Urban PDS Partnership: Preparing Teachers for Social Justice

We believe that for urban schools to meet their goals and mission — in the way the DECA is modeling — takes a partnership among many stakeholders. One such partnership that supports DECA, and might buttress other schools and students — and simultaneously help to enact a social justice ideal — is a school-university connection. DECA was founded as a Professional Development School (PDS), with the school and university developing a reciprocal relationship with a shared focus on the preparation of new teachers, the enhancement of high school students\u27 achievement, school and university faculty members\u27 professional development, and collaborative inquiries aimed at improving instructional practices for all of the educators involved. In this chapter, we will describe our Midwestern university\u27s response to two social justice issues: the lack of support for urban students to be ready for college; and the issue of teacher quality in urban schools. DECA explicitly endeavors to respond to the dearth of educational opportunities for city youth. As well, as a PDS, DECA serves the university and our profession as a site for preparing the next generation of urban teachers. Our partnership relies on a PDS framework and a social justice approach to impact students\u27 access to learning and to develop quality educators through learning communities. Using the lenses of the Marianist Catholic tradition and the PDS mission, here we will frame our social justice stance. We will specifically describe the revamping of two critical courses in the teacher education program with the goal of enacting social justice through developing effective teachers for urban settings

Scanning Electrochemical Cell Microscopy (SECCM) in aprotic solvents : practical considerations and applications

Many applications in modern electrochemistry, notably electrosynthesis and energy storage/conversion take advantage of the “tunable” physicochemical properties (e.g., proton availability and/or electrochemical stability) of non-aqueous (e.g., aprotic) electrolyte media. This work develops general guidelines pertaining to the use of scanning electrochemical cell microscopy (SECCM) in aprotic solvent electrolyte media to address contemporary structure−electrochemical activity problems. Using the simple outer-sphere Fc0/+ process (Fc = ferrocene) as a model system, high boiling point (low vapor pressure) solvents give rise to highly robust and reproducible electrochemistry, whereas volatile (low boiling point) solvents need to be mixed with suitable low melting point supporting electrolytes (e.g., ionic liquids) or high boiling point solvents to avoid complications associated with salt precipitation/crystallization on the scanning (minutes to hours) timescale. When applied to perform microfabrication — specifically the electrosynthesis of the conductive polymer, polypyrrole — the optimized SECCM set up produces highly reproducible arrays of synthesized (electrodeposited) material on a commensurate scale to the employed pipet probe. Applying SECCM to map electrocatalytic activity — specifically the electro-oxidation of iodide at polycrystalline platinum — reveals unique (i.e., structure-dependent) patterns of surface activity, with grains of specific crystallographic orientation, grain boundaries and areas of high local surface misorientation identified as potential electrocatalytic “hot spots”. The work herein further cements SECCM as a premier technique for structure−function−activity studies in (electro)materials science and will open up exciting new possibilities through the use of aprotic solvents for rational analysis/design in electrosynthesis, microfabrication, electrochemical energy storage/conversion and beyond

WASP-26b : a 1-Jupiter-mass planet around an early-G-type star

We report the discovery of WASP-26b, a moderately over-sized Jupiter-mass exoplanet transiting its 11.3-mag early-G-type host star (1SWASP J001824.70-151602.3; TYC 5839-876-1) every 2.7566 days. A simultaneous fit to transit photometry and radial-velocity measurements yields a planetary mass of 1.02 ± 0.03 MJup and radius of 1.32 ± 0.08 RJup. The host star, WASP-26, has a mass of 1.12 ± 0.03 M and a radius of 1.34 ± 0.06 R and is in a visual double with a fainter K-type star. The two stars are at least a common-proper motion pair with a common distance of around 250 ± 15 pc and an age of 6 ± 2 Gy

Multiscale analysis of electrocatalytic particle activities : linking nanoscale measurements and ensemble behavior

Nanostructured electrocatalysts exhibit variations in electrochemical properties across different length scales, and the intrinsic catalytic characteristics measured at the nanoscale often differ from those at the macro-level due to complexity in electrode structure and/or composition. This aspect of electrocatalysis is addressed herein, where the oxygen evolution reaction (OER) activity of β-Co­(OH)2 platelet particles of well-defined structure is investigated in alkaline media using multiscale scanning electrochemical cell microscopy (SECCM). Microscale SECCM probes of ∼50 μm diameter provide voltammograms from small particle ensembles (ca. 40–250 particles) and reveal increasing dispersion in the OER rates for samples of the same size as the particle population within the sample decreases. This suggests the underlying significance of heterogeneous activity at the single-particle level that is confirmed through single-particle measurements with SECCM probes of ∼5 μm diameter. These measurements of multiple individual particles directly reveal significant variability in the OER activity at the single-particle level that do not simply correlate with the particle size, basal plane roughness, or exposed edge plane area. In combination, these measurements demarcate a transition from an “individual particle” to an “ensemble average” response at a population size of ca. 130 particles, above which the OER current density closely reflects that measured in bulk at conventional macroscopic particle-modified electrodes. Nanoscale SECCM probes (ca. 120 and 440 nm in diameter) enable measurements at the subparticle level, revealing that there is selective OER activity at the edges of particles and highlighting the importance of the three-phase boundary where the catalyst, electrolyte, and supporting carbon electrode meet, for efficient electrocatalysis. Furthermore, subparticle measurements unveil heterogeneity in the OER activity among particles that appear superficially similar, attributable to differences in defect density within the individual particles, as well as to variations in electrical and physical contact with the support material. Overall this study provides a roadmap for the multiscale analysis of nanostructured electrocatalysts, directly demonstrating the importance of multilength scale factors, including particle structure, particle–support interaction, presence of defects, etc., in governing the electrochemical activities of β-Co­(OH)2 platelet particles and ultimately guiding the rational design and optimization of these materials for alkaline water electrolysis

Screening the surface structure-dependent action of a benzotriazole derivative on copper electrochemistry in a triple-phase nanoscale environment

Copper (Cu) corrosion is a compelling problem in the automotive sector and in oil refinery and transport, where it is mainly caused by the action of acidic aqueous droplets dispersed in an oil phase. Corrosion inhibitors, such as benzotriazole (BTAH) and its derivatives, are widely used to limit such corrosion processes. The efficacy of corrosion inhibitors is expected to be dependent on the surface crystallography of metals exposed to the corrosion environment. Yet, studies of the effect of additives at the local level of the surface crystallographic structure of polycrystalline metals are challenging, particularly lacking for the triple-phase corrosion problem (metal/aqueous/oil). To address this issue, scanning electrochemical cell microscopy (SECCM), is used in an acidic nanodroplet meniscus|oil layer|polycrystalline Cu configuration to explore the grain-dependent influence of an oil soluble BTAH derivative (BTA-R) on Cu electrochemistry within the confines of a local aqueous nanoprobe. Electrochemical maps, collected in the voltammetric mode at an array of >1000 points across the Cu surface, reveal both cathodic (mainly the oxygen reduction reaction) and anodic (Cu electrooxidation) processes, of relevance to corrosion, as a function of the local crystallographic structure, deduced with co-located electron backscatter diffraction (EBSD). BTA-R is active on the whole spectrum of crystallographic orientations analyzed, but there is a complex grain-dependent action, distinct for oxygen reduction and Cu oxidation. The methodology pinpoints the surface structural motifs that facilitate corrosion-related processes and where BTA-R works most efficiently. Combined SECCM–EBSD provides a detailed screen of a spectrum of surface sites, and the results should inform future modeling studies, ultimately contributing to a better inhibitor design

Nanoscale visualization and multiscale electrochemical analysis of conductive polymer electrodes

Conductive polymers are exceptionally promising for modular electrochemical applications including chemical sensors, bioelectronics, redox-flow batteries, and photo-electrochemical systems due to considerable synthetic tunability and ease of processing. Despite well-established structural heterogeneity in these systems, conventional macroscopic electroanalytical methods – specifically cyclic voltammetry – are typically used as the primary tool for structure-property elucidation. This work presents an alternative correlative multi-microscopy strategy; data from laboratory and synchrotron-based micro-spectroscopies, including conducting-atomic force microscopy and synchrotron nanoscale infrared spectroscopy, is combined with potentiodynamic movies of electrochemical fluxes from scanning electrochemical cell microscopy (SECCM) to reveal the relationship between electrode structure and activity. A model conductive polymer electrode system of tailored heterogeneity is investigated, consisting of phase-segregated domains of poly(3-hexylthiophene) (P3HT) surrounded by contiguous regions of insulating poly(methyl methacrylate) (PMMA), representing an ultramicroelectrode array. Isolated domains of P3HT are shown to retain bulk-like chemical and electronic structure when blended with PMMA, and possess approximately equivalent electron-transfer rate constants compared to pure P3HT electrodes. The nanoscale electrochemical data are used to model and predict multiscale electrochemical behavior, revealing that macroscopic cyclic voltammograms should be much more kinetically facile than observed experimentally. This indicates that parasitic resistances rather than redox kinetics play a dominant role in macroscopic measurements in these conducting polymer systems. SECCM further demonstrates that the ambient degradation of the P3HT electroactivity within P3HT/PMMA blends is spatially heterogeneous. This work serves as a roadmap for benchmarking the quality of conductive polymer films as electrodes, emphasizing the importance of nanoscale electrochemical measurements in understanding macroscopic properties

Discovery and characterization of WASP-6b, an inflated sub-Jupiter mass planet transiting a solar-type star

We report the discovery of WASP-6b, an inflated sub-Jupiter mass planet transiting every 3.3610060^{\rm + 0.0000022 }_ days a mildly metal-poor solar-type star of magnitude V = 11.9. A combined analysis of the WASP photometry, high-precision followup transit photometry and radial velocities yield a planetary mass M_{\rm p} = 0.503^_ $M_{\rm J}$ and radius R_{\rm p} = 1.224^_ $R_{\rm J}$, resulting in a density $\rho_{\rm p} = 0.27 \pm 0.05$ $\rho_{\rm J}$. The mass and radius for the host star are M_\ast = 0.88^_ $M_\odot$ and R_\ast = 0.870^_ $R_\odot$. The non-zero orbital eccentricity e = 0.054^{\rm +0.018}_ that we measure suggests that the planet underwent a massive tidal heating ~1 Gyr ago that could have contributed to its inflated radius. High-precision radial velocities obtained during a transit allow us to measure a sky-projected angle between the stellar spin and orbital axis \beta = 11^_ deg. In addition to similar published measurements, this result favors a dominant migration mechanism based on tidal interactions with a protoplanetary disk

New rotation periods in the Pleiades: Interpreting activity indicators

We present results of photometric monitoring campaigns of G, K and M dwarfs in the Pleiades carried out in 1994, 1995 and 1996. We have determined rotation periods for 18 stars in this cluster. In this paper, we examine the validity of using observables such as X-ray activity and amplitude of photometric variations as indicators of angular momentum loss. We report the discovery of cool, slow rotators with high amplitudes of variation. This contradicts previous conclusions about the use of amplitudes as an alternate diagnostic of the saturation of angular momentum loss. We show that the X-ray data can be used as observational indicators of mass-dependent saturation in the angular momentum loss proposed on theoretical grounds.Comment: 24 pages, LaTex (AASTeX); includes 8 postscript figures and 4 Latex tables. To appear in ApJ, Feb. 1, 1998. Postscript version of preprint can be obtained from http://casa.colorado.edu/~anitak/pubs.htm

The EBLM Project I-Physical and orbital parameters, including spin-orbit angles, of two low-mass eclipsing binaries on opposite sides of the Brown Dwarf limit

This paper introduces a series of papers aiming to study the dozens of low mass eclipsing binaries (EBLM), with F, G, K primaries, that have been discovered in the course of the WASP survey. Our objects are mostly single-line binaries whose eclipses have been detected by WASP and were initially followed up as potential planetary transit candidates. These have bright primaries, which facilitates spectroscopic observations during transit and allows the study of the spin-orbit distribution of F, G, K+M eclipsing binaries through the Rossiter-McLaughlin effect. Here we report on the spin-orbit angle of WASP-30b, a transiting brown dwarf, and improve its orbital parameters. We also present the mass, radius, spin-orbit angle and orbital parameters of a new eclipsing binary, J1219-39b (1SWAPJ121921.03-395125.6, TYC 7760-484-1), which, with a mass of 95 +/- 2 Mjup, is close to the limit between brown dwarfs and stars. We find that both objects orbit in planes that appear aligned with their primaries' equatorial planes. Neither primaries are synchronous. J1219-39b has a modestly eccentric orbit and is in agreement with the theoretical mass--radius relationship, whereas WASP-30b lies above it.Comment: 12 pages, 7 figures, data in appendices, submitted to A&A (taking in account 1st referee report