Effect of bonding of a CO molecule on the conductance of atomic metal wires

We have measured the effect of bonding of a CO molecule on the conductance of Au, Cu, Pt, and Ni atomic contacts at 4.2 K. When CO gas is admitted to the metal nano contacts, a conductance feature appears in the conductance histogram near 0.5 of the quantum unit of conductance, for all metals. For Au, the intensity of this fractional conductance feature can be tuned with the bias voltage, and it disappears at high bias voltage (above $\sim$ 200 mV). The bonding of CO to Au appears to be weakest, and associated with monotomic Au wire formation.Comment: 6 figure

Averaged cubature schemes on the real positive semiaxis

Stratified cubature rules are proposed to approximate double integrals defined on the real positive semiaxis. In particular, anti-Gauss cubature formulae are introduced and averaged cubature schemes are developed. Some of their appropriate modifications are also studied. Several numerical experiments are given to testify the performance of all the formulae

Absence of magnetically-induced fractional quantization in atomic contacts

Using the mechanically controlled break junction technique at low temperatures and under cryogenic vacuum conditions we have studied atomic contacts of several magnetic (Fe, Co and Ni) and non-magnetic (Pt) metals, which recently were claimed to show fractional conductance quantization. In the case of pure metals we see no quantization of the conductance nor half-quantization, even when high magnetic fields are applied. On the other hand, features in the conductance similar to (fractional) quantization are observed when the contact is exposed to gas molecules. Furthermore, the absence of fractional quantization when the contact is bridged by H_2 indicates the current is never fully polarized for the metals studied here. Our results are in agreement with recent model calculations.Comment: 4 pages, 3 figure

Evidence for a single hydrogen molecule connected by an atomic chain

Stable, single-molecule conducting-bridge configurations are typically identified from peak structures in a conductance histogram. In previous work on Pt with H$_2$ at cryogenic temperatures it has been shown that a peak near 1 $G{_0}$ identifies a single molecule Pt-H$_{2}$-Pt bridge. The histogram shows an additional structure with lower conductance that has not been identified. Here, we show that it is likely due to a hydrogen decorated Pt chain in contact with the H$_2$ molecular bridge.Comment: 4 pages, 4 figure

Vibrationally Induced Two-Level Systems in Single-Molecule Junctions

Single-molecule junctions are found to show anomalous spikes in dI/dV spectra. The position in energy of the spikes are related to local vibration mode energies. A model of vibrationally induced two-level systems reproduces the data very well. This mechanism is expected to be quite general for single-molecule junctions. It acts as an intrinsic amplification mechanism for local vibration mode features and may be exploited as a new spectroscopic tool.Comment: 4 pages, 4 figure

Highly conductive molecular junctions based on direct binding of benzene to platinum electrodes

Highly conductive molecular junctions were formed by direct binding of benzene molecules between two Pt electrodes. Measurements of conductance, isotopic shift in inelastic spectroscopy and shot noise compared with calculations provide indications for a stable molecular junction where the benzene molecule is preserved intact and bonded to the Pt leads via carbon atoms. The junction has a conductance comparable to that for metallic atomic junctions (around 0.1-1 Go), where the conductance and the number of transmission channels are controlled by the molecule's orientation at different inter-electrode distances.Comment: 4 pages, 4 figure

Compressive, tensile and thermal properties of epoxy grouts subjected to underwater conditioning at elevated temperature

Oil and gas pipes are susceptible to failure initiated by corrosion due to their operating pressure under adverse atmospheric conditions. Repairs, comprising a composite shell assembled around the pipe with a small gap, which is then infilled with grout, are considered a suitable option for corroded pipelines. This paper presents the investigation on the mechanical (compression, tension) properties and glass transition temperatures of two infill grouts, after 1000 hour of hot/wet conditioning. An extended investigation on the moisture absorption behaviour was also carried out, revealing the highest absorption to be about 6% after 2520 hours of immersion. The glass transition temperatures of the grouts are reduced by approximately 20ºC. The results suggest that the grouts underwent significant reduction of strength and stiffness due to hot/wet conditioning when tested at an elevated temperature, compared to room temperature. This reduced strength and stiffness is the result of the grouts being tested in close proximity to their glass transition temperatures

Morphological Characteristics of Breast and Thigh Muscles of Autochthonous Breeds of Chickens

Morphological characteristics of skeletal muscles of autochthonous breeds of chickens are very important for meat quality and comparison with current hybrids for intensive production. The autochthonous breeds used in the experiment were Sombor crested and Banat naked neck, both sexes. For the purposes of morphological examination, tissue samples were taken from the thigh muscle (m. biceps femoris) and muscles of the breast (m. pectoralis profundus) of 5 male and female animals of each breed. After a standard histological procedure for conventional light microscopy, samples were stained with hematoxylin - eosin. After the processing of the samples for the histochemical analysis, samples were stained with the enzyme succinate - dehydrogenase (SDH) with the aim of determining the presence of different muscle cell types (red, white and intermediate). Morphological parameters, in this study, were diameter of muscle cells, nucleocytoplasmic ratio of muscle cells, volume density of connective tissue within the muscle and the presence of red, white and intermediate muscle cell types. Comparison of diameters of muscle cells thigh and breast muscles between Sombor crested and Banat naked neck have showed that kind of muscle, race or gender have no significant effect on the differences in this parameter. There were no statistically significant differences in the nucleo-cytoplasmic ratio of the volume density of the connective tissue of muscles. Red muscle cells were, in both autochthonous breeds, significantly more represented in m. biceps femoris than m. pectoralis profundus. The results of this study indicate that no differences were observed between autochthonous breeds in morphological parameters for examined breast and thigh muscle

Effects of Phytogenic Feed Additive and Enzyme on Growth Performance of Broilers Fed Diets with Reduced Energy Concentrations

The effects of dietary supplementation with phytogenic feed additives (PFA) and enzyme (E) on performance parameters were investigated using Ross 308 as hatched broilers fed standard diets or diets with reduced energy concentrations. Birds were assigned to 5 treatments with 5 replications each and fed either a standard basal diet or a re-formulated basal diet with reduced energy concentrations. Reduction was made according to enzyme matrix (Ronozyme WX, DSM). Treatments were: (1) Standard diet; (2) Negative control (NC) – 4% reduction in ME (3) NC + E; (4) NC + PFA (5) NC + E + PFA. Body weight and feed consumption were recorded weekly. Mortality was recorded on daily basis. Foot pad lesions were scored at day 35 using scale from 0 (no lesion) to 2 (lesion extending through skin). The results showed that birds fed Negative control diets had a significantly lower body weights (P0.05). Mortality and FCR did not differ significantly between treatments. Average foot pad lesion score was the highest in Negative control (1.05) and the lowest in NC+E (0.55). In conclusion, re-formulation of diets for 4% energy reduction decreased broiler growth rate. Supplementation of diets with PFA improved live weight especially in combination with enzyme, hence confirming a growth-promoting effect of both phytogenics and enzymes in broilers

Effect of Litter Treatment on the Occurrence of Foot Pad Lesions

Pododermatitis (foot pad lesions) is one of the main welfare problems in modern broiler production in countries with developed poultry farming. Factors contributing to the occurrence of these lesions are nutrition, stocking density and material used for litter. There are a number of different procedures that can be applied in order to prevent and reduce the number of lesions with the most pronounced defects. The experiment was conducted on broiler chickens grown in 10 buildings of 240 m2 each. The stocking density was 35 kg/m2. The experiment was set up in five treatments with two replicates. Treatment one (T1) - control with a straw litter, treatment two (T2) - litter treated with microbial preparation Micropan®, treatment three (T3) – litter with addition of lignin, treatment four (T4) – litter with addition of lignin and Micropan® and treatment five (T5) - chopped straw without supplements. At the end of the experiment, on day 42 the intensity of the lesions was scored on the slaughter line. The presence of lesions was scored using scale from 0 (no lesions) to 3 (plantar pads with more than 50% damage). Based on the results of the trial it can be concluded that litter has a significant impact on the presence and the degree of foot pad lesions. The lowest score of foot pad lesions was observed in the treatment T5 (chopped straw). Different treatments of litters may also contribute to the solution of the problem of pododermatitis since the results in all treated groups (T2, T3, T4 and T5) were better when compared to the control