Vertical segregation among pathways mediating nitrogen loss (N2 and N2O production) across the oxygen gradient in a coastal upwelling ecosystem

Indexación: ScopusThe upwelling system off central Chile (36.5 S) is seasonally subjected to oxygen (O2)-deficient waters, with a strong vertical gradient in O2 (from oxic to anoxic conditions) that spans a few metres (30-50€m interval) over the shelf. This condition inhibits and/or stimulates processes involved in nitrogen (N) removal (e.g. anammox, denitrification, and nitrification). During austral spring (September 2013) and summer (January 2014), the main pathways involved in N loss and its speciation, in the form of N2 and/or N2O, were studied using 15N-tracer incubations, inhibitor assays, and the natural abundance of nitrate isotopes along with hydrographic information. Incubations were developed using water retrieved from the oxycline (25€m depth) and bottom waters (85€m depth) over the continental shelf off Concepción, Chile. Results of 15N-labelled incubations revealed higher N removal activity during the austral summer, with denitrification as the dominant N2-producing pathway, which occurred together with anammox at all times. Interestingly, in both spring and summer maximum potential N removal rates were observed in the oxycline, where a greater availability of oxygen was observed (maximum O2 fluctuation between 270 and 40€μmol€L'1) relative to the hypoxic bottom waters ( < €20€μmol€O2€L'1). Different pathways were responsible for N2O produced in the oxycline and bottom waters, with ammonium oxidation and dissimilatory nitrite reduction, respectively, as the main source processes. Ammonium produced by dissimilatory nitrite reduction to ammonium (DNiRA) could sustain both anammox and nitrification rates, including the ammonium utilized for N2O production. The temporal and vertical variability of /15N-NO3' confirms that multiple N-cycling processes are modulating the isotopic nitrate composition over the shelf off central Chile during spring and summer. N removal processes in this coastal system appear to be related to the availability and distribution of oxygen and particles, which are a source of organic matter and the fuel for the production of other electron donors (i.e. ammonium) and acceptors (i.e. nitrate and nitrite) after its remineralization. These results highlight the links between several pathways involved in N loss. They also establish that different mechanisms supported by alternative N substrates are responsible for substantial accumulation of N2O, which are frequently observed as hotspots in the oxycline and bottom waters. Considering the extreme variation in oxygen observed in several coastal upwelling systems, these findings could help to understand the ecological and biogeochemical implications due to global warming where intensification and/or expansion of the oceanic OMZs is projected.https://www.biogeosciences.net/14/4795/2017

Inter-annual variability of the Pelagic-Benthic coupling in the upwelling system off central Chile

International audienceThe coastal region of central Chile (36° S) is one of the most productive coastal systems, characterized by a marked seasonality in the upwelling regime, that brings subsurface waters rich in nutrient and poor in oxygen (ESSW) into the euphotic zone. This oceanographic condition depends basically on the equatorward wind strength and is modified on different time scales, with the El Niño-Southern Oscillation (ENSO) phenomenon as the main source of interannual variability in the Pacific Ocean. Here we present an effort to integrate physical and biogeochemical variability associated with in situ information and experiments at coastal stations off central Chile (36° S) in order to improve the knowledge on the pelagic-benthic coupling in this upwelling system during the warm ENSO phase or El Niño. Carbon fluxes exported from the water column to the sediments and the ammonium exchange across the sediment-water interface are discussed together with oceanographic and benthic conditions. All measurements and estimations were carried out from May 1997 until April 2001 at two stations, one located inside Concepción Bay (~28 m depth), and the other on the continental shelf at ~36° S (~88 m depth). The results show that the pelagic and benthic systems are strongly coupled off central Chile (36° S). Oceanographic variability associated with upwelling events (seasonal scale) and an El Niño event (interannual scale) was observed. The carbon fluxes exported to the sediments, the benthic conditions (i.e., quantity and quality of the sediment organic matter), and the ammonium exchange across the sediment-water interface, responded to the seasonal regime of upwelling during non El Niño years as well as to the ENSO related oceanographic variability

Diacritical study of light, electrons, and sound scattering by particles and holes

We discuss the differences and similarities in the interaction of scalar and vector wave-fields with particles and holes. Analytical results are provided for the transmission of isolated and arrayed small holes as well as surface modes in hole arrays for light, electrons, and sound. In contrast to the optical case, small-hole arrays in perforated perfect screens cannot produce acoustic or electronic surface-bound states. However, unlike electrons and light, sound is transmitted through individual holes approximately in proportion to their area, regardless their size. We discuss these issues with a systematic analysis that allows exploring both common properties and unique behavior in wave phenomena for different material realizations.Comment: 3 figure

Electronic and Geometric Corrugation of Periodically Rippled, Self-nanostructured Graphene Epitaxially Grown on Ru(0001)

Graphene epitaxially grown on Ru(0001) displays a remarkably ordered pattern of hills and valleys in Scanning Tunneling Microscopy (STM) images. To which extent the observed "ripples" are structural or electronic in origin have been much disputed recently. A combination of ultrahigh resolution STM images and Helium Atom diffraction data shows that i) the graphene lattice is rotated with respect to the lattice of Ru and ii) the structural corrugation as determined from He diffraction is substantially smaller (0.015 nm) than predicted (0.15 nm) or reported from X-Ray Diffraction or Low Energy Electron Diffraction. The electronic corrugation, on the contrary, is strong enough to invert the contrast between hills and valleys above +2.6 V as new, spatially localized electronic states enter the energy window of the STM. The large electronic corrugation results in a nanostructured periodic landscape of electron and holes pockets.Comment: 16 pages, 6 figure

Experimental investigation of dynamical invariants in bipartite entanglement

The non-conservation of entanglement, when two or more particles interact, sets it apart from other dynamical quantities like energy and momentum. It does not allow the interpretation of the subtle dynamics of entanglement as a flow of this quantity between the constituents of the system. Here we show that adding a third party to a two-particle system may lead to a conservation law that relates the quantities characterizing the bipartite entanglement between each of the parties and the other two. We provide an experimental demonstration of this idea using entangled photons, and generalize it to N-partite GHZ states

Direct analysis of Antarctic krill by slurry sampling: determination of copper, iron, manganese and zinc by flame atomic absorption spectrometry

Slurry sampling in combination with flame atomic absorption spectrometry was employed for the direct determination of four essential trace elements, namely Cu, Fe, Mn and Zn in Antarctic krill. The effect of instrumental operating conditions and slurry sampling preparation on the analytical signal was investigated. For the determination of Cu, Fe and Zn, samples were suspended in a solution containing 2 mol L-1 HNO3. In the case of Mn, 4 mol L-1 HNO3 was necessary for the preparation of the slurry. The precision between sample replicates was better than 5%. The method was applied to the direct determination of Cu, Fe, Mn and Zn in Antarctic krill samples using aqueous reference solutions to prepare the calibration curves. The results obtained were in good agreement with those achieved by FAAS and ICP-AES after microwave-assisted wet digestion of the krill samples. The detection limits were 4.5, 1.0, 4.9 and 8.4 mug L-1 for Cu, Zn, Mn and Fe, respectively.A técnica de amostragem de suspensão aliada à espectrometria de absorção atômica com chama foi empregada para a determinação direta de Cu, Fe, Mn e Zn em matrizes de Krill antártico. O efeito dos parâmetros instrumentais e o preparo das suspensões foram estudados em função do sinal analítico. Para a determinação de Cu, Fe e Zn, as amostras foram suspensas em uma solução de HNO3 2,0 mol L-1 e para a determinação de Mn, o krill foi suspenso em uma solução de HNO3 4,0 mol L-1. A precisão entre as replicas foi melhor que 5 %. A metodologia foi aplicada para a determi-nação direta de Cu, Fe, Mn e Zn em amostras de krill antártico, usando padrões aquosos no preparo das curvas analíticas. Os resultados obtidos estão concordantes com os encontrados na determinação por FAAS e ICP-AES, depois da digestão das amostras em um forno de microondas. Os limites de detecção foram 4,5; 1,0; 4,9 e 8,4 mig L-1 para Cu, Zn, Mn e Fe, respectivamente.365370Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq

Shadow of your former self: Exploring project leaders’ post-failure behaviors (resilience, self-esteem and self-efficacy) in high-tech startup projects

Globally, demands for sustainable strategies in the ICT industry have attracted greater momentum as high-tech projects continue to fail in large numbers. Recent studies have underpinned project resilience as a major factor for overcoming these increasing project failures, delays, or ter-mination. However, the complex behaviors of resilient project leaders, especially in post-failure conditions, have been largely overlooked. To address this critical research gap, the present study identifies the direct relationships between three potential behavioral traits of project leaders (i.e., resilience, self-esteem, and self-efficacy) and examines how they move forward beyond project failures. The present study also explored whether self-esteem mediates project leaders’ resilience and self-efficacy. Drawing on data from 232 project leaders in Pakistan’s high-tech start-ups, the new findings suggest that there are significant positive effects of project leaders’ resilience and self-esteem on their self-efficacy, and that project leaders’ resilience and self-efficacy is significantly mediated by their self-esteem. As the project resilience theory gains traction, the present study findings have pinpointed major steps for meeting project challenges ahead of time, allowing leaders and teams to learn from failures, and also for improving organisations’ ability to implement successful and sustainable high-tech projects especially in emerging economies

A high-reflectivity, ambient-stable graphene mirror for neutral atomic and molecular beams

The following article appeared in Applied Physics Letters Volume 99, Issue 21, 21 November 2011, Article number 211907 and may be found at http://scitation.aip.org/content/aip/journal/apl/99/21/10.1063/1.3663866We report a He and H2 diffraction study of graphene-terminated Ru(0001) thin films grown epitaxially on c-axis sapphire. Even for samples exposed for several weeks to ambient conditions, brief annealing in ultrahigh vacuum restored extraordinarily high specular reflectivities for He and H 2 beams (23 and 7 of the incident beam, respectively). The quality of the angular distributions recorded with both probes exceeds the one obtained from in-situ prepared graphene on Ru(0001) single crystals. Our results for graphene-terminated Ru thin films represent a significant step toward ambient tolerant, high-reflectivity curved surface mirrors for He-atom microscopyWork performed in part at the Center for Functional Nanomaterials, Brookhaven National Laboratory, which issupported by the U.S. Department of Energy, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886. Work supported by the Ministerio de Educacion y Ciencia through projects CONSOLIDER-INGENIO 2010 on Molecular Nanoscience (CSD 2007-00010), FIS2010-18847, and byComunidad de Madrid through the program NANOBIOMAGNET (S2009/MAT-1726)

Calibration and validation of an aerodynamic method to estimate the spatial variability of sensible and latent heat fluxes over a drip irrigated Merlot vineyard

A study was carried out to calibrate and validate the aerodynamic temperature method for estimating the spatial variability of the sensible (H) and latent (LE) heat fluxes over a drip-irrigated merlot vineyard located in the Maule Region, in Chile. For this study, measurement of energy balance components and meteorological data were collected from the 2006 to 2010 growing seasons. The experimental plot was composed of a 4.25 ha of ‘Merlot’ vineyard, which was equipped with an Eddy- Covariance system and an automatic weather station. The k-fold cross-validation method was utilized to tune and validate a vineyard surface aerodynamic temperature (Taero) model, considering all of the days when Landsat scenes and ground measurements of meteorological data and surface energy balance (SEB) were available. Then, the satellite-based estimations of Taero were utilized to calculate the surface aerodynamic resistance (rah) and, subsequently, heat fluxes of H and LE. Results indicated that the estimated H and rah values were not significantly different to those measured in the vineyard (95% significance level) showing a root mean square (RMSE) and mean absolute error (MAE) between 34–29 W m−2 and 1.01–0.78 s m−1, respectively. Satellite-based computations of LE were somewhat higher than those measured at the time of satellite overpass (RMSE = 63 W m−2; MAE = 56 W m−2), presumably due to the biases embedded in the net radiation (Rn) and soil heat flux (G) computations. The proposed SEB method based on Taero is very simple to implement, presenting similar accuracies on ET mapping to those computed by complex satellitebased models.Sociedad Argentina de Informática e Investigación Operativ