1,396 research outputs found
Meta-analyses of Post-acquisition Performance: Indications of Unidentified Moderators
Empirical research has not consistently identified antecedents for predicting post-acquisition performance. We employ meta-analytic techniques to empirically assess the impact of the most commonly researched antecedent variables on post-acquisition performance. We find robust results indicating that, on average and across the most commonly studied variables, acquiring firms’ performance does not positively change as a function of their acquisition activity, and is negatively affected to a modest extent. More importantly, our results indicate that unidentified variables may explain significant variance in post-acquisition performance, suggesting the need for additional theory development and changes to M&A research methods
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Understanding solvent spreading for Langmuir deposition of nanomaterial films: a Hansen solubility parameter approach
In order to prepare high-quality Langmuir films of two-dimensional materials it is important to select a solvent optimized for both exfoliation and spreading at the air-water interface. Whilst it is generally accepted that exfoliation and stabilisation of two-dimensional materials is well-described using the Hansen solubility parameter theory, a complementary description of solvent spreading behaviour is lacking.
To this end we develop an understanding of solvent spreading using a Hansen solubility parameter framework. Our model accurately predicts the behaviour of both water-immiscible and water-miscible solvents in Langmuir film formation experiments. We demonstrate that spreading behaviour can be modified by controlling the surface pressure of the subphase using an amphiphilic species and accordingly utilise this approach to determine the maximum spreading pressure for a selection of solvents. Ultimately, by building on this understanding we open up additional routes to optimize the preparation of Langmuir films of two-dimensional materials and other nanoparticles
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Edge selective gas detection using Langmuir films of graphene platelets
Recent advances in large-scale production of graphene have led to the availability of solution processable platelets at the commercial scale. Langmuir-Schaefer (L-S) deposition is a scalable process for forming a percolating film of graphene platelets which can be used for electronic gas sensing. Here, we demonstrate the use of this deposition method to produce functional gas sensors, using a chemiresistor structure from commercially-available graphene dispersions. The sensitivity of the devices and repeatability of the electrical response upon gas exposure has been characterized. Raman spectroscopy and Kelvin probe force microscopy (KPFM) show doping of the basal plane using ammonia (n-dopant) and acetone (p-dopant). The resistive signal is increased upon exposure to both gases showing that sensing originates from the change in contact resistance between nanosheets. We demonstrate that Arrhenius fitting of the desorption response potentially allows measurements of the desorption process activation energies for gas molecules adsorbed onto the graphene nanosheets
The role of science in physical natural hazard assessment : report to the UK Government by the Natural Hazard Working Group
Following the tragic Asian tsunami on 26 December 2004, the Prime Minister asked
the Government’s Chief Scientific Adviser, Sir David King, to convene a group of
experts (the Natural Hazard Working Group) to advise on the mechanisms that could
and should be established for the detection and early warning of global physical
natural hazards.
2. The Group was asked to examine physical hazards which have high global or regional
impact and for which an appropriate early warning system could be put in place. It
was also asked to consider the global natural hazard frameworks currently in place
and under development and their effectiveness in using scientific evidence; to
consider whether there is an existing appropriate international body to pull together
the international science community to advise governments on the systems that need
to be put in place, and to advise on research needed to fill current gaps in knowledge.
The Group was asked to make recommendations on whether a new body was
needed, or whether other arrangements would be more effective
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[Letter] Size selection of liquid-exfoliated 2D nanosheets
Here we present a size selection model for liquid-exfoliated two-dimensional nanosheets. The ability to consistently select exfoliated nanosheets with desired properties is important for development of applications in all areas. The model presented facilitates determination of centrifugation parameters for production of dispersions with controlled size and thickness for different materials, solvents and exfoliation processes. Importantly, after accounting for the influence of viscosity on exfoliation, comparisons of different solvents are shown to be well described by the surface tension and Hansen parameter matching. This suggests that previous analyses may have overestimated the relative performance of more viscous solvents. This understanding can be extended to develop a model based on the force balance of nanosheets falling under viscous drag during centrifugation. By considering the microscopic aspect ratio relationships, this model can be both calibrated for size selection of nanosheets and compare the exfoliation processes themselves
Functional liquid structures by emulsification of graphene and other two-dimensional nanomaterials
Pickering emulsions stabilised with nanomaterials provide routes to a range of functional macroscopic assemblies. We demonstrate the formation and properties of water-in-oil emulsions prepared through liquid-phase exfoliation of graphene. Due to the functional nature of the stabiliser, the emulsions exhibit conductivity due to inter-particle tunnelling. We demonstrate a strain sensing application with a large gauge factor of ~40; the highest reported in a liquid. Our methodology can be applied to other two-dimensional layered materials opening up applications such as energy storage materials, and flexible and printable electronics
‘Off With Their Heads’: British Prime Ministers and the Power to Dismiss
The British prime minister’s power to appoint and dismiss ministers is probably his most important single power. This article explores how prime ministers from Macmillan to Blair have used that power. The article considers the criteria that prime ministers use when choosing to appoint or dismiss individuals from office before examining the calculations and miscalculations that prime ministers have made in practice. Finally, the article analyses the way that prime ministers have exercised, in particular, their power to dismiss and finds that Thatcher was far more likely than others to sack cabinet colleagues on ideological or policy grounds. The article emphasizes that prime ministers’ relationships with especially powerful ministers – ‘big beasts of the jungle’ – are crucial to an understanding of British government at the top.</jats:p
Selective mechanical transfer deposition of Langmuir graphene films for high-performance silver nanowire hybrid electrodes
In this work we present silver nanowire hybrid electrodes, prepared through the addition of small quantities of pristine graphene by mechanical transfer deposition from surface-assembled Langmuir films. This technique is a fast, efficient, and facile method for modifying the opto-electronic performance of AgNW films. We demonstrate that it is possible to use this technique to perform two-step device production by selective patterning of the stamp used, leading to controlled variation in the local sheet resistance across a device. This is particularly attractive for producing extremely low-cost sensors on arbitrarily large scales. Our aim is to address some of the concerns surrounding the use of AgNW films as replacements for indium tin oxide (ITO); namely the use of scarce materials and poor stability of AgNWs against flexural and environmental degradation
On the metallicity dependence of HMXBs
It is commonly assumed that high mass X-ray binary (HMXB) populations are
little-affected by metallicity. However, the massive stars making up their
progenitor systems depend on metallicity in a number of ways, not least through
their winds. We present simulations, well-matched to the observed sample of
Galactic HMXBs, which demonstrate that both the number and the mean period of
HMXB progenitors can vary with metallicity, with the number increasing by about
a factor of three between solar and SMC metallicity. However, the SMC
population itself cannot be explained simply by metallicity effects; it
requires both that the HMXBs observed therein primarily sample the older end of
the HMXB population, and that the star formation rate at the time of their
formation was very large.Comment: 13 pages, 6 figures, MNRAS accepte
Locomotor and technical characteristics of female soccer players training: exploration of differences between competition standards.
OBJECTIVES: To (i) quantify the differences in locomotor and technical characteristics between different drill categories in female soccer and (ii) explore the training drill distributions between different standards of competition. METHODS: Technical (ball touches, ball releases, high-speed ball releases) and locomotor data (total distance, high-speed running distance [>5.29 m∙s-1]) were collected using foot-mounted inertial measurement units from 458 female soccer players from three Women's Super League (WSL; n = 76 players), eight Women's Championship (WC; n = 217) and eight WSL Academy (WSLA; n = 165) teams over a 28-week period. Data were analysed using general linear mixed effects. RESULTS: Across all standards, the largest proportion of time was spent in technical (TEC) (WSL = 38%, WC = 28%, WSLA = 29%) and small-sided extensive games (SSGe) (WSL = 20%, WC = 31%, WSLA = 30%) drills. WSL completed more TEC and tactical (TAC) training whilst WC and WSLA players completed more SSGe and possession (POS) drills. Technical drills elicited the highest number of touches, releases and the highest total distance and high-speed activity. Position-specific drills elicited the lowest number of touches and releases and the lowest total distance. When the technical and locomotor demand of each drill were made relative to time, there were limited differences between drills, suggesting drill duration was the main moderating factor. CONCLUSION: Findings provide novel understanding of the technical and locomotor demands of different drill categories in female soccer. These results can be used by coaches and practitioners to inform training session design
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