262 research outputs found
An experimental study on gold precipitation from leach solutions of technogenic gold-bearing raw materials
This paper presents the results of the study dedicated to the determination of the optimum parameters for the electrolytic gold precipitation from thiourea leach solutions. The leaching was carried out using technogenic gold-bearing raw materials (gold-bearing sands) of the Far East of the Russian Federation. The study focused on the influence of the below parameters of electrolytic precipitation: electrolyte composition, overall cathodic current density, electrode voltage, and structural design of an electrolytic cell. As the results of the experiments, the optimum electrolyte composition and parameters of the current (overall cathodic current density 1000 А/m2, electrode voltage 6 V) were determined. Under these parameters, it is possible to recover up to 93 % of gold from thiourea leach solutions.Keywords: technogenic gold-bearing raw materials, gold, thiourea leaching, electrolyte, cathodic current density, electrolytic cel
Evolution of the Triplet Excited State in PtII Perylenediimides
Here, we present the ultrafast dynamics of a series of metal complexes developed to permit access to the perylenediimide (PDI) triplet manifold that preserves the desirable colorfastness and visible light-absorption properties associated with these dyes. To this end, three PtII complexes each bearing two PDI moieties tethered to the metal center through acetylide linkages emanating from one of the PDI bay positions have been thoroughly examined by static spectroscopic methods, electrochemistry, laser flash photolysis, and ultrafast transient absorption spectrometry. Upon ligation to the PtII center, the bright singlet-state fluorescence (Φ = 0.91, τ = 4.53 ns) of the free PDI?CCH chromophore is quantitatively quenched, and no long wavelength photoluminescence is observed from any of the PtII?PDI complexes in deaerated solutions. Ultrafast transient measurements reveal that upon ligation of PDI?CCH to the PtII center, picosecond intersystem crossing (τ = 2?4 ps) from the 1PDI excited state is followed by vibrational cooling (τ = 12?19 ps) of the hot 3PDI excited state, whereas only singlet-state dynamics, including stimulated emission, were observed in the ?free? PDI?CCH moiety. In each of the Pt?PDI chromophores, quantitatively similar transient absorption difference spectra were obtained; the only distinguishing characteristic is in their single-exponential lifetimes (τ = 246 ns, 1.0 ?s, and 710 ns). These long-lived 3PDI excited states are clearly poised for bimolecular electron and energy transfer schemes. In the present case, the latter is demonstrated through bimolecular sensitization of singlet oxygen phosphorescence at ?1270 nm in aerated dichloromethane solutions, producing reasonable 1O2 quantum yields (Φ? = 0.40?0.55) across this series of molecules
Chronic non-specific back pain: patho-genetic substantiation of manual therapy
We presented the review of data from MEDLINE, EMBASE, CINAHL on the mechanisms of therapeutic activity of manual therapy, as well as on studied tissue and systemic responses, and the elaborations on the issue of manual treatment choice in chronic non-specific back pain.</p
Is the Luttinger liquid a new state of matter?
We are demonstrating that the Luttinger model with short range interaction
can be treated as a type of Fermi liquid. In line with the main dogma of
Landau's theory one can define a fermion excitation renormalized by interaction
and show that in terms of these fermions any excited state of the system is
described by free particles. The fermions are a mixture of renormalized right
and left electrons. The electric charge and chirality of the Landau
quasi-particle is discussed.Comment: paper 10 pages. This version of the paper will be published in
Foundations of Physic
Study of KS KL Coupled Decays and KL -Be Interactions with the CMD-2 Detector at VEPP-2M Collider
The integrated luminosity about 4000 inverse nanobarn of around phi meson
mass ( 5 millions of phi mesons) has been collected with the CMD-2 detector at
the VEPP-2M collider. A latest analysis of the KS KL coupled decays based on 30
% of available data is presented in this paper.
The KS KL pairs from phi meson decays were reconstructed in the drift chamber
when both kaons decayed into two charged particles. From a sample of 1423
coupled decays a selection of candidates to the CP violating KL into pi+ pi-
decay was performed. CP violating decays were not identified because of the
domination of events with a KL regenerating at the Be beam pipe into KS and a
background from KL semileptonic decays.
The regeneration cross section of 110 MeV/c KL mesons was found to be 53 +-
17 mb in agreement with theoretical expectations. The angular distribution of
KS mesons after regeneration and the total cross section of KL for Be have been
measured.Comment: 14 pages, 8 figure
Quasi freestanding graphene on SiC 0001 via cobalt intercalation of zero layer graphene
Modification of the electronic and crystal structure of zero layer graphene grown on 6H SiC 0001 after Co intercalation is reported. Using a wide range of techniques including angle resolved photoelectron spectroscopy, x ray photoelectron spectroscopy, Raman spectroscopy, low energy electron diffraction, we found that zero layer graphene on SiC transforms into graphene monolayer as a result of cobalt intercalation. The Dirac cone of amp; 960; band characteristic of quasi freestanding graphene is observed. In combination with high resolution transmission electron microscopy and atomic force microscopy data, we conclude that ultrathin silicide CoSi CoSi2 structure is formed between graphene and SiC substrate. Investigation of magnetic properties reveals ferromagnetic behavior with open hysteresis loop. The results of this work are the basis for further implementation of magneto spin orbit graphene on a semiconducting substrate and are important for the future application of such graphene in spintronic
Search for lepton-flavor violation at HERA
A search for lepton-flavor-violating interactions and has been performed with the ZEUS detector using the entire HERA I
data sample, corresponding to an integrated luminosity of 130 pb^{-1}. The data
were taken at center-of-mass energies, , of 300 and 318 GeV. No
evidence of lepton-flavor violation was found, and constraints were derived on
leptoquarks (LQs) that could mediate such interactions. For LQ masses below
, limits were set on , where
is the coupling of the LQ to an electron and a
first-generation quark , and is the branching ratio of
the LQ to the final-state lepton ( or ) and a quark . For
LQ masses much larger than , limits were set on the four-fermion
interaction term for LQs that couple to an electron and a quark
and to a lepton and a quark , where and are
quark generation indices. Some of the limits are also applicable to
lepton-flavor-violating processes mediated by squarks in -Parity-violating
supersymmetric models. In some cases, especially when a higher-generation quark
is involved and for the process , the ZEUS limits are the most
stringent to date.Comment: 37 pages, 10 figures, Accepted by EPJC. References and 1 figure (Fig.
6) adde
Multijet production in neutral current deep inelastic scattering at HERA and determination of alpha_s
Multijet production rates in neutral current deep inelastic scattering have
been measured in the range of exchanged boson virtualities 10 < Q2 < 5000 GeV2.
The data were taken at the ep collider HERA with centre-of-mass energy sqrt(s)
= 318 GeV using the ZEUS detector and correspond to an integrated luminosity of
82.2 pb-1. Jets were identified in the Breit frame using the k_T cluster
algorithm in the longitudinally invariant inclusive mode. Measurements of
differential dijet and trijet cross sections are presented as functions of jet
transverse energy E_{T,B}{jet}, pseudorapidity eta_{LAB}{jet} and Q2 with
E_{T,B}{jet} > 5 GeV and -1 < eta_{LAB}{jet} < 2.5. Next-to-leading-order QCD
calculations describe the data well. The value of the strong coupling constant
alpha_s(M_Z), determined from the ratio of the trijet to dijet cross sections,
is alpha_s(M_Z) = 0.1179 pm 0.0013(stat.) {+0.0028}_{-0.0046}(exp.)
{+0.0064}_{-0.0046}(th.)Comment: 22 pages, 5 figure
Photoproduction of mesons associated with a leading neutron
The photoproduction of mesons associated with a leading
neutron has been observed with the ZEUS detector in collisions at HERA
using an integrated luminosity of 80 pb. The neutron carries a large
fraction, {}, of the incoming proton beam energy and is detected at
very small production angles, { mrad}, an indication of
peripheral scattering. The meson is centrally produced with
pseudorapidity {
GeV}, which is large compared to the average transverse momentum of the neutron
of 0.22 GeV. The ratio of neutron-tagged to inclusive production is
in the photon-proton
center-of-mass energy range { GeV}. The data suggest that the
presence of a hard scale enhances the fraction of events with a leading neutron
in the final state.Comment: 28 pages, 4 figures, 2 table
Measurement of beauty production in deep inelastic scattering at HERA
The beauty production cross section for deep inelastic scattering events with
at least one hard jet in the Breit frame together with a muon has been
measured, for photon virtualities Q^2 > 2 GeV^2, with the ZEUS detector at HERA
using integrated luminosity of 72 pb^-1. The total visible cross section is
sigma_b-bbar (ep -> e jet mu X) = 40.9 +- 5.7 (stat.) +6.0 -4.4 (syst.) pb. The
next-to-leading order QCD prediction lies about 2.5 standard deviations below
the data. The differential cross sections are in general consistent with the
NLO QCD predictions; however at low values of Q^2, Bjorken x, and muon
transverse momentum, and high values of jet transverse energy and muon
pseudorapidity, the prediction is about two standard deviations below the data.Comment: 18 pages, 4 figure
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