A case study of zeolitization process: 'Tufo Rosso a Scorie Nere' (Vico Volcano, Italy). Inferences for a general model

This paper focuses on the authigenic mineralization processes acting on 'Tufo Rosso a Scorie Nere' (TRS), i.e. one of the main pyroclastic units of the Vico stratovolcano (Latium, Italy). The pyroclastic deposits appear in general massive and made of 'black vitreous vesiculated juvenile scoriae', immersed in an ashy matrix lithified after zeolitization processes. The main minerals are chabazite and phillipsite, and the zeolitic content is locally variable, reaching 68 % wt. Zeolites grow replacing both amorphous fraction and pre-existing phases, occurring inside both matrix and scoriae. Concerning scoriae, zeolitization moves from the rim to the core of the scoriaceous fragment as a function of (a) temperature of the fluids and (b) permeability (primary or secondary). Composition of parental fresh glass and that of zeolitized rocks is compatible with trachyte chemistry, lightly undersaturated in SiO2, and the alteration processes modified the parental rock chemical features. Zeolites genesis is ascribed to a 'geoautoclave-like system', and zeolites display a Si/Al ratio similar to that of the parental glasses. TRS presents promising mineralogical characteristics as supplementary cementitious material in the production of mixed cements

Small launch platforms for micro-satellites

The number of small satellites launched into orbit has enormously increased in the last twenty years. The introduction of new standards of micro-satellites has multiplied the launch demand around the world. Nevertheless, not all the missions can easily have access to space: not all kinds of micro-satellites have granted a deployer system and, furthermore, once a micro-satellite is able to reach it, it cannot usually choose its final orbit. Recently two new platforms have been introduced for the release of micro-satellites as piggy-backs. These platforms are totally operative spacecrafts that act like motherships, and allow to select some parameters of the final orbit of the piggy-backs. They provide a solution for three different nano-satellites standard, and at the same time they are being developed in order to reach more powerful orbital release capabilities in the future. The design and the mission of these platforms are described in this paper

Evidence for the interaction of d-amino acid oxidase with pLG72 in a glial cell line.

Accumulating genetic evidence indicates that the primate-specific gene locus G72/G30 is related to schizophrenia: it encodes for the protein pLG72, whose function is still the subject of controversy. We recently demonstrated that pLG72 negatively affects the activity of human d-amino acid oxidase (hDAAO, also related to schizophrenia susceptibility), which in neurons and (predominantly) in glia is expected to catabolize the neuromodulator d-serine. The d-serine regulation mechanism relying on hDAAO-pLG72 interaction does not match with the subcellular localizations proposed for hDAAO (peroxisomes) and pLG72 (mitochondria). By using glioblastoma U87 cells transfected with plasmids encoding for hDAAO and/or pLG72 we provide convergent lines of evidence that newly synthesized hDAAO, transitorily present in cytosol before being delivered to the peroxisomes, colocalizes and interacts with pLG72 which we propose to be exposed on the external membrane of mitochondria. We also report that newly synthesized cytosolic hDAAO is catalytically active, and therefore pLG72 binding-and ensuing hDAAO inactivation-plays a protective role against d-serine depletion

Growth of Rhodococcus sp. strain BCP1 on gaseous n-alkanes: New metabolic insights and transcriptional analysis of two soluble di-iron monooxygenase genes

Rhodococcus sp. strain BCP1 was initially isolated for its ability to grow on gaseous n-alkanes, which act as inducers for the co-metabolic degradation of low-chlorinated compounds. Here, both molecular and metabolic features of BCP1 cells grown on gaseous and short-chain n-alkanes (up to n-heptane) were examined in detail. We show that propane metabolism generated terminal and sub-terminal oxidation products such as 1- and 2-propanol, whereas 1-butanol was the only terminal oxidation product detected from n-butane metabolism. Two gene clusters, prmABCD and smoABCD-coding for Soluble Di-Iron Monooxgenases (SDIMOs) involved in gaseous n-alkanes oxidation-were detected in the BCP1 genome. By means of Reverse Transcriptase-quantitative PCR (RT-qPCR) analysis, a set of substrates inducing the expression of the sdimo genes in BCP1 were assessed as well as their transcriptional repression in the presence of sugars, organic acids, or during the cell growth on rich medium (Luria-Bertani broth). The transcriptional start sites of both the sdimo gene clusters were identified by means of primer extension experiments. Finally, proteomic studies revealed changes in the protein pattern induced by growth on gaseous- (n-butane) and/or liquid (n-hexane) short-chain n-alkanes as compared to growth on succinate. Among the differently expressed protein spots, two chaperonins and an isocytrate lyase were identified along with oxidoreductases involved in oxidation reactions downstream of the initial monooxygenase reaction step

The role of right and left parietal lobes in the conceptual processing of numbers

Neuropsychological and functional imaging studies have associated the conceptual processing of numbers with bilateral parietal regions (including intraparietal sulcus). However, the processes driving these effects remain unclear because both left and right posterior parietal regions are activated by many other conceptual, perceptual, attention, and response-selection processes. To dissociate parietal activation that is number-selective from parietal activation related to other stimulus or response-selection processes, we used fMRI to compare numbers and object names during exactly the same conceptual and perceptual tasks while factoring out activations correlating with response times. We found that right parietal activation was higher for conceptual decisions on numbers relative to the same tasks on object names, even when response time effects were fully factored out. In contrast, left parietal activation for numbers was equally involved in conceptual processing of object names. We suggest that left parietal activation for numbers reflects a range of processes, including the retrieval of learnt facts that are also involved in conceptual decisions on object names. In contrast, number selectivity in right parietal cortex reflects processes that are more involved in conceptual decisions on numbers than object names. Our results generate a new set of hypotheses that have implications for the design of future behavioral and functional imaging studies of patients with left and right parietal damage

Age does not count: resilience of quantity processing in healthy ageing

Quantity skills have been extensively studied in terms of their development and pathological decline. Recently, numerosity discrimination (i.e., how many items are in a set) has been shown to be resilient to healthy ageing despite relying on inhibitory skills, but whether processing continuous quantities such as time and space is equally well-maintained in ageing participants is not known. Life-long exposure to quantity-related problems may progressively refine proficiency in quantity tasks, or alternatively quantity skills may decline with age. In addition, is not known whether the tight relationship between quantity dimensions typically shown in their interactions is preserved in ageing. To address these questions, two experimental paradigms were used in 38 younger and 32 older healthy adults who showed typical age-related decline in attention, executive function and memory tasks. In both groups we first assessed time and space discrimination independently using a two-choice task (i.e., “Which of two horizontal lines is longer in duration or extension?”), and found that time and space processing were equally accurate in younger and older participants. In a second paradigm, we assessed the relation between different quantity dimensions which were presented as a dynamic pattern of dots independently changing in duration, spatial extension and numerosity. Younger and older participants again showed a similar profile of interaction between number, cumulative area and duration, although older adults showed a greater sensitivity to task-irrelevant information than younger adults in the cumulative area task but lower sensitivity in the duration task. Continuous quantity processing seems therefore resilient to ageing similar to numerosity and to other non-quantity skills like vocabulary or implicit memory; however, ageing might differentially affect different quantity dimensions

3-quasi-Sasakian manifolds

In the present paper we carry on a systematic study of 3-quasi-Sasakian manifolds. In particular we prove that the three Reeb vector fields generate an involutive distribution determining a canonical totally geodesic and Riemannian foliation. Locally, the leaves of this foliation turn out to be Lie groups: either the orthogonal group or an abelian one. We show that 3-quasi-Sasakian manifolds have a well-defined rank, obtaining a rank-based classification. Furthermore, we prove a splitting theorem for these manifolds assuming the integrability of one of the almost product structures. Finally, we show that the vertical distribution is a minimum of the corrected energy.Comment: 17 pages, minor modifications, references update

Aerobic growth of Rhodococcus aetherivorans BCP1 using selected naphthenic acids as the sole carbon and energy sources

Naphthenic acids (NAs) are an important group of toxic organic compounds naturally occurring in hydrocarbon deposits. This work shows that Rhodococcus aetherivorans BCP1 cells not only utilize a mixture of eight different NAs (8XNAs) for growth but they are also capable of marked degradation of two model NAs, cyclohexanecarboxylic acid (CHCA) and cyclopentanecarboxylic acid (CPCA) when supplied at concentrations from 50 to 500 mgL-1. The growth curves of BCP1 on 8XNAs, CHCA, and CPCA showed an initial lag phase not present in growth on glucose, which presumably was related to the toxic effects of NAs on the cell membrane permeability. BCP1 cell adaptation responses that allowed survival on NAs included changes in cell morphology, production of intracellular bodies and changes in fatty acid composition. Transmission electron microscopy (TEM) analysis of BCP1 cells grown on CHCA or CPCA showed a slight reduction in the cell size, the production of EPS-like material and intracellular electron-transparent and electron-dense inclusion bodies. The electron-transparent inclusions increased in the amount and size in NA-grown BCP1 cells under nitrogen limiting conditions and contained storage lipids as suggested by cell staining with the lipophilic Nile Blue A dye. Lipidomic analyses revealed significant changes with increases of methyl-branched (MBFA) and polyunsaturated fatty acids (PUFA) examining the fatty acid composition of NAs-growing BCP1 cells. PUFA biosynthesis is not usual in bacteria and, together with MBFA, can influence structural and functional processes with resulting effects on cell vitality. Finally, through the use of RT (Reverse Transcription)-qPCR, a gene cluster (chcpca) was found to be transcriptionally induced during the growth on CHCA and CPCA. Based on the expression and bioinformatics results, the predicted products of the chcpca gene cluster are proposed to be involved in aerobic NA degradation in R. aetherivorans BCP1. This study provides first insights into the genetic and metabolic mechanisms allowing a Rhodococcus strain to aerobically degrade NAs

The anomalous warming of summer 2003 in the surface layer of the Central Ligurian Sea (Western Mediterranean)

"Meteorological and sea temperature data from the ODAS Italia 1 buoy (Ligurian Sea, Western Mediterranean) are used to study the anomalous warming of summer 2003 at sea. The event was related to the record heat wave that interested much of Europe from June to September of that year. The data show that the anomalous warming was prevalently confined to within a few meters below the sea surface. On the contrary, the temperatures in the underlying layers were lower than usual. The limited vertical propagation of heat is ascribed to the high temperature difference that arose between the surface and the deeper layers due to protracted calm weather conditions. The degree of penetration of heat deduced from the observations is consistent with that computed on the basis of an energetic argument, wherein the wind constitutes the sole supply of kinetic energy, while the heating is viewed as the source of potential energy that must be ""subtracted"" by mixing. The results support the hypothesis that the scanty energy from the wind is mainly responsible for the development of the temperature anomaly at the sea surface.

Boosting Productivity of Laser Powder Bed Fusion for AlSi10Mg

The Laser Powder Bed Fusion (L-PBF) process is recognized for high-end industrial applications due to its ability to produce parts with high geometric complexity. If lightweighting is one of the main strengths of L-PBF, a weakness is still the trade-off between high mechanical properties and competitive productivity. This objective can be targeted through a fine tuning of the process parameters within the manufacturing window. The paper pursues the combined optimization of part quality and process productivity for AlSi10Mg by going beyond the commonly used approach based solely on volumetric energy density. The effects of hatch distance and scan speed on the two targets were analyzed in detail. The best results were achieved by the adoption of a high scan speed and a low hatch distance, with notably different outcomes for nearly the same energy density