1,447 research outputs found
Hyperbranched Rigid Aromatic Phosphorus-Containing Flame Retardants for Epoxy Resins
A rigid aromatic phosphorus-containing hyperbranched flame retardant structure is synthesized from 10-(2,5-dihydroxyphenyl)-10H-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-HQ), tris(4-hydroxyphenyl)phosphine oxide (THPPO), and 1,4-terephthaloyl chloride (TPC). The resulting poly-(DOPO-HQ/THPPO-terephthalate) (PDTT) is implemented as a flame retardant into an epoxy resin (EP) at a 10 wt% loading. The effects on EP are compared with those of the monomer DOPO-HQ and triphenylphosphine oxide (OPPh3) as low molar mass flame retardants. The glass transition temperature, thermal decomposition, flammability (reaction to small flame), and burning behavior of the thermosets are investigated using differential scanning calorimetry, thermogravimetric analysis, pyrolysis combustion flow calorimetry, UL 94-burning chamber testing, and cone calorimeter measurements. Although P-contents are low at only 0.6 wt%, the study aims not at attaining V-0, but at presenting a proof of principle: Epoxy resinswith PDTT show promising fire performance, exhibiting a 25% reduction in total heat evolved (THE), a 30% reduction in peak heat release rate (PHRR) due to flame inhibition (21% reduction in effective heat of combustion (EHC)), and an increase in T-g at the same time. This study indicates that rigid aromatic hyperbranched polymeric structures offer a promising route toward multifunctional flame retardancy
Estimating rates of carriage acquisition and clearance and competitive ability for pneumococcal serotypes in Kenya with a Markov transition model.
BACKGROUND: There are more than 90 serotypes of Streptococcus pneumoniae, with varying biologic and epidemiologic properties. Animal studies suggest that carriage induces an acquired immune response that reduces duration of colonization in a nonserotype-specific fashion. METHODS: We studied pneumococcal nasopharyngeal carriage longitudinally in Kenyan children 3-59 months of age, following up positive swabs at days 2, 4, 8, 16, and 32 and then monthly thereafter until 2 swabs were negative for the original serotype. As previously reported, 1868/2840 (66%) of children swabbed at baseline were positive. We estimated acquisition, clearance, and competition parameters for 27 serotypes using a Markov transition model. RESULTS: Point estimates of type-specific acquisition rates ranged from 0.00025/d (type 1) to 0.0031/d (type 19F). Point estimates of time to clearance (inverse of type-specific immune clearance rate) ranged from 28 days (type 20) to 124 days (type 6A). For the serotype most resistant to competition (type 19F), acquisition of other serotypes was 52% less likely (95% confidence interval = 37%-63%) than in an uncolonized host. Fitness components (carriage duration, acquisition rate, lack of susceptibility to competition) were positively correlated with each other and with baseline prevalence, and were associated with biologic properties previously shown to associate with serotype. Duration of carriage declined with age for most serotypes. CONCLUSIONS: Common S. pneumoniae serotypes appear superior in many dimensions of fitness. Differences in rate of immune clearance are attenuated as children age and become capable of more rapid clearance of the longest-lived serotypes. These findings provide information for comparison after introduction of pneumococcal conjugate vaccine
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Multiple List Learning in Adults with Autism Spectrum Disorder: Parallels with Frontal Lobe Damage or Further Evidence of Diminished Relational Processing?
To test the effects of providing relational cues at encoding and/or retrieval on multi-trial, multi-list free recall in adults with high-functioning autism spectrum disorder (ASD), 16 adults with ASD and 16 matched typical adults learned a first followed by a second categorised list of 24 words. Category labels were provided at encoding, retrieval, both or not at all. Both groups showed enhanced recall when labels were available during encoding or throughout the task. ASD individuals showed reduced recall of the second list and reduced clustering. Clustering and recall were correlated in both groups, which also showed similar levels of subjective organisation. The findings are discussed in relation to theories of frontal and medial temporal lobe contributions to memory in ASD
Observation of an Excited Bc+ State
Using pp collision data corresponding to an integrated luminosity of 8.5 fb-1 recorded by the LHCb experiment at center-of-mass energies of s=7, 8, and 13 TeV, the observation of an excited Bc+ state in the Bc+Ï+Ï- invariant-mass spectrum is reported. The observed peak has a mass of 6841.2±0.6(stat)±0.1(syst)±0.8(Bc+) MeV/c2, where the last uncertainty is due to the limited knowledge of the Bc+ mass. It is consistent with expectations of the Bcâ(2S31)+ state reconstructed without the low-energy photon from the Bcâ(1S31)+âBc+Îł decay following Bcâ(2S31)+âBcâ(1S31)+Ï+Ï-. A second state is seen with a global (local) statistical significance of 2.2Ï (3.2Ï) and a mass of 6872.1±1.3(stat)±0.1(syst)±0.8(Bc+) MeV/c2, and is consistent with the Bc(2S10)+ state. These mass measurements are the most precise to date
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Measurement of CP observables in the process B <sup>0</sup> â DK <sup>*0</sup> with two- and four-body D decays
Measurements of observables in decays are presented,
where represents a superposition of and states. The
meson is reconstructed in the two-body final states , ,
and , and, for the first time, in the four-body final
states , and .
The analysis uses a sample of neutral mesons produced in proton-proton
collisions, corresponding to an integrated luminosity of 1.0, 2.0 and 1.8 collected with the LHCb detector at centre-of-mass energies of
7, 8 and 13 TeV, respectively. First observations of the decays
and are
obtained. The measured observables are interpreted in terms of the
-violating weak phase
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Updated measurement of time-dependent CP -violating observables in Bs0âJ/Ï<sup>K+</sup><sup>K-</sup> decays
The decay-time-dependent asymmetry in
decays is measured using proton-proton collision data, corresponding to an
integrated luminosity of , collected with the LHCb
detector at a centre-of-mass energy of in 2015 and 2016.
Using a sample of approximately 117\,000 signal decays with an invariant mass in the vicinity of the resonance, the -violating
phase is measured, along with the difference in decay widths of the
light and heavy mass eigenstates of the - system,
. The difference of the average and meson
decay widths, , is determined using in addition a sample of
decays. The values obtained are , and , where the first uncertainty is statistical and the
second systematic. These are the most precise single measurements of these
quantities to date and are consistent with expectations based on the Standard
Model and with a previous LHCb analysis of this decay using data recorded at
centre-of-mass energies 7 and 8 TeV. Finally, the results are combined with
recent results from decays obtained using
the same dataset as this analysis, and with previous independent LHCb results
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Observation of the Îb0âÏc1 (3872) pK<sup>â</sup> decay
Using proton-proton collision data, collected with the LHCb detector and
corresponding to 1.0, 2.0 and 1.9fb of integrated luminosity at the
centre-of-mass energies of 7, 8, and 13 TeV, respectively, the decay
with is
observed for the first time. The significance of the observed signal is in
excess of seven standard deviations. It is found that of the
decays proceed via the two-body intermediate state
. The~branching fraction with respect to that of
the decay mode, where the
~meson is reconstructed in the final state, is
measured to be: \begin{equation*}
\frac{\Lambda_b^0\to\chi_{c1}(3872)pK^-}{\Lambda_b\to\psi(2S)p K^-} \times
\frac{\mathcal{B}(\chi_{c1} \to J/\psi \pi^+\pi^-)}{\mathcal{B}(\psi(2S)\to
J/\psi \pi^+\pi^-)} = \left(5.4 \pm 1.1 \pm 0.2\right)\times 10^{-2}\,,
\end{equation*} where the first uncertainty is statistical and the second is
systematic
Measurement of b hadron fractions in 13 TeV pp collisions
The production fractions of
ÂŻ
B
0
s
and
Î
0
b
hadrons, normalized to the sum of
B
â
and
ÂŻ
B
0
fractions, are measured in 13 TeV
p
p
collisions using data collected by the LHCb experiment, corresponding to an integrated luminosity of
1.67
â
â
fb
â
1
. These ratios, averaged over the
b
hadron transverse momenta from 4 to 25 GeV and pseudorapidity from 2 to 5, are
0.122
±
0.006
for
ÂŻ
B
0
s
, and
0.259
±
0.018
for
Î
0
b
, where the uncertainties arise from both statistical and systematic sources. The
Î
0
b
ratio depends strongly on transverse momentum, while the
ÂŻ
B
0
s
ratio shows a mild dependence. Neither ratio shows variations with pseudorapidity. The measurements are made using semileptonic decays to minimize theoretical uncertainties. In addition, the ratio of
D
+
to
D
0
mesons produced in the sum of
ÂŻ
B
0
and
B
â
semileptonic decays is determined as
0.359
±
0.006
±
0.009
, where the uncertainties are statistical and systematic
Observation of B(s)0âJ/ÏppÂŻ decays and precision measurements of the B(s)0 masses
The first observation of the decays
B
0
(
s
)
â
J
/
Ï
p
ÂŻ
p
is reported, using proton-proton collision data corresponding to an integrated luminosity of
5.2
â
â
fb
â
1
, collected with the LHCb detector. These decays are suppressed due to limited available phase space, as well as due to Okubo-Zweig-Iizuka or Cabibbo suppression. The measured branching fractions are
B
(
B
0
â
J
/
Ï
p
ÂŻ
p
)
=
[
4.51
±
0.40
(
stat
)
±
0.44
(
syst
)
]
Ă
10
â
7
,
B
(
B
0
s
â
J
/
Ï
p
ÂŻ
p
)
=
[
3.58
±
0.19
(
stat
)
±
0.39
(
syst
)
]
Ă
10
â
6
. For the
B
0
s
meson, the result is much higher than the expected value of
O
(
10
â
9
)
. The small available phase space in these decays also allows for the most precise single measurement of both the
B
0
mass as
5279.74
±
0.30
(
stat
)
±
0.10
(
syst
)
â
â
MeV
and the
B
0
s
mass as
5366.85
±
0.19
(
stat
)
±
0.13
(
syst
)
â
â
MeV
Measurement of the Charm-Mixing Parameter yCP
A measurement of the charm-mixing parameter y_{CP} using D^{0}âK^{+}K^{-}, D^{0}âÏ^{+}Ï^{-}, and D^{0}âK^{-}Ï^{+} decays is reported. The D^{0} mesons are required to originate from semimuonic decays of B^{-} and B[over ÂŻ]^{0} mesons. These decays are partially reconstructed in a data set of proton-proton collisions at center-of-mass energies of 7 and 8 TeV collected with the LHCb experiment and corresponding to an integrated luminosity of 3ââfb^{-1}. The y_{CP} parameter is measured to be (0.57±0.13(stat)±0.09(syst))%, in agreement with, and as precise as, the current world-average value
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