267 research outputs found
Biogas-to-biomethane upgrading: A comparative review and assessment in a life cycle perspective
The study reviews and compares the most utilised techniques to obtain high quality biomethane by upgrading biogas from anaerobic digestion of the organic fraction of municipal solid waste. Environmental and economic aspects of membrane separation, water scrubbing, chemical absorption with amine solvent, and pressure swing adsorption have been quantified in a life cycle perspective. An attributional environmental Life Cycle Assessment has been implemented with the support of a Material Flow Analysis and in combination with a complementary environmental Life Cycle Costing. The analyses are based on data largely obtained from Italian existing plants but they can be generalised to the whole European Union, as demonstrated by a companion sensitivity analysis. The comparative assessment of the results indicates all the examined options as fully sustainable, also identifying the “win-win” situations. In particular, the membrane separation technique appears to have the best performances, even though in some cases with limited differences. With reference to base case scenarios, this technique shows better results for the respiratory inorganics potential (up to 34%, i.e. up to 328 kgPM2.5eq/y), global warming potential (up to 7%, i.e. up to 344 tCO2eq/y), and non-renewable energy potential (up to 12%, i.e. up to 6400 GJprimary/y) as well as for life cycle costs (up to 3.4%, i.e. about 60 k€/y). The performances of the examined techniques appear anyway dependent on site-specific conditions (such as the injection pressure in the gas grid or the existence/amount of local economic incentives) and commercial strategies for the market of interest
Molecular interactions of carbapenem antibiotics with the multidrug efflux transporter acrb of escherichia coli
The drug/proton antiporter AcrB, engine of the major efflux pump AcrAB(Z)-TolC of Escherichia coli and other bacteria, is characterized by its impressive ability to transport chemically diverse compounds, conferring a multi-drug resistance (MDR) phenotype. Although hundreds of small molecules are known to be AcrB substrates, only a few co-crystal structures are available to date. Computational methods have been therefore intensively employed to provide structural and dynamical fingerprints related to transport and inhibition of AcrB. In this work, we performed a systematic computational investigation to study the interaction between representative carbapenem antibiotics and AcrB. We focused on the interaction of carbapenems with the so-called distal pocket, a region known for its importance in binding inhibitors and substrates of AcrB. Our findings reveal how the different physico-chemical nature of these antibiotics is reflected on their binding preference for AcrB. The molecular-level information provided here could help design new antibiotics less susceptible to the efflux mechanism
Characterisation of the microflora contaminating the wooden vats used for traditional sicilian cheese production
Traditional Sicilian cheese productions are carried out employing traditional wooden vats, called tina. Many studies have highlighted the beneficial role of wooden dairy equipment by contributing to enriching the milk microflora and improving the acidification processes. The present work was undertaken to evaluate the safety of the wooden vats used to coagulate milk. To this purpose, the different microbial populations hosted onto the internal surfaces of the vats used to produce two different stretched cheeses, namely Caciocavallo Palermitano and Vastedda della valle del Bel\uecce DOP, were investigated for the presence of spoilage and pathogenic microorganisms as well as for bacteria with inhibitory effect in vitro against pathogenic microorganisms. A wide biodiversity of protechnological lactic acid bacteria (LAB), in terms of species, was revealed. Several LAB inhibited the growth of Listeria monocytogenes ATCC 7644. The wooden vats analysed resulted safe for three main findings: absence of the main pathogenic species, presence of high levels of LAB, anti-Listeria activity of many LAB
Unveiling the nature of the "Green Pea" galaxies
We review recent results on the oxygen and nitrogen chemical abundances in
extremely compact, low-mass starburst galaxies at redshifts between 0.1-0.3
recently named to as "Green Pea" galaxies. These galaxies are genuine
metal-poor galaxies ( one fifth solar) with N/O ratios unusually high for
galaxies of the same metallicity. In combination with their known general
properties, i.e., size, stellar mass and star-formation rate, these findings
suggest that these objects could be experiencing a short and extreme phase in
their evolution. The possible action of both recent and massive inflow of gas,
as well as stellar feedback mechanisms are discussed here as main drivers of
the starburst activity and their oxygen and nitrogen abundances.Comment: To appear in JENAM Symposium "Dwarf Galaxies: Keys to Galaxy
Formation and Evolution", P. Papaderos, G. Hensler, S. Recchi (eds.). Lisbon,
September 2010, Springer Verlag, in pres
Giant Thermoelectric Effect from Transmission Supernodes
We predict an enormous order-dependent quantum enhancement of thermoelectric
effects in the vicinity of a higher-order `supernode' in the transmission
spectrum of a nanoscale junction. Single-molecule junctions based on
3,3'-biphenyl and polyphenyl ether (PPE) are investigated in detail. The
nonequilibrium thermodynamic efficiency and power output of a thermoelectric
heat engine based on a 1,3-benzene junction are calculated using many-body
theory, and compared to the predictions of the figure-of-merit ZT.Comment: 5 pages, 6 figure
Human Computation and Convergence
Humans are the most effective integrators and producers of information,
directly and through the use of information-processing inventions. As these
inventions become increasingly sophisticated, the substantive role of humans in
processing information will tend toward capabilities that derive from our most
complex cognitive processes, e.g., abstraction, creativity, and applied world
knowledge. Through the advancement of human computation - methods that leverage
the respective strengths of humans and machines in distributed
information-processing systems - formerly discrete processes will combine
synergistically into increasingly integrated and complex information processing
systems. These new, collective systems will exhibit an unprecedented degree of
predictive accuracy in modeling physical and techno-social processes, and may
ultimately coalesce into a single unified predictive organism, with the
capacity to address societies most wicked problems and achieve planetary
homeostasis.Comment: Pre-publication draft of chapter. 24 pages, 3 figures; added
references to page 1 and 3, and corrected typ
Inferring Compton-thick AGN candidates at z>2 with Chandra using the >8 keV restframe spectral curvature
To fully understand cosmic black hole growth we need to constrain the
population of heavily obscured active galactic nuclei (AGN) at the peak of
cosmic black hole growth (1-3). Sources with obscuring column densities
higher than atoms , called Compton-thick
(CT) AGN, can be identified by excess X-ray emission at 20-30 keV, called
the "Compton hump". We apply the recently developed Spectral Curvature (SC)
method to high-redshift AGN (2<z<5) detected with Chandra. This method
parametrizes the characteristic "Compton hump" feature cosmologically
redshifted into the X-ray band at observed energies <10 keV. We find good
agreement in CT AGN found using the SC method and bright sources fit using
their full spectrum with X-ray spectroscopy. In the Chandra deep field south,
we measure a CT fraction of (3/17) for sources with
observed luminosity erg . In the
Cosmological evolution survey (COSMOS), we find an observed CT fraction of
(40/272) or when corrected for
the survey sensitivity. When comparing to low redshift AGN with similar X-ray
luminosities, our results imply the CT AGN fraction is consistent with having
no redshift evolution. Finally, we provide SC equations that can be used to
find high-redshift CT AGN (z>1) for current (XMM-Newton) and future (eROSITA
and ATHENA) X-ray missions.Comment: 10 pages, 8 figure
Identifying Luminous AGN in Deep Surveys: Revised IRAC Selection Criteria
Spitzer IRAC selection is a powerful tool for identifying luminous AGN. For
deep IRAC data, however, the AGN selection wedges currently in use are heavily
contaminated by star-forming galaxies, especially at high redshift. Using the
large samples of luminous AGN and high-redshift star-forming galaxies in
COSMOS, we redefine the AGN selection criteria for use in deep IRAC surveys.
The new IRAC criteria are designed to be both highly complete and reliable, and
incorporate the best aspects of the current AGN selection wedges and of
infrared power-law selection while excluding high redshift star-forming
galaxies selected via the BzK, DRG, LBG, and SMG criteria. At QSO-luminosities
of log L(2-10 keV) (ergs/s) > 44, the new IRAC criteria recover 75% of the hard
X-ray and IRAC-detected XMM-COSMOS sample, yet only 38% of the IRAC AGN
candidates have X-ray counterparts, a fraction that rises to 52% in regions
with Chandra exposures of 50-160 ks. X-ray stacking of the individually X-ray
non-detected AGN candidates leads to a hard X-ray signal indicative of heavily
obscured to mildly Compton-thick obscuration (log N_H (cm^-2) = 23.5 +/- 0.4).
While IRAC selection recovers a substantial fraction of luminous unobscured and
obscured AGN, it is incomplete to low-luminosity and host-dominated AGN.Comment: 22 pages, 15 figures, accepted for publication in ApJ, full
resolution version available at http://www.stsci.edu/~donley/iragn_paper
A population of z> 2 far-infrared Herschel-spire-selected starbursts
We present spectroscopic observations for a sample of 36 Herschel-SPIRE
250-500um selected galaxies (HSGs) at 2<z<5 from the Herschel Multi-tiered
Extragalactic Survey (HerMES). Redshifts are confirmed as part of a large
redshift survey of Herschel-SPIRE-selected sources covering ~0.93deg^2 in six
extragalactic legacy fields. Observations were taken with the Keck I Low
Resolution Imaging Spectrometer (LRIS) and the Keck II DEep Imaging
Multi-Object Spectrograph (DEIMOS). Precise astrometry, needed for
spectroscopic follow-up, is determined by identification of counterparts at
24um or 1.4GHz using a cross-identification likelihood matching method.
Individual source luminosities range from log(L_IR/Lsun)=12.5-13.6
(corresponding to star formation rates 500-9000Msun/yr, assuming a Salpeter
IMF), constituting some of the most intrinsically luminous, distant infrared
galaxies yet discovered. We present both individual and composite rest-frame
ultraviolet spectra and infrared spectral energy distributions (SEDs). The
selection of these HSGs is reproducible and well characterized across large
areas of sky in contrast to most z>2 HyLIRGs in the literature which are
detected serendipitously or via tailored surveys searching only for high-z
HyLIRGs; therefore, we can place lower limits on the contribution of HSGs to
the cosmic star formation rate density at (7+-2)x10^(-3)Msun/yr h^3Mpc^(-3) at
z~2.5, which is >10% of the estimated total star formation rate density (SFRD)
of the Universe from optical surveys. The contribution at z~4 has a lower limit
of 3x10^(-3)Msun/yr h^3 Mpc^(-3), ~>20% of the estimated total SFRD. This
highlights the importance of extremely infrared-luminous galaxies with high
star formation rates to the build-up of stellar mass, even at the earliest
epochs.Comment: 25 pages, 10 figures; ApJ accepte
Evidence for Quantum Interference in SAMs of Arylethynylene Thiolates in Tunneling Junctions with Eutectic Ga-In (EGaIn) Top-Contacts
This paper compares the current density (J) versus applied bias (V) of self-assembled monolayers (SAMs) of three different ethynylthiophenol-functionalized anthracene derivatives of approximately the same thickness with linear-conjugation (AC), cross-conjugation (AQ), and broken-conjugation (AH) using liquid eutectic Ga-In (EGaIn) supporting a native skin (~1 nm thick) of Ga2O3 as a nondamaging, conformal top-contact. This skin imparts non-Newtonian rheological properties that distinguish EGaIn from other top-contacts; however, it may also have limited the maximum values of J observed for AC. The measured values of J for AH and AQ are not significantly different (J ≈ 10-1 A/cm2 at V = 0.4 V). For AC, however, J is 1 (using log averages) or 2 (using Gaussian fits) orders of magnitude higher than for AH and AQ. These values are in good qualitative agreement with gDFTB calculations on single AC, AQ, and AH molecules chemisorbed between Au contacts that predict currents, I, that are 2 orders of magnitude higher for AC than for AH at 0 < |V| < 0.4 V. The calculations predict a higher value of I for AQ than for AH; however, the magnitude is highly dependent on the position of the Fermi energy, which cannot be calculated precisely. In this sense, the theoretical predictions and experimental conclusions agree that linearly conjugated AC is significantly more conductive than either cross-conjugated AQ or broken conjugate AH and that AQ and AH cannot necessarily be easily differentiated from each other. These observations are ascribed to quantum interference effects. The agreement between the theoretical predictions on single molecules and the measurements on SAMs suggest that molecule-molecule interactions do not play a significant role in the transport properties of AC, AQ, and AH.
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