Effect of testing conditions on the photovoltaic performance of ZnO-based dye sensitized solar cells

Dye-sensitized solar cells based on vertically-aligned ZnO nanorod, were analyzed at different conditions. Stability tests showed an improvement on solar conversion efficiency between ∼20% (1000 W/m) and ∼50% (1800 W/m). This behavior was ascribed to the physisorption/ chemisorption of the N-719 dye on the ZnO due to UV light. Studies at different temperatures proved that the performance of the cells can double when decreasing temperature from 72°C to room temperature. An increase on the efficiency and decrease in FF was observed when light intensity is increased. IPCE analyses were used to monitor the stability of the solar cells with time

Toothpick Mania

This sculpture was created as part of the Linfield College course Introduction to Studio, taught by Totem Shriver.https://digitalcommons.linfield.edu/avcstud_toothpick/1043/thumbnail.jp

A wearable electrochemical sensing system for non-invasive monitoring of lithium drug in bipolar disorder

Lithium represents the main drug for the treatment of Bipolar Disorder (BD) as it acts as a mood stabilizer. However, because of its narrow therapeutic window, psychiatric patients are obliged to frequent tests in hospital to control their lithium blood concentration during therapy. In this paper, we fabricate for the first time a complete non-invasive system for the Therapeutic Drug Monitoring (TDM) of lithium in sweat in people suffering from BD. The wearable electrochemical sensing platform includes a paper fluidics and a stable Reference Electrode (RE). Lithium detection is based on the use of a potentiometric Ion-Selective Electrode (ISE) with a nanostructured solid contact in order to increase the potential stability of the sensor. A chemical chlorination combined with the use of a PVC membrane doped with an Ionic Liquid (IL) is used to minimize possible potential drifts of the RE. The Nernstian response (56.8±3.9 mV /decade) of the system in the range of clinical interest is then proved in aqueous solution and in sweat. The integration of the sensing platform with a paper fluidics transporting fresh sweat sample to the sensing area is also considered. The already tested sweat is collected in a reservoir made of slow adsorbing paper. The complete wearable system is then successfully tested in a simulated setup by using a mannequin. The measured potential is well compared to the predicted ones in the therapeutic window of lithium drug, proving the good sensing capability in artificial sweat

Genomic structural variation in Nebbiolo grapevines at the individual, clonal and cultivar levels

Background: ‘Nebbiolo’ is a grapevine cultivar typical of north-western Italy, appreciated for producing high-quality red wines. Grapevine cultivars are characterized by possessing highly heterozygous genomes, including a great incidence of genomic rearrangements larger than 50 bp, so called structural variations (SVs). Even though abundant, SVs are an under-explored source of genetic variation mainly due to methodological limitations at their detection. Results: We employed a multiple platform approach to produce long-range genomic data for two diferent ‘Nebbiolo’ clones, namely: optical mapping, long-reads and linked-reads. We performed a haplotype-resolved de novo assembly for cultivar ‘Nebbiolo’ (clone CVT 71) and used an ab-initio strategy to annotate it. The annotated assembly enhanced our ability to detect SVs, enabling the study of genomic regions not present in the grapevines’ reference genome and accounting for their functional implications. We performed variant calling analyses at three diferent organizational levels: i) between haplotypes of clone CVT 71 (primary assembly vs haplotigs), ii) between ‘Nebbiolo’ and ‘Cabernet Sauvignon’ assemblies and iii) between clones CVT 71 and CVT 185, representing diferent ‘Nebbiolo’ biotypes. The cumulative size of non-redundant merged SVs indicated a total of 79.6 Mbp for the frst comparison and 136.1 Mbp for the second one, while no SVs were detected for the third comparison. Interestingly, SVs diferentiating cultivars and haplotypes afected similar numbers of coding genes. Conclusions: Our results suggest that SVs accumulation rate and their functional implications in ‘Nebbiolo’ genome are highly-dependent on the organizational level under study. SVs are abundant when comparing ‘Nebbiolo’ to a diferent cultivar or the two haplotypes of the same individual, while they turned absent between the two analyse

‘Nebbiolo’ genome assembly allows surveying the occurrence and functional implications of genomic structural variations in grapevines (Vitis vinifera L.)

Background: ‘Nebbiolo’ is a grapevine cultivar typical of north-western Italy, appreciated for producing high-quality red wines. Grapevine cultivars are characterized by possessing highly heterozygous genomes, including a great incidence of genomic rearrangements larger than 50 bp, so called structural variations (SVs). Even though abundant, SVs are an under-explored source of genetic variation mainly due to methodological limitations at their detection. Results: We employed a multiple platform approach to produce long-range genomic data for two different ‘Nebbiolo’ clones, namely: optical mapping, long-reads and linked-reads. We performed a haplotype-resolved de novo assembly for cultivar ‘Nebbiolo’ (clone CVT 71) and used an ab-initio strategy to annotate it. The annotated assembly enhanced our ability to detect SVs, enabling the study of genomic regions not present in the grapevines’ reference genome and accounting for their functional implications. We performed variant calling analyses at three different organizational levels: i) between haplotypes of clone CVT 71 (primary assembly vs haplotigs), ii) between ‘Nebbiolo’ and ‘Cabernet Sauvignon’ assemblies and iii) between clones CVT 71 and CVT 185, representing different ‘Nebbiolo’ biotypes. The cumulative size of non-redundant merged SVs indicated a total of 79.6 Mbp for the first comparison and 136.1 Mbp for the second one, while no SVs were detected for the third comparison. Interestingly, SVs differentiating cultivars and haplotypes affected similar numbers of coding genes. Conclusions: Our results suggest that SVs accumulation rate and their functional implications in ‘Nebbiolo’ genome are highly-dependent on the organizational level under study. SVs are abundant when comparing ‘Nebbiolo’ to a different cultivar or the two haplotypes of the same individual, while they turned absent between the two analysed clones.Fil: Maestri, Simone. Universita di Verona; ItaliaFil: Gambino, Giorgio. Centre National de la Recherche Scientifique; FranciaFil: Lopatriello, Giulia. Universita di Verona; ItaliaFil: Minio, Andrea. University of California at Davis; Estados UnidosFil: Perrone, Irene. Centre National de la Recherche Scientifique; FranciaFil: Cosentino, Emanuela. Universita di Verona; ItaliaFil: Giovannone, Barbara. Universita di Verona; ItaliaFil: Marcolungo, Luca. Universita di Verona; ItaliaFil: Alfano, Massimiliano. Universita di Verona; ItaliaFil: Rombauts, Stephane. University of Ghent; BélgicaFil: Cantu, Dario. University of California at Davis; Estados UnidosFil: Rossato, Marzia. Universita di Verona; ItaliaFil: Delledonne, Massimo. Universita di Verona; ItaliaFil: Calderón, Pablo Luciano Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto de Biología Agrícola de Mendoza. Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias. Instituto de Biología Agrícola de Mendoza; Argentin

Worldwide outdoor round robin study of organic photovoltaic devices and modules

Accurate characterization and reporting of organic photovoltaic (OPV) device performance remains one of the important challenges in the field. The large spread among the efficiencies of devices with the same structure reported by different groups is significantly caused by different procedures and equipment used during testing. The presented article addresses this issue by offering a new method of device testing using suitcase sample approach combined with outdoor testing that limits the diversity of the equipment, and a strict measurement protocol. A round robin outdoor characterization of roll-to-roll coated OPV cells and modules conducted among 46 laboratories worldwide is presented, where the samples and the testing equipment were integrated in a compact suitcase that served both as a sample transportation tool and as a holder and test equipment during testing. In addition, an internet based coordination was used via plasticphotovoltaics.org that allowed fast and efficient communication among participants and provided a controlled reporting format for the results that eased the analysis of the data. The reported deviations among the laboratories were limited to 5% when compared to the Si reference device integrated in the suitcase and were up to 8% when calculated using the local irradiance data. Therefore, this method offers a fast, cheap and efficient tool for sample sharing and testing that allows conducting outdoor measurements of OPV devices in a reproducible manner