Radiation effects in Zr and Hf containing garnets

Garnets have been considered as host phases for the safe immobilisation of high-level nuclear waste, as they have been shown to accommodate a wide range of elements across three different cation sites, such as Ca, Y, Mn on the a-site, Fe, Al, U, Zr, and Ti on the b-site, and Si, Fe, Al on the c-site. Garnets, due to their ability to have variable composition, make ideal model materials for the examination of radiation damage and recovery in nuclear materials, including as potential waste forms. Kimzeyite, Ca3Zr2FeAlSiO12, has been shown naturally to contain up to 30 wt% Zr, and has previously been examined to elucidate both the structure and ordering within the lattice. This study examines the effects of radiation damage and recovery using in-situ ion beam irradiation with 1 MeV Kr ions at the IVEM-TANDEM facility, Argonne National Laboratory. The complementary Hf containing system Ca3Hf2FeAlSiO12 was also examined, and found to have a different response to irradiation damage. A sample of irradiated Ca3Zr2FeAlSiO12, at 1000 K, was characterised using aberration corrected (S)TEM and found to contain discreet, nano-sized, crystalline Fe rich particles, indicating a competing process during recovery is occurring

The enigmatic multiple star VV Ori

New photometry, including TESS data, have been combined with recent spectroscopic observations of the Orion Ib pulsating triple-star system VV Ori. This yields a revised set of absolute parameters with increased precision. Two different programs were utilized for the light curve analysis, with results in predictably close agreement. The agreement promotes confidence in the analysis procedures. The spectra were analysed using the {\sc FDBinary} program. The main parameters are as follows: $M_1 = 11.6 \pm 0.14$ and $M_2 = 4.8 \pm 0.06$ (M$_\odot$). We estimate an approximate mass of the wide companion as $M_3 = 2.0 \pm 0.3$ M$_\odot$. Similarly, $R_{1} = 5.11 \pm 0.03$, $R_2 = 2.51 \pm 0.02$, $R_3 = 1.8 \pm 0.1$ (R$_\odot$); $T_{\rm e 1} = 26600 \pm 300$, $T_{\rm e 2} = 16300 \pm 400$ and $T_{\rm e 3} = 10000 \pm 1000$ (K). The close binary's orbital separation is $a= 13.91$ (R$_\odot$); its age is $8 \pm 2$ (Myr) and its photometric distance is $396 \pm 7$ pc. The primary's $\beta$ Cep type oscillations support these properties and confirm our understanding of its evolutionary status. Examination of the well-defined $\lambda$6678 He I profiles reveals the primary to have a significantly low projected rotation: some 80\% of the synchronous value. This can be explained on the basis of the precession of an unaligned spin axis. This proposal can resolve also observed variations of the apparent inclination and address other longer-term irregularities of the system reported in the literature. This topic invites further observations and follow-up theoretical study of the dynamics of this intriguing young multiple star.Comment: 17 pages, 15 figures, 14 tables, accepted by MNRA

BVRI photometric observations, light curve solutions and orbital period analysis of BF Pav

A new ephemeris, period change analysis and light curve modeling of the W UMa-type eclipsing binary BF Pav are presented in this study. Light curves of the system taken in BVRI filters from two observatories, in Australia and Argentina, were modeled using the Wilson-Devinney code. The results of this analysis demonstrate that BF Pav is a contact binary system with a photometric mass ratio q = 1.460 ± 0.014, a fillout factor f = 12.5%, an inclination of 87.97 ± 0.45 deg and a cold spot on the secondary component. By applying the distance modulus formula, the distance of BF Pav was calculated to be d = 268 ± 18 pc which is in good agreement with the Gaia EDR3 distance. We obtain an orbital period increase at a rate of 0.142 s century−1 due to a quadratic trend in the O − C diagram. Also, an alternative sudden period jump probably occurred which could be interpreted as a rapid mass transfer from the lower mass star to its companion of about ∆M = 2.45×10−6 M. Furthermore, there is an oscillatory behavior with a period of 18.3 ± 0.3 yr. Since BF Pav does not seem to have significant magnetic activity, this behavior could be interpreted as the light-time effect caused by an undetected third body in this system. In this case, the probability for the third body to be a low mass star with M ≥ 0.075 M or a brown dwarf is 5.4% and 94.6% respectively. If we assume i0 = 90◦, a3 = 8.04 ± 0.33 AU. The mass of the secondary component was also determined following two different methods which result close to each other.Fil: Poro, Atila. The International Occultation Timing Association Middle East section; IránFil: Alicavus, Fahri. Canakkale Onsekiz Mart University; TurquíaFil: Fernandez Lajus, Eduardo Eusebio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Astrofísica La Plata. Universidad Nacional de La Plata. Facultad de Ciencias Astronómicas y Geofísicas. Instituto de Astrofísica La Plata; ArgentinaFil: Davoudi, Fatemeh. The International Occultation Timing Association Middle East section; IránFil: MirshafieKhozani, PegahSadat. The International Occultation Timing Association Middle East section; IránFil: Blackford, Mark G.. Congarinni Observatory; AustraliaFil: Budding, Edwin. Université du Québec a Montreal; CanadáFil: Jalalabadi, Behjat Zarei. Carter Observatory; Nueva ZelandaFil: Rahimi, Jabar. The International Occultation Timing Association Middle; IránFil: Farahani, Farzaneh Ahangarani. The International Occultation Timing Association Middle; Irá

Detection and impacts of leakage from sub-seafloor deep geological carbon dioxide storage

Fossil fuel power generation and other industrial emissions of carbon dioxide are a threat to global climate1, yet many economies will remain reliant on these technologies for several decades2. Carbon dioxide capture and storage (CCS) in deep geological formations provides an effective option to remove these emissions from the climate system3. In many regions storage reservoirs are located offshore4, 5, over a kilometre or more below societally important shelf seas6. Therefore, concerns about the possibility of leakage7, 8 and potential environmental impacts, along with economics, have contributed to delaying development of operational CCS. Here we investigate the detectability and environmental impact of leakage from a controlled sub-seabed release of CO2. We show that the biological impact and footprint of this small leak analogue (<1 tonne CO2 d?1) is confined to a few tens of metres. Migration of CO2 through the shallow seabed is influenced by near-surface sediment structure, and by dissolution and re-precipitation of calcium carbonate naturally present in sediments. Results reported here advance the understanding of environmental sensitivity to leakage and identify appropriate monitoring strategies for full-scale carbon storage operations

Genome-wide meta-analysis identifies five new susceptibility loci for pancreatic cancer.

In 2020, 146,063 deaths due to pancreatic cancer are estimated to occur in Europe and the United States combined. To identify common susceptibility alleles, we performed the largest pancreatic cancer GWAS to date, including 9040 patients and 12,496 controls of European ancestry from the Pancreatic Cancer Cohort Consortium (PanScan) and the Pancreatic Cancer Case-Control Consortium (PanC4). Here, we find significant evidence of a novel association at rs78417682 (7p12/TNS3, P = 4.35 × 10-8). Replication of 10 promising signals in up to 2737 patients and 4752 controls from the PANcreatic Disease ReseArch (PANDoRA) consortium yields new genome-wide significant loci: rs13303010 at 1p36.33 (NOC2L, P = 8.36 × 10-14), rs2941471 at 8q21.11 (HNF4G, P = 6.60 × 10-10), rs4795218 at 17q12 (HNF1B, P = 1.32 × 10-8), and rs1517037 at 18q21.32 (GRP, P = 3.28 × 10-8). rs78417682 is not statistically significantly associated with pancreatic cancer in PANDoRA. Expression quantitative trait locus analysis in three independent pancreatic data sets provides molecular support of NOC2L as a pancreatic cancer susceptibility gene

Towards improved monitoring of offshore carbon storage: A real-world field experiment detecting a controlled sub-seafloor CO2 release

Carbon capture and storage (CCS) is a key technology to reduce carbon dioxide (CO2) emissions from industrial processes in a feasible, substantial, and timely manner. For geological CO2 storage to be safe, reliable, and accepted by society, robust strategies for CO2 leakage detection, quantification and management are crucial. The STEMM-CCS (Strategies for Environmental Monitoring of Marine Carbon Capture and Storage) project aimed to provide techniques and understanding to enable and inform cost-effective monitoring of CCS sites in the marine environment. A controlled CO2 release experiment was carried out in the central North Sea, designed to mimic an unintended emission of CO2 from a subsurface CO2 storage site to the seafloor. A total of 675 kg of CO2 were released into the shallow sediments (∼3 m below seafloor), at flow rates between 6 and 143 kg/d. A combination of novel techniques, adapted versions of existing techniques, and well-proven standard techniques were used to detect, characterise and quantify gaseous and dissolved CO2 in the sediments and the overlying seawater. This paper provides an overview of this ambitious field experiment. We describe the preparatory work prior to the release experiment, the experimental layout and procedures, the methods tested, and summarise the main results and the lessons learnt

Transmission electron microscopy (TEM) characterisation of thermally grown RuO2 thin films

RuO2 thin film fabricated by rf- sputtering from a pure Ru target and subsequently oxidized at 600C 30 minutes under O2/N2 gas was studied by transmission electron microscopy (TEM). The un-oxidized Ru grains are found at the bottom of the film in broken segments; whereas the oxidized RuO2 grains are found on top of the Ru grains but are frequently in direct contact with the SiO2 layer. The observations partially support the work function measurement of such films in a previous study

Transmission electron microscopy (TEM) characterisation of Ru2Si3 thin films formed by solid state reaction of Ru and Si

Transmission electron microscopy investigation on Ru2Si3 thin films formed by solid state reaction of Ru and Si revealed a top layer of SiO2 with embedded Ru clusters. We attribute the formation of the top layer to the oxidation between residual oxygen traces in the nitrogen and the silicon in Ru2Si3 grains. The observation is in agreement with electrical measurements. In addition, an interlayer, which has complex structure and chemistry, was observed between the film and substrate

The Influence of fly ash morphology and phase distribution on collection in an electrostatic precipitator

Fly Ash is the unburnt portion of fuels which is carried away as solid particles in the hot gas stream of a furnace. About 99% of the fly ash produced in a typical coal-fired power station is removed by electrostatic precipitators or baghouse filters located at the base of the emission stack. Precipitator efficiency is dependent on the charging properties of the fly ash particles and the adhesive forces between them. These forces depend on the size, morphology, chemical constitution and phase distribution of the fly ash. Larger particles are usually found as aggregates held together by bridging material which may be small glassy particles, graphite sheets, or a mixture of amorphous material and small crystallites