Lead Isotope Data for Gold-Bearing Veins and Their Host Metasedimentary Rocks of the Goldenville Formation, Eastern Nova Scotia

Lead isotope analyses have been determined for galenas which occur in small quantities in quartz veins in the Goldenville Formation of the Meguma Terrane, and also for five whole rock samples from this formation- The ten least radiogenic galenas are homogeneous in isotopic composition, and they plot close to the average terrestrial growth curve of Stacey and Kramers and the "orogene" curve of Doe and Zartman. The mean model ages are 550 Ma (Stacey and Kramers) and 600 Ma (Doe and Zartman), which are in approximate agreement with the Cambro-Ordovician age of deposition of the sediments. The close position of the galena compositions to these average growth curves suggests that these compositions were established by mixing processes as envisaged in the Doe and Zartman "plumbotectonics" model. The isotopic analyses of the whole rocks indicate that small amounts of radiogenic lead are present in non-mineralized sections of the sedimentary sequence- Three galenas from veins in rocks metamorphosed to biotite and staurolite-andalusite grades, and from late veins (post-dating deformation, metamorphism and plutonism) are significantly more radiogenic than the majority of the samples. We interpret the isotopic characteristics of these galenas to be the result of extraction of lead from Meguma metasediments or of additions of radiogenic lead to less radiogenic lead during remobllization. Other interpretations consistent with the isotopic data are possible. RÉSUMÉ Des analyses aux isotopes de plomb ont été déterminé pour les galènes qui se trouvent en petite quantitié's dans les veines de quartz de la formation Goldenville du terrane Meguma, et aussi pour cinq échantillons de roches entieres de cette formation. Les dix galènes les moins radiogèniques sont homogènes en composition isotopique, et elles ont une trace proche de la courbe de croissauce terreste moyenne de Stacey et Kramers, et de la courbe "orogène" de Doe et Zartman. Le âges moyens des modules sont de 550 Ma (Stacey et Kramers) et de 600 Ma (Doe et Zartman), ce qui s'accorde approximativement avec l'âge Cambro-Ordovicien du dépôt des sédiments. La position proche des compositions de la galène avec ces courbes moyennes de croissance, indique que ces compositions ont été établies par un processus de mélanges, comme le propose le modèle "Piumbotectonique" de Doe et Zartman. Les analyses isotopiques de roche entiere indiquent que de petites quantitié's de plomb radiogenique sont présences dans les sections non-minéralisees de la séquence sédimentaire. Trois galènes, provenant de veines de roches métamorphosée au dégris de biotite et de staurolite-anda lusite, et de veines avancées (post-datant la déformation, le métamorphisine et le plutonisme) sont d'une maniere significative plus radiogèniques que la majoritié des échantillons. Nous interprètons les caractéristiques isotopiques de ces galènes comme le résultat de l'extraction de plomb des méta-sédiments Meguma, ou a L’addition de plomb radiogènique au plomb moins radiogènique durant la remobilisation. D'autres Interprètations en accord avec les donnés isotopiques sont possible. [Traduit par le journal

The role of ice particle shapes and size distributions in the single scattering properties of cirrus clouds

The roles of ice particle size distributions (SDs) and particle shapes in cirrus cloud solar radiative transfer are investigated by analyzing SDs obtained from optical array probe measurements (particle sizes larger than 20–40 μm) during intensive field observations of the International Cirrus Experiment, the European Cloud and Radiation Experiment, the First ISCCP Regional Experiment, and the Central Equatorial Pacific Experiment. It is found that the cloud volume extinction coefficient is more strongly correlated with the total number density than with the effective particle size. Distribution-averaged mean single scattering properties are calculated for hexagonal columns, hexagonal plates, and polycrystals at a nonabsorbing (0.5 μm), moderately absorbing (1.6 μm), and strongly absorbing (3.0 μm) wavelength. At 0.5 μm (1.6 μm) (3.0 μm), the spread in the resulting mean asymmetry parameters due to different SDs is smaller than (comparable to) (smaller than) the difference caused by applying different particle shapes to these distributions. From a broadband solar radiative transfer point of view it appears more important to use the correct particle shapes than to average over the correct size distributions

Inter-observer agreement of canine and feline paroxysmal event semiology and classification by veterinary neurology specialists and non-specialists

Background: Advances in mobile technology mean vets are now commonly presented with videos of paroxysmal events by clients, but the consistency of the interpretation of these videos has not been investigated. The objective of this study was to investigate the level of agreement between vets (both neurology specialists and non-specialists) on the description and classification of videos depicting paroxysmal events, without knowing any results of diagnostic workup. An online questionnaire study was conducted, where participants watched 100 videos of dogs and cats exhibiting paroxysmal events and answered questions regarding: epileptic seizure presence (yes/ no), seizure type, consciousness status, and the presence of motor, autonomic and neurobehavioural signs. Agreement statistics (percentage agreement and kappa) calculated for each variable, with prevalence indices calculated to aid their interpretation. Results: Only a fair level of agreement (kappa = 0.40) was found for epileptic seizure presence. Overall agreement of seizure type was moderate (kappa = 0.44), with primary generalised seizures showing the highest level of agreement (kappa = 0.60), and focal the lowest (kappa = 0.31). Fair agreement was found for consciousness status and the presence of autonomic signs (kappa = 0.21-0.40), but poor agreement for neurobehavioral signs (kappa = 0.16). Agreement for motor signs ranged from poor (kappa = <= 0.20) to moderate (kappa = 0.41-0.60). Differences between specialists and non-specialists were identified. Conclusions: The relatively low levels of agreement described here highlight the need for further discussions between neurology experts regarding classifying and describing epileptic seizures, and additional training of non-specialists to facilitate accurate diagnosis. There is a need for diagnostic tools (e.g. electroencephalogram) able to differentiate between epileptic and non-epileptic paroxysms

VALUE study : a protocol for a qualitative semi-structured interview study of IVF add-ons use by patients, clinicians and embryologists in the UK and Australia

Funding This research was funded by an Obstetrics and Gynaecology Innovation Grant from the University of Melbourne Australia. MP is supported by a University of Melbourne Department of Obstetrics and Gynaecology MCR Fellowship. Acknowledgements Our heartfelt thanks to our PPI panel who gave up their time to contribute to the development of VALUE. UK: Isabella Dash, Jennifer Nisbett, Hannah Reid, Ally Richardson, Victoria Thomas, Bassel Wattar. Australia: Katherine Gobbi, Hilary Smith, Natasha Devetak, Alex Polyakov, Anna Ninnis, Lisa Lee, Vadim Mirmilstein.Peer reviewedPublisher PD

Environmental Effects on Oxygen Isotope Enrichment of Leaf Water in Cotton Leaves

The oxygen isotope enrichment of bulk leaf water (Db) was measured in cotton (Gossypium hirsutum) leaves to test the Craig- Gordon and Farquhar-Gan models under different environmental conditions. Db increased with increasing leaf-to-air vapor pressure difference (VPd) as an overall result of the responses to the ratio of ambient to intercellular vapor pressures (ea/ei) and to stomatal conductance (gs). The oxygen isotope enrichment of lamina water relative to source water ðD1Þ; which increased with increasing VPd, was estimated by mass balance between less enriched water in primary veins and enriched water in the leaf. The Craig-Gordon model overestimated Db (and D1Þ; as expected. Such discrepancies increased with increase in transpiration rate (E), supporting the Farquhar-Gan model, which gave reasonable predictions of Db and D1 with an L of 7.9 mm, much less than the total radial effective length Lr of 43 mm. The fitted values of L for D1 of individual leaves showed little dependence on VPd and temperature, supporting the assumption that the Farquhar-Gan formulation is relevant and useful in describing leaf water isotopic enrichment

Carbon stable isotope analysis of cereal remains as a way to reconstruct water availability: preliminary results

Reconstructing past water availability, both as rainfall and irrigation, is important to answer questions about the way society reacts to climate and its changes and the role of irrigation in the development of social complexity. Carbon stable isotope analysis of archaeobotanical remains is a potentially valuable method for reconstructing water availability. To further define the relationship between water availability and plant carbon isotope composition and to set up baseline values for the Southern Levant, grains of experimentally grown barley and sorghum were studied. The cereal crops were grown at three stations under five different irrigation regimes in Jordan. Results indicate that a positive but weak relationship exists between irrigation regime and total water input of barley grains, but no relationship was found for sorghum. The relationship for barley is site-specific and inter-annual variation was present at Deir ‘Alla, but not at Ramtha and Khirbet as-Samra

The effects of a video intervention on posthospitalization pulmonary rehabilitation uptake

Rationale: Pulmonary rehabilitation (PR) after hospitalizations for exacerbations of chronic obstructive pulmonary disease (COPD) improves exercise capacity and health-related quality of life and reduces readmissions. However, posthospitalization PR uptake is low. To date, no trials of interventions to increase uptake have been conducted.Objectives: To study the effect of a codesigned education video as an adjunct to usual care on posthospitalization PR uptake.Methods: The present study was an assessor- and statistician-blinded randomized controlled trial with nested, qualitative interviews of participants in the intervention group. Participants hospitalized with COPD exacerbations were assigned 1:1 to receive either usual care (COPD discharge bundle including PR information leaflet) or usual care plus the codesigned education video delivered via a handheld tablet device at discharge. Randomization used minimization to balance age, sex, FEV1 % predicted, frailty, transport availability, and previous PR experience.Measurements and Main Results: The primary outcome was PR uptake within 28 days of hospital discharge. A total of 200 patients were recruited, and 196 were randomized (51% female, median FEV1% predicted, 36 [interquartile range, 27-48]). PR uptake was 41% and 34% in the usual care and intervention groups, respectively (P = 0.37), with no differences in secondary (PR referral and completion) or safety (readmissions and death) endpoints. A total of 6 of the 15 participants interviewed could not recall receiving the video.Conclusions: A codesigned education video delivered at hospital discharge did not improve posthospitalization PR uptake, referral, or completion

Canonical thermalization

For quantum systems that are weakly coupled to a much 'bigger' environment, thermalization of possibly far from equilibrium initial ensembles is demonstrated: for sufficiently large times, the ensemble is for all practical purposes indistinguishable from a canonical density operator under conditions that are satisfied under many, if not all, experimentally realistic conditions

Large sulfur isotope fractionations in Martian sediments at Gale crater

Variability in the sulfur isotopic composition in sediments can reflect atmospheric, geologic and biological processes. Evidence for ancient fluvio-lacustrine environments at Gale crater on Mars and a lack of efficient crustal recycling mechanisms on the planet suggests a surface environment that was once warm enough to allow the presence of liquid water, at least for discrete periods of time, and implies a greenhouse effect that may have been influenced by sulfur-bearing volcanic gases. Here we report in situ analyses of the sulfur isotopic compositions of SO2 volatilized from ten sediment samples acquired by NASA’s Curiosity rover along a 13 km traverse of Gale crater. We find large variations in sulfur isotopic composition that exceed those measured for Martian meteorites and show both depletion and enrichment in 34S. Measured values of δ34S range from −47 ± 14‰ to 28 ± 7‰, similar to the range typical of terrestrial environments. Although limited geochronological constraints on the stratigraphy traversed by Curiosity are available, we propose that the observed sulfur isotopic signatures at Gale crater can be explained by equilibrium fractionation between sulfate and sulfide in an impact-driven hydrothermal system and atmospheric processing of sulfur-bearing gases during transient warm periods