Smart dual thermal network

Conventional district heating (DH) systems enable demand aggregation at district level and can provide high centralized heat generation performance values. However, thermal Renewable Energy Sources (RES) deployment at building level still remains low, and exploitation suboptimal, as it is limited by the instantaneous thermal load and storage capacity availability of each building. Buildings play the role of consumers that request a variable amount of heat over time and the thermal network the role of unidirectional heat supplier, without any smart interaction. The FP7 project A2PBEER has developed an innovative Smart Dual Thermal Network concept based on RES and Combined Heat and Power (CHP) as generation technologies, that enables transforming existing suboptimal DH systems, into integrated thermal networks with optimized performance and building level RES system production exploitation. It is based on an innovative Smart Dual Building Thermal Substation concept, which allows a bidirectional heat exchange of the buildings with the thermal network, and to aggregate district level distributed production and storage capacity (Virtual District Plant). With this approach buildings become prosumers maximizing decentralized RES production exploitation, as any possible local heat production surplus on any building of the district, will be delivered to the network to be used by other buildings. Additionally, this thermal network allows the delivery of the energy necessary to meet the heating and cooling demand of the buildings through a single hot water distribution network. In this way, it is possible to upgrade conventional DH systems to district heating and cooling systems, without the construction of a district cooling plant and a dedicated cooling distribution network. Cooling is produced at building level through sorption technologies using locally deployed solar collectors and the thermal network as energy sources. Finally, the district typologies and climatic conditions that maximize the potential of this thermal network concept have been identified.The research activities leading to the described developments and results, were funded by the FP7 project A2PBEER, under grant agreement No 906090. Special thanks to Olof Hallström and ClimateWell AB for making the TRNSYS model of the innovative sorption system and developing the component level simulation work

On-line carbon dots synthesis using flow injection analysis. Application to aluminium determination in water samples

An on-line synthesis of CDots is proposed for the first time, using the flow injection analysis (FIA) technique, which was coupled, in a single system, to the analytical determination of aluminium in water samples. The nanoparticles were obtained from the carbonization of glucose and iron(III) in an acidic medium, and their photoluminescence increased in the presence of aluminium ions. Under optimal experimental conditions, the proposed method has shown an acceptable linearity range –between 0.04 and 3.0 mg L−1 (R2 = 0.9999) – and a detection limit of 0.007 mg L−1. The analysis of drinking water and groundwater samples showed good accuracy (recoveries ranged between 91 – 113%) and RSD% < 13. The on-line system exhibited a high sample throughput (36 h−1), since no incubation time was required.Financial support from Universidad Nacional del Sur (PGI 24/Q099 and 24/Q123, CONICET 11220200102603CO, CONICET 11220200103198CO and the ANPCyT PICT-2019-04458 (2021-2023) is gratefully acknowledged. This research was part of the Ph.D. thesis of Damian Uriarte, which was supported by a doctoral grant funded by Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET). M. Garrido and C.E. Domini wish to thank CONICET

Analysis of instabilities in the Basque Coast Geopark coastal cliffs for its environmentally friendly management (Basque-Cantabrian basin, northern Spain)

Coastal cliffs provide a high landscape value to many natural sites around the world. This means that an ever-increasing number of people are attracted to them. At this point, there is a growing need to manage these spaces from the safety of visitors, but with a view to preserving the environment. With this aim, this paper presents an approach to analyze and manage instabilities in these environments, particularly those subjected to significant anthropic activity, which has been implemented in the cliffs of the Basque Coast Geopark. The starting point is a detailed topographic information, obtained from UAV flights, and the identification on site of unstable elements, including their typology, active source areas, dynamics and reach. From this information, the simulation of rockfall processes, which basically correspond to toppling and infinite slope instabilities favored by differential erosion along the coastline, is approached in two and three dimensions. Results allow the design of precise actions by sectors, according to the energy, height and reach of the detached blocks, including barriers, middle slope actions, ditches and information strategies, depending on the different uses of the sectors. Therefore, this approach leads to a more detailed and environmentally friendly management of these environments. © 2021This study has been carried out by the UPV/EHU Research GroupIT-1029/16 (Government of the Basque Country) in the framework of the strategic project ?Analysis of instabilities in coastal environments of the Basque Country? PES-18/97 (University of the Basque Country) and the collaboration of the Basque Coast Geopark (Geoparkea). Finally, the authors are grateful to the reviewers and the handling editor, for the valuable comments that highly improved the paper

Effect of forcing vine regrowth on 'Tempranillo' (Vitis vinifera L.) berry development and quality in Extremadura

In warmer regions, fruit ripening in the wine grape tends to take place during the hottest part of the growing season. This can have negative consequences on the qualitative characteristics of the grape berries at harvest. Forcing vines to regrow can be an aggressive but effective technique to delay the harvest date, but needs to be evaluated carefully in each growing condition. In 2017, in an experimental vineyard in Extremadura, forcing was conducted 3 (F1 treatment) and 22 (F2 treatment) days after anthesis (May 18 and June 6) by hedging growing shoots to seven nodes and removing summer laterals, leaves and primary clusters. Vines grown using conventional practices were used for the Control treatment. Forcing delayed the harvest date from August 22 (Control) to September 14 (F1) and October 19 (F2). Shifting the berry growth period modified the duration of the different fruit development stages. Compared to the Control treatment, the F1 and F2 berries were smaller at harvest, but had similar skin weight percentages; however, the seed weight percentage of the F2 berries was higher. The differences in grape composition observed at harvest between the various treatments were further accentuated in the wines. At harvest, the F2 berries had significantly higher total polyphenol and anthocyanin content than the Control and F1 berries, which had similar values. In the wines, both F1 and F2 characteristics differed considerably from the Control, most notably in the high F2 tannin concentration. These preliminary results from the first year of study indicate the potential of this technique to obtain wine grapes with very different characteristics, offering new viticultural perspectives in warm climate areas

Knowledge-based gene expression classification via matrix factorization

Motivation: Modern machine learning methods based on matrix decomposition techniques, like independent component analysis (ICA) or non-negative matrix factorization (NMF), provide new and efficient analysis tools which are currently explored to analyze gene expression profiles. These exploratory feature extraction techniques yield expression modes (ICA) or metagenes (NMF). These extracted features are considered indicative of underlying regulatory processes. They can as well be applied to the classification of gene expression datasets by grouping samples into different categories for diagnostic purposes or group genes into functional categories for further investigation of related metabolic pathways and regulatory networks. Results: In this study we focus on unsupervised matrix factorization techniques and apply ICA and sparse NMF to microarray datasets. The latter monitor the gene expression levels of human peripheral blood cells during differentiation from monocytes to macrophages. We show that these tools are able to identify relevant signatures in the deduced component matrices and extract informative sets of marker genes from these gene expression profiles. The methods rely on the joint discriminative power of a set of marker genes rather than on single marker genes. With these sets of marker genes, corroborated by leave-one-out or random forest cross-validation, the datasets could easily be classified into related diagnostic categories. The latter correspond to either monocytes versus macrophages or healthy vs Niemann Pick C disease patients.Siemens AG, MunichDFG (Graduate College 638)DAAD (PPP Luso - Alem˜a and PPP Hispano - Alemanas

Validation of age determination using otoliths of the European anchovy (Engraulis encrasicolus L.) in the Bay of Biscay

Validation of the age determination procedure using otoliths of European anchovy in the Bay of Biscay was achieved by monitoring very strong year-classes in successive spring catches and surveys, as well as the seasonal occurrence of edge types. Historical corroboration of the ageing method was obtained by cross-correlation between successive age groups by year-classes in catches and surveys (1987–2013). Summary annual growth in length is also presented. Yearly annuli consist of a hyaline zone (either single or composite) and a wide opaque zone, disrupted occasionally by some typical checks (mainly at age-0 and age-1 at peak spawning time). Age determination, given a date of capture, requires knowledge of the typical annual growth pattern of otoliths, their seasonal edge formation by ages and the most typical checks. Most opaque growth occurs in summer and is minimal (translucent) in winter. Opaque zone formation begins earlier in younger fish (in spring), and this helps distinguish age-1 from age-2þ.Versión del edito

Effect of Level of Surface Spoilage on the Nutritive Value of Maize Silage Diets

This study determined the effect of surface spoilage in the diet on feed intake and nutrient digestibilities using growing steers fed whole-plant maize silage-based diets. A bunker silo, 0.9 m in depth, and a 2.7 m diameter AgBag were filled with alternating loads of chopped forage. After 90 days, the bunker was sealed with a sheet of polyethylene, and this silage was designated “spoiled”. The silage in the AgBag was designated “normal”. The four diets contained 90% silage and 10% supplement (dry matter basis), and the proportions of silage in the diets were A) 100% normal, B) 75% normal: 25% spoiled; C) 50% normal: 50% spoiled; and D) 25% normal: 75% spoiled. Feed intake decreased linearly as the proportion of spoiled silage increased from 0 to 75%. Steers consuming the normal silage diet had the highest nutrient digestibilities. Spoiled silage also had negative associative effects on nutrient digestibilities, and the integrity of the forage mat in the rumen was partially destroyed

Effects of irrigation and shoot thinning on the size and phenolics content of developing grape berries (Vitis vinifera L. cv. Tempranillo)

 Aim of study: The concentration of phenolics in the grape berries can be influenced by cultural practices such as irrigation or thinning. The main objective of the present study was to evaluate the effect of combinations of these practices on grape size and phenolics content. Area of study: The trial was carried out in an experimental cv. Tempranillo vineyard located in Extremadura, Spain. Material and methods: Two irrigation regimes were considered: rainfed vines (non-irrigated, NIr), and 100% ETc irrigated vines (Ir). For each irrigation treatment, two cropping levels were studied: low shoot-thinning (LT) vs high shoot-thinning (HT) implemented in winter and spring, respectively. Berry weight, and total phenolics, proanthocyanidin, and anthocyanin concentrations were determined at eight stages of berry development in three consecutive years (2014, 2015, and 2016). Main results: Specific weather conditions of each year affected phenolics accumulation differently. In 2014, where maximum temperatures were low and an important rainfall occurred at Stage II, both the NIr-LT and NIr-HT treatments led to the greatest concentrations of total phenolics, proanthocyanidins, and anthocyanins. In 2015, where a little rainfall was registered at Stage II, the berries from the NIr-HT and Ir-HT treatments accumulated the greatest total phenolics and proanthocyanidin contents, but the NIr-LT and NIr-HT treatments led to the greatest accumulation of anthocyanins. Finally, in 2016, where high maximum temperatures and scarce rainfall were registered, the Ir-LT and Ir-HT treatments presented the greatest concentrations of total phenolics, proanthocyanidins, and anthocyanins. Research highlights: A significant effect of irrigation and thinning was observed on berry size and phenolic content, as well as year × thinning interaction

Reconfiguración de nanopartículas de plata obtenidas por ablación láser en líquido

Estudia la reconfiguración de la nanopartículas de plata coloidal, obtenidos por ablación láser en líquido a diferentes pulsos láser y su caracterización por espectroscopia de absorción UV-Vis y microscopia STEM