4,548 research outputs found
Reversible Fluorination of Graphene: towards a Two-Dimensional Wide Bandgap Semiconductor
We report the synthesis and evidence of graphene fluoride, a two-dimensional
wide bandgap semiconductor derived from graphene. Graphene fluoride exhibits
hexagonal crystalline order and strongly insulating behavior with resistance
exceeding 10 G at room temperature. Electron transport in graphene
fluoride is well described by variable-range hopping in two dimensions due to
the presence of localized states in the band gap. Graphene obtained through the
reduction of graphene fluoride is highly conductive, exhibiting a resistivity
of less than 100 k at room temperature. Our approach provides a new
path to reversibly engineer the band structure and conductivity of graphene for
electronic and optical applications.Comment: 7 pages, 5 figures, revtex, to appear in PR
Direct observation and imaging of a spin-wave soliton with like symmetry
The prediction and realization of magnetic excitations driven by electrical
currents via the spin transfer torque effect, enables novel magnetic
nano-devices where spin-waves can be used to process and store information. The
functional control of such devices relies on understanding the properties of
non-linear spin-wave excitations. It has been demonstrated that spin waves can
show both an itinerant character, but also appear as localized solitons. So
far, it was assumed that localized solitons have essentially cylindrical,
like symmetry. Using a newly developed high-sensitivity time-resolved
magnetic x-ray microscopy, we instead observe the emergence of a novel
localized soliton excitation with a nodal line, i.e. with like symmetry.
Micromagnetic simulations identify the physical mechanism that controls the
transition from to like solitons. Our results suggest a potential new
pathway to design artificial atoms with tunable dynamical states using
nanoscale magnetic devices
Social physique anxiety and physical activity in early adolescent girls : the influence of maturation and physical activity motives
This study considered the influence of maturation on social physique anxiety (SPA), the relationship between SPA and current and future physical activity (PA) levels and the influence of motives for physical activity on this relationship in early adolescent girls (n=162; mean age=11.80±0.33 years). Participants completed the Pubertal Development Scale, the modified Social Physique Anxiety Scale and the Motives for Physical Activity Scale at baseline and the Physical Activity Questionnaire for Older Children at baseline and 6 months later. The girls became less active across the 6 months and girls in the early stages of maturation had significantly lower SPA than the girls in the middle and late stages of maturation. SPA was not related to current or future physical activity in the sample as a whole. Cluster analysis identified four groups with different motive profiles and the High Appearance and Fitness group demonstrated a moderate negative relationship between SPA and PA at phase 1, whereas the other groups did not. These findings indicate that SPA may increase with maturation and the relationship between SPA and PA is dependent on reasons for being active. For girls who are motivated to be active primarily by body-related reasons SPA is likely to lead to lower levels of PA
Electronic structure investigation of Ti3AlC2, Ti3SiC2, and Ti3GeC2 by soft-X-ray emission spectroscopy
The electronic structures of epitaxially grown films of Ti3AlC2, Ti3SiC2 and
Ti3GeC2 have been investigated by bulk-sensitive soft X-ray emission
spectroscopy. The measured high-resolution Ti L, C K, Al L, Si L and Ge M
emission spectra are compared with ab initio density-functional theory
including core-to-valence dipole matrix elements. A qualitative agreement
between experiment and theory is obtained. A weak covalent Ti-Al bond is
manifested by a pronounced shoulder in the Ti L-emission of Ti3AlC2. As Al is
replaced with Si or Ge, the shoulder disappears. For the buried Al and
Si-layers, strongly hybridized spectral shapes are detected in Ti3AlC2 and
Ti3SiC2, respectively. As a result of relaxation of the crystal structure and
the increased charge-transfer from Ti to C, the Ti-C bonding is strengthened.
The differences between the electronic structures are discussed in relation to
the bonding in the nanolaminates and the corresponding change of materials
properties.Comment: 15 pages, 8 figure
Stochastic Model for Surface Erosion Via Ion-Sputtering: Dynamical Evolution from Ripple Morphology to Rough Morphology
Surfaces eroded by ion-sputtering are sometimes observed to develop
morphologies which are either ripple (periodic), or rough (non-periodic). We
introduce a discrete stochastic model that allows us to interpret these
experimental observations within a unified framework. We find that a periodic
ripple morphology characterizes the initial stages of the evolution, whereas
the surface displays self-affine scaling in the later time regime. Further, we
argue that the stochastic continuum equation describing the surface height is a
noisy version of the Kuramoto-Sivashinsky equation.Comment: 4 pages, 7 postscript figs., Revtex, to appear in Phys. Rev. Let
Refining predictions of metacommunity dynamics by modeling species non-independence
Abstract Predicting the dynamics of biotic communities is difficult because species? environmental responses are not independent, but covary due to shared or contrasting ecological strategies and the influence of species interactions. We used latent-variable joint species distribution models to analyse paired historical and contemporary inventories of 585 vascular plant species on 471 islands in the south-west Finnish archipelago. Larger, more heterogeneous islands were characterized by higher colonisation rates and lower extinction rates. Ecological and taxonomical species groups explained small but detectable proportions of variance in species? environmental responses. To assess the potential influence of species interactions on community dynamics, we estimated species associations as species-to-species residual correlations for historical occurrences, for colonisations, and for extinctions. Historical species associations could to some extent predict joint colonisation patterns, but the overall estimated influence of species associations on community dynamics was weak. These results illustrate the benefits of considering metacommunity dynamics within a joint framework, but also suggest that any influence of species interactions on community dynamics may be hard to detect from observational data.Peer reviewe
Imaging, Structural and Chemical Analysis of Silicon Nanowires
Laser ablation has been used to grow silicon nanowires with an average diameter of 6.7 nm ± 2.7 nm surrounded by an amorphous SiOx sheath of 1-2 nm. This paper reports the imaging, chemical and structural analysis of these wires. Due to the growth temperature and the presence of calcium impurities and trace oxygen, two distinct types of wires are found. They appear to grow by two different processes. One requires a metal catalyst, the other is catalyzed by oxygen
Hole Hopping through Tryptophan in Cytochrome P450
Electron-transfer kinetics have been measured in four conjugates of cytochrome P450 with surface-bound Ru-photosensitizers. The conjugates are constructed with enzymes from Bacillus megaterium (CYP102A1) and Sulfolobus acidocaldarius (CYP119). A W96 residue lies in the path between Ru and the heme in CYP102A1, whereas H76 is present at the analogous location in CYP119. Two additional conjugates have been prepared with (CYP102A1)W96H and (CYP119)H76W mutant enzymes. Heme oxidation by photochemically generated Ru^(3+) leads to P450 compound II formation when a tryptophan residue is in the path between Ru and the heme; no heme oxidation is observed when histidine occupies this position. The data indicate that heme oxidation proceeds via two-step tunneling through a tryptophan radical intermediate. In contrast, heme reduction by photochemically generated Ru+ proceeds in a single electron tunneling step with closely similar rate constants for all four conjugates
The biological activity of serum bacterial lipopolysaccharides associates with disease activity and likelihood of achieving remission in patients with rheumatoid arthritis
Peer reviewe
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