and those found in the literature for other samples, we conclude that our sources are massive objects probably in a stage prior to the formation of an HII region. We propose a scenario in which 'High' and 'Low' sources are both made of a massive clump hosting a high-mass protostellar candidate and a nearby stellar cluster. The difference might be due to the fact that the IRAS 12mu flux, the best discriminant between the two groups, is dominated by the emission from the cluster in 'Lows' and from the massive protostellar object in 'Highs'.Comment: Accepted for publication in Astron. & Astroph.; 34 pages (incl. 14 figures and 8 tables

The L1157-B1 astrochemical laboratory: testing the origin of DCN

L1157-B1 is the brightest shocked region of the large-scale molecular outflow, considered the prototype of chemically rich outflows, being the ideal laboratory to study how shocks affect the molecular gas. Several deuterated molecules have been previously detected with the IRAM 30m, most of them formed on grain mantles and then released into the gas phase due to the shock. We aim to observationally investigate the role of the different chemical processes at work that lead to formation the of DCN and test the predictions of the chemical models for its formation. We performed high-angular resolution observations with NOEMA of the DCN(2-1) and H13CN(2-1) lines to compute the deuterated fraction, Dfrac(HCN). We detected emission of DCN(2-1) and H13CN(2-1) arising from L1157-B1 shock. Dfrac(HCN) is ~4x10$^{-3}$ and given the uncertainties, we did not find significant variations across the bow-shock. Contrary to HDCO, whose emission delineates the region of impact between the jet and the ambient material, DCN is more widespread and not limited to the impact region. This is consistent with the idea that gas-phase chemistry is playing a major role in the deuteration of HCN in the head of the bow-shock, where HDCO is undetected as it is a product of grain-surface chemistry. The spectra of DCN and H13CN match the spectral signature of the outflow cavity walls, suggesting that their emission result from shocked gas. The analysis of the time dependent gas-grain chemical model UCL-CHEM coupled with a C-type shock model shows that the observed Dfrac(HCN) is reached during the post-shock phase, matching the dynamical timescale of the shock. Our results indicate that the presence of DCN in L1157-B1 is a combination of gas-phase chemistry that produces the widespread DCN emission, dominating in the head of the bow-shock, and sputtering from grain mantles toward the jet impact region.Comment: Accepted for publication in A&A. 7 pages, 5 Figures, 1 Tabl

First ALMA maps of HCO, an important precursor of complex organic molecules, towards IRAS 16293-2422

The formyl radical HCO has been proposed as the basic precursor of many complex organic molecules such as methanol (CH$_3$OH) or glycolaldehyde (CH$_2$OHCHO). Using ALMA, we have mapped, for the first time at high angular resolution ($\sim$1$^{\prime\prime}$, $\sim$140 au), HCO towards the Solar-type protostellar binary IRAS 16293$-$2422, where numerous complex organic molecules have been previously detected. We also detected several lines of the chemically related species H$_2$CO, CH$_3$OH and CH$_2$OHCHO. The observations revealed compact HCO emission arising from the two protostars. The line profiles also show redshifted absorption produced by foreground material of the circumbinary envelope that is infalling towards the protostars. Additionally, IRAM 30m single-dish data revealed a more extended HCO component arising from the common circumbinary envelope. The comparison between the observed molecular abundances and our chemical model suggests that whereas the extended HCO from the envelope can be formed via gas-phase reactions during the cold collapse of the natal core, the HCO in the hot corinos surrounding the protostars is predominantly formed by the hydrogenation of CO on the surface of dust grains and subsequent thermal desorption during the protostellar phase. The derived abundance of HCO in the dust grains is high enough to produce efficiently more complex species such as H$_2$CO, CH$_3$OH, and CH$_2$OHCHO by surface chemistry. We found that the main formation route of CH$_2$OHCHO is the reaction between HCO and CH$_2$OH.Comment: Accepted in Monthly Notices of the Royal Astronomical Society; 19 pages, 12 figures, 7 table

Water and acetaldehyde in HH212: The first hot corino in Orion

Aims: Using the unprecedented combination of high resolution and sensitivity offered by ALMA, we aim to investigate whether and how hot corinos, circumstellar disks, and ejected gas are related in young solar-mass protostars. Methods: We observed CH$_3$CHO and deuterated water (HDO) high-excitation ($E_{\rm u}$ up to 335 K) lines towards the Sun-like protostar HH212--MM1. Results: For the first time, we have obtained images of CH$_3$CHO and HDO emission in the inner $\simeq$ 100 AU of HH212. The multifrequency line analysis allows us to contrain the density ($\geq$ 10$^{7}$ cm$^{-3}$), temperature ($\simeq$ 100 K), and CH$_3$CHO abundance ($\simeq$ 0.2--2 $\times$ 10$^{-9}$) of the emitting region. The HDO profile is asymmetric at low velocities ($\leq$ 2 km s$^{-1}$ from $V_{\rm sys}$). If the HDO line is optically thick, this points to an extremely small ($\sim$ 20--40 AU) and dense ($\ge$ 10$^{9}$ cm$^{-3}$) emitting region. Conclusions: We report the first detection of a hot corino in Orion. The HDO asymmetric profile indicates a contribution of outflowing gas from the compact central region, possibly associated with a dense disk wind.Comment: Astronomy & Astrophysics Letter, in pres

The NH2D/NH3 ratio toward pre-protostellar cores around the UCHII region in IRAS 20293+3952

The deuterium fractionation, Dfrac, has been proposed as an evolutionary indicator in pre-protostellar and protostellar cores of low-mass star-forming regions. We investigate Dfrac, with high angular resolution, in the cluster environment surrounding the UCHII region IRAS 20293+3952. We performed high angular resolution observations with the IRAM Plateau de Bure Interferometer (PdBI) of the ortho-NH2D 1_{11}-1_{01} line at 85.926 GHz and compared them with previously reported VLA NH3 data. We detected strong NH2D emission toward the pre-protostellar cores identified in NH3 and dust emission, all located in the vicinity of the UCHII region IRAS 20293+3952. We found high values of Dfrac~0.1-0.8 in all the pre-protostellar cores and low values, Dfrac<0.1, associated with young stellar objects. The high values of Dfrac in pre-protostellar cores could be indicative of evolution, although outflow interactions and UV radiation could also play a role.Comment: 5 pages, 3 figures. Accepted for publication in Astronomy and Astrophysics Letter

Broad N2H+ emission towards the protostellar shock L1157-B1

We present the first detection of N2H+ towards a low-mass protostellar outflow, namely the L1157-B1 shock, at about 0.1 pc from the protostellar cocoon. The detection was obtained with the IRAM 30-m antenna. We observed emission at 93 GHz due to the J = 1-0 hyperfine lines. The analysis of the emission coupled with the HIFI CHESS multiline CO observations leads to the conclusion that the observed N2H+(1-0) line originates from the dense (> 10^5 cm-3) gas associated with the large (20-25 arcsec) cavities opened by the protostellar wind. We find a N2H+ column density of few 10^12 cm-2 corresponding to an abundance of (2-8) 10^-9. The N2H+ abundance can be matched by a model of quiescent gas evolved for more than 10^4 yr, i.e. for more than the shock kinematical age (about 2000 yr). Modelling of C-shocks confirms that the abundance of N2H+ is not increased by the passage of the shock. In summary, N2H+ is a fossil record of the pre-shock gas, formed when the density of the gas was around 10^4 cm-3, and then further compressed and accelerated by the shock.Comment: ApJ, in pres