322 research outputs found

    White dwarf luminosity and mass functions from sloan digital sky survey spectra

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    We present the first phase in our ongoing work to use Sloan Digital Sky Survey (SDSS) data to create separate white dwarf (WD) luminosity functions (LFs) for two or more different mass ranges. In this paper, we determine the completeness of the SDSS spectroscopic WD sample by comparing a proper-motion selected sample of WDs from SDSS imaging data with a large catalog of spectroscopically determined WDs. We derive a selection probability as a function of a single color (g - i) and apparent magnitude (g) that covers the range -1.0 eff≲ 12,000 K and offer arguments that the problem is limited to the line profiles and is not present in the continuum. We offer an empirical method of removing the upturn, recovering a reasonable mass function for WDs with Teff< 12,000 K. Finally, we present a WD LF with nearly an order of magnitude (3358) more spectroscopically confirmed WDs than any previous work.Facultad de Ciencias Astronómicas y GeofísicasInstituto de Astrofísica de La Plat

    The Physics of Crystallization from Globular Cluster White Dwarf Stars in NGC 6397

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    We explore the physics of crystallization in the deep interiors of white dwarf stars using the color-magnitude diagram and luminosity function constructed from proper motion cleaned Hubble Space Telescope photometry of the globular cluster NGC 6397. We demonstrate that the data are consistent with the theory of crystallization of the ions in the interior of white dwarf stars and provide the first empirical evidence that the phase transition is first order: latent heat is released in the process of crystallization as predicted by van Horn (1968). We outline how this data can be used to observationally constrain the value of Gamma = E_{Coulomb}/E_{thermal} near the onset of crystallization, the central carbon/oxygen abundance, and the importance of phase separation.Comment: 5 pages, 5 figures, accepted for publication in the Astrophysical Journal Letter

    New Techniques to Determine Ages of Open Clusters Using White Dwarfs

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    Currently there are two main techniques for independently determining the ages of stellar populations: main sequence evolution theory (via cluster isochrones) and white dwarf cooling theory. Open clusters provide the ideal environment for the calibration of these two clocks. Because current techniques to derive cluster ages from white dwarfs are observationally challenging, we discuss the feasibility of determining white dwarf ages from the brighter white dwarfs alone. This would eliminate the requirement of observing the coolest (i.e., faintest) white dwarfs. We discuss our method for testing this new idea, as well as the required photometric precision and prior constraints on metallicity, distance, and reddening. We employ a new Bayesian statistical technique to obtain and interpret results.Comment: 15 pages, 5 figures. accepted to Astrophysical Journa

    Highly Chemoselective NH- and O-Transfer to Thiols Using Hypervalent Iodine Reagents: Synthesis of Sulfonimidates and Sulfonamides

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    Aryl thiols can be selectively converted to sulfonimidates or sulfonamides with three new S-X connections being made selectively in one pot. Using hypervalent iodine reagents in the presence of ammonium carbamate, NH- and O-groups are transferred under mild and practical conditions. Reducing the loading of ammonium carbamate changed the product distribution, converting the sulfonimidate to the sulfonamide. Studies into the possible intermediate species are presented, suggesting that multiple pathways may be possible via sulfinate esters, or related intermediates, with each species forming the same products

    Pulsation in carbon-atmosphere white dwarfs: A new chapter in white dwarf asteroseismology

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    We present some of the results of a survey aimed at exploring the asteroseismological potential of the newly-discovered carbon-atmosphere white dwarfs. We show that, in certains regions of parameter space, carbon-atmosphere white dwarfs may drive low-order gravity modes. We demonstrate that our theoretical results are consistent with the recent exciting discovery of luminosity variations in SDSS J1426+5752 and some null results obtained by a team of scientists at McDonald Observatory. We also present follow-up photometric observations carried out by ourselves at the Mount Bigelow 1.6-m telescope using the new Mont4K camera. The results of follow-up spectroscopic observations at the MMT are also briefly reported, including the surprising discovery that SDSS J1426+5752 is not only a pulsating star but that it is also a magnetic white dwarf with a surface field near 1.2 MG. The discovery of gg-mode pulsations in SDSS J1426+5752 is quite significant in itself as it opens a fourth asteroseismological "window", after the GW Vir, V777 Her, and ZZ Ceti families, through which one may study white dwarfs.Comment: 7 pages, 4 figures, to appear in Journal of Physics Conference Proceedings for the 16th European White Dwarf Worksho

    A new benchmark T8-9 brown dwarf and a couple of new mid-T dwarfs from the UKIDSS DR5+ LAS

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    Benchmark brown dwarfs are those objects for which fiducial constraints are available, including effective temperature, parallax, age, metallicity. We searched for new cool brown dwarfs in 186 sq.deg. of the new area covered by the data release DR5+ of the UKIDSS Large Area Survey. Follow-up optical and near-infrared broad-band photometry, and methane imaging of four promising candidates, revealed three objects with distinct methane absorption, typical of mid- to late-T dwarfs, and one possibly T4 dwarf. The latest-type object, classified as T8-9, shares its large proper motion with Ross 458 (BD+13o2618), an active M0.5 binary which is 102" away, forming a hierarchical low-mass star+brown dwarf system. Ross 458C has an absolute J-band magnitude of 16.4, and seems overluminous, particularly in the K band, compared to similar field brown dwarfs. We estimate the age of the system to be less than 1 Gyr, and its mass to be as low as 14 Jupiter masses for the age of 1 Gyr. At 11.4 pc, this new late T benchmark dwarf is a promising target to constrain the evolutionary and atmospheric models of very low-mass brown dwarfs. We present proper motion measurements for our targets and for 13 known brown dwarfs. Two brown dwarfs have velocities typical of the thick disk and may be old brown dwarfs.Comment: 15 pages, 10 figures and 6 tables. Accepted by MNRAS. Uses mn2e.cls and aas_macr

    Customer Specific Transaction Risk Management in eCommerce

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    Increasing potential for turnover in e-commerce is inextricably linked with an increase in risk. Online retailers (e-tailers), aiming for a company-wide value orientation should manage this risk. However, current approaches to risk management either use average retail prices elevated by an overall risk premium or restrict the payment methods offered to customers. Thus, they neglect customer-specific value and risk attributes and leave turnover potentials unconsidered. To close this gap, an innovative valuation model is proposed in this contribution that integrates customer-specific risk and potential turnover. The approach presented evaluates different payment methods using their risk-turnover characteristic, provides a risk-adjusted decision basis for selecting payment methods and allows e-tailers to derive automated risk management decisions per customer and transaction without reducing turnover potential
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