Effective coagulation-flocculation treatment of highly polluted palm oil mill biogas plant wastewater using dual coagulants: Decolourisation, kinetics and phytotoxicity studies

The performance of several chemical coagulants including ferric chloride, calcium lactate, magnesium hydroxide, aluminium chlorohydrate, and polydiallyldimethylammonium chloride (polyDADMAC) were investigated in removing colour of palm oil mill biogas plant wastewater (POMBPW). The results show that ferric chloride as a sole coagulant can achieve high colour removal of more than 80% without needed for pH adjustment, which indicates the effectiveness of the coagulant to treat palm oil mill biogas plant wastewater (POMBPW).However, dual coagulants i.e. ferric chloride-anionic polyacrylamide (APAM) shows better performance than ferric chloride-polyDADMAC in terms of colour removal, pH, with shorter sedimentation time. The addition of polymer to system not only reduces the ferric chloride dosage, but also increases the colour removal of more than 20%. Comparison between APAM and polyDADMAC as flocculant aids shows that APAM can achieve stable removal at wider pH range and lowest sedimentation time at 20 min while polyDADMAC was at one hour. Both dual coagulants were followed second order kinetic and APAM shows the highest rate over polyDADMAC i.e. 3 × 10−5/PtCo.min and 2 × 10−5/PtCo.min respectively. Addition of polymers reduced phytotoxicity of generated sludge and the sludge has potential to be reused for land application

Chemical and toxicological assessment of a full-scale biosolid compost

International audienceThe impact of a full-scale biosolid composting plant on the fate of a broad range of priority organic pollutants was investigated. Chemical analysis was performed at different steps of the process during two seasons. Simultaneously, the toxicological quality was assessed using estrogen alpha-, dioxin-, and pregnane X-receptor reporter cell lines. Mass-balance calculation highlighted the removal of easily degradable pollutants during composting. The important variations observed for each compound and for the two seasons might be explained by pollutant-fate dependency on process parameters like temperature. The final compost displayed low pregnane X activity but high estrogenic activity. The dioxin-like activity stayed constant through the process. The chemical and toxicological results highlight the importance of combining both approaches to accurately assess the compost quality. Such compilation of data on full-scale processes may be also very helpful for the environmental risk assessment of new organic waste disposal practices