An Optical Sprayer Nozzle Flow Rate Sensor

Ensuring proper flow rates from each nozzle on an agricultural sprayer has become even more important as advances continue to be made in precision application technology. In this article, we describe the structure and testing of a sensor technology based on optical cross-correlation to determine the flow rate of individual sprayer nozzles. An advantage of this technology is that it does not require that impellers or other components be placed in the flow, which could cause plugging. The only moving part in the entire system is a solenoid used to inject a tracer dye. The objective of this study was to evaluate the ability of this sensor technology to determine volumetric flow rate from a single nozzle as used on an agricultural sprayer system. Tests were conducted at four system pressures (100, 200, 300, and 400 kPa) and with four nozzles in the 80° extended-range flat spray nozzle family to produce different flow rates (from 0.46 to 2.74 L min-1). Thirty-five samples were taken for each test condition. Five randomly selected samples were used to create a calibration curve for the sensor system, and the remaining 30 samples were used for validation of performance. The worst absolute error for flow rate estimation in percent was 7.9%, while the mean absolute error in percent was 1.6% for all measurements. While the flow rate estimates for the XRC8006 nozzle at 100 kPa exhibited bias in the errors, for the rest of the test conditions, the errors were clustered around zero. The overall mean absolute error of 1.6% indicates the capability of this sensor technology to monitor flow rate of individual nozzles. However, the bias in errors in one test condition demonstrate that more testing needs to be conducted with a variety of different nozzle types and sprayer configurations before this sensor technology can be considered applicable for all sprayer applications

An analysis of the foot in turnout using a dance specific 3D multi-segment foot model

Introduction: Recent three-dimensional (3D) kinematic research has revealed foot abduction is the strongest predictor of standing functional and forced turnout postures. However, it is still unknown how the internal foot joints enable a large degree of foot abduction in turnout. The primary purpose of this study was to use a dance specific multi-segment foot model to determine the lower leg and foot contributions to turnout that female university-level ballets use to accentuate their turnout. Methods: Eighteen female dance students (mean age, 18.8 ± 1.6 years) volunteered for this study. Retro-reflective markers were attached to the dancers\u27 dominant foot. Each dancer performed three repetitions of functional turnout, forced turnout and ten consecutive sautés in first position. Repeated measures ANOVA with Bonferroni adjustments for the multiple comparisons were used to determine the kinematic adjustments, hindfoot eversion, midfoot and forefoot abduction, navicular drop (i.e. lowering of the medial longitudinal arch) and first metatarsophalangeal joint abduction between natural double leg up-right posture and the first position conditions. Results: Hindfoot eversion (4.6°, p \u3c 0.001) and midfoot abduction (2.8°, p \u3c 0.001) significantly increased in functional turnout compared to the natural double leg up-right posture. Thirteen dancers demonstrated increased first metatarsophalangeal joint (MTPJ) abduction in forced turnout, however no statistically significant increase was found. Navicular drop during sautés in first position significantly increased by 11 mm (p \u3c 0.001) compared to the natural double leg up-right posture. Conclusion: Our findings suggest dancers do pronate, via hindfoot eversion and midfoot abduction in both functional and forced turnout, however, no immediate association was found between forced turnout and first MTPJ abduction. Foot pronation does play a role in achieving turnout. Further prospective research on in situ measures of the lower limb in turnout and injury surveillance is required to improve our understanding of the normal and abnormal dance biomechanics. © 2019 The Author(s)

Islands of isolation in a modern metropolis: Social structures and the geography of social exclusion in Toronto, Ontario, Canada

In response to a request from a local community health centre, an inquiry was undertaken into the service needs and day-to-day lives of residents in five social housing complexes in the inner suburbs of Etobicoke, Toronto. Unlike other low-income communities embedded within larger wealthier communities, these complexes have little in the way of health care, social service, or recreational facilities. Focus groups revealed that anticipated issues of difficulty in accessing primary health care services, limited access to support services, and lack of recreational opportunities for youth were intensified by gentrification of neighbourhoods, ongoing experiences of racism and discrimination, a dearth of occupational opportunities for youth and political invisibility of these residents. These experiences of social exclusion are especially troubling when contrasted with the opportunities for health and well-being offered to many others in one of Canada’s wealthiest urban communities.En réponse à une demande d’un centre de santé communautaire local, une enquête a été entreprise sur les besoins en services et la vie quotidienne de résidents de cinq complexes de logements sociaux dans la banlieue intérieure d’Etobicoke, à Toronto. Contrairement à d’autres communautés à faible revenu intégrées dans des communautés plus grandes et plus riches, ces complexes ont peu de soins de santé, services sociaux ou d’installations récréatives. Les groupes de discussion ont révélés que les problèmes anticipés de difficultés d’accès aux services de soin de santé primaires, d’accès limité aux services de soutien et de manque d’opportunités récréatives pour les jeunes étaient intensifiés par l’embourgeoisement des quartiers, les expériences continues de racisme et de discriminations, le maque d’opportunités professionnelles pour les jeunes et l’invisibilité politique de ces résidents. Ces expériences d’exclusion sociale sont particulièrement troublantes lorsqu’elles sont mises en contraste avec les opportunités de santés et de bien-être offertes à beaucoup d’autres dans l’une des communautés urbaines les plus riches au Canada

Towards Water Soluble Mitochondria-Targeting Theranostic Osmium(II) Triazole-Based Complexes

The complex [Os(btzpy)2][PF6]2 (1, btzpy = 2,6-bis(1-phenyl-1,2,3-triazol-4-yl)pyridine) has been prepared and characterised. Complex 1 exhibits phosphorescence (λem = 595 nm, τ = 937 ns, φem = 9.3% in degassed acetonitrile) in contrast to its known ruthenium(II) analogue, which is non-emissive at room temperature. The complex undergoes significant oxygen-dependent quenching of emission with a 43-fold reduction in luminescence intensity between degassed and aerated acetonitrile solutions, indicating its potential to act as a singlet oxygen sensitiser. Complex 1 underwent counterion metathesis to yield [Os(btzpy)2]Cl2 (1 Cl), which shows near identical optical absorption and emission spectra to those of 1. Direct measurement of the yield of singlet oxygen sensitised by 1 Cl was carried out (φ ( 1O2) = 57%) for air equilibrated acetonitrile solutions. On the basis of these photophysical properties, preliminary cellular uptake and luminescence microscopy imaging studies were conducted. Complex 1 Cl readily entered the cancer cell lines HeLa and U2OS with mitochondrial staining seen and intense emission allowing for imaging at concentrations as low as 1 µM. Long-term toxicity results indicate low toxicity in HeLa cells with LD50 >100 µM. Osmium(II) complexes based on 1 therefore present an excellent platform for the development of novel theranostic agents for anticancer activity

Performance of MEMS-based visible-light adaptive optics at Lick Observatory: Closed- and open-loop control

At the University of California's Lick Observatory, we have implemented an on-sky testbed for next-generation adaptive optics (AO) technologies. The Visible-Light Laser Guidestar Experiments instrument (ViLLaGEs) includes visible-light AO, a micro-electro-mechanical-systems (MEMS) deformable mirror, and open-loop control of said MEMS on the 1-meter Nickel telescope at Mt. Hamilton. In this paper we evaluate the performance of ViLLaGEs in open- and closed-loop control, finding that both control methods give equivalent Strehl ratios of up to ~ 7% in I-band and similar rejection of temporal power. Therefore, we find that open-loop control of MEMS on-sky is as effective as closed-loop control. Furthermore, after operating the system for three years, we find MEMS technology to function well in the observatory environment. We construct an error budget for the system, accounting for 130 nm of wavefront error out of 190 nm error in the science-camera PSFs. We find that the dominant known term is internal static error, and that the known contributions to the error budget from open-loop control (MEMS model, position repeatability, hysteresis, and WFS linearity) are negligible.Comment: 16 pages, 13 figures, to appear in Proc. SPIE 2010 Vol. 7736 Adaptive Optics Systems II, high-resolution full-color version available at http://spiedl.org

Multi-Functional BN-BN Composite

Multifunctional Boron Nitride nanotube-Boron Nitride (BN-BN) nanocomposites for energy transducers, thermal conductors, anti-penetrator/wear resistance coatings, and radiation hardened materials for harsh environments. An all boron-nitride structured BN-BN composite is synthesized. A boron nitride containing precursor is synthesized, then mixed with boron nitride nanotubes (BNNTs) to produce a composite solution which is used to make green bodies of different forms including, for example, fibers, mats, films, and plates. The green bodies are pyrolized to facilitate transformation into BN-BN composite ceramics. The pyrolysis temperature, pressure, atmosphere and time are controlled to produce a desired BN crystalline structure. The wholly BN structured materials exhibit excellent thermal stability, high thermal conductivity, piezoelectricity as well as enhanced toughness, hardness, and radiation shielding properties. By substituting with other elements into the original structure of the nanotubes and/or matrix, new nanocomposites (i.e., BCN, BCSiN ceramics) which possess excellent hardness, tailored photonic bandgap and photoluminescence, result

Conversion of sub-tropical native vegetation to introduced conifer forest: Impacts on below-ground and above-ground carbon pools

Land-use change can have a major influence on soil organic carbon (SOC) and above-ground C pools. We assessed a change from native vegetation to introduced Pinus species plantations on C pools using eight paired sites. At each site we determined the impacts on 0–50 cm below-ground (SOC, charcoal C, organic matter C, particulate organic C, humic organic C, resistant organic C) and above-ground (litter, coarse woody debris, standing trees and woody understorey plants) C pools. In an analysis across the different study sites there was no significant difference (P > 0.05) in SOC or above-ground tree C stocks between paired native vegetation and pine plantations, although significant differences did exist at specific sites. SOC (calculated based on an equivalent soil mass basis) was higher in the pine plantations at two sites, higher in the native vegetation at two sites and did not differ for the other four sites. The site to site variation in SOC across the landscape was far greater than the variation observed with a change from native vegetation to introduced Pinus plantation. Differences between sites were not explained by soil type, although tree basal area was positively correlated with 0–50 cm SOC. In fact, in the native vegetation there was a significant linear relationship between above-ground biomass and SOC that explained 88.8% of the variation in the data. Fine litter C (0–25 mm diameter) tended to be higher in the pine forest than in the adjacent native vegetation and was significantly higher in the pine forest at five of the eight paired sites. Total litter C (0–100 mm diameter) increased significantly with plantation age (R2 = 0.64). Carbon stored in understorey woody plants (2.5–10 cm DBH) was higher in the native vegetation than in the adjacent pine forest. Total site C varied greatly across the study area from 58.8 Mg ha−1 at a native heathland site to 497.8 Mg ha−1 at a native eucalypt forest site. Our findings suggest that the effects of change from native vegetation to introduced Pinus sp. forest are highly site-specific and may be positive, negative, or have no influence on various C pools, depending on local site characteristics (e.g. plantation age and type of native vegetation)

Zwitterionic PEG-PC hydrogels modulate the foreign body response in a modulus-dependent manner

Reducing the foreign body response (FBR) to implanted biomaterials will enhance their performance in tissue engineering. Poly(ethylene glycol) (PEG) hydrogels are increasingly popular for this application due to their low cost, ease of use, and the ability to tune their compliance via molecular weight and crosslinking densities. PEG hydrogels can elicit chronic inflammation in vivo, but recent evidence has suggested that extremely hydrophilic, zwitterionic materials and particles can evade the immune system. To combine the advantages of PEG-based hydrogels with the hydrophilicity of zwitterions, we synthesized hydrogels with co-monomers PEG and the zwitterion phosphorylcholine (PC). Recent evidence suggests that stiff hydrogels elicit increased immune cell adhesion to hydrogels, which we attempted to reduce by increasing hydrogel hydrophilicity. Surprisingly, hydrogels with the highest amount of zwitterionic co-monomer elicited the highest FBR we observed. Lowering the hydrogel modulus (165 kPa to 3 kPa), or PC content (20 wt% to 0 wt%), mitigated this effect. A high density of macrophages was found at the surface of implants associated with a high FBR, and mass spectrometry analysis of the proteins adsorbed to these gels implicated extracellular matrix, immune response, and cell adhesion protein categories as drivers of macrophage recruitment to these hydrogels. Overall, we show that modulus regulates macrophage adhesion to zwitterionic-PEG hydrogels, and demonstrate that chemical modifications to hydrogels should be studied in parallel with their physical properties to optimize implant design