Lifetime of d-holes at Cu surfaces: Theory and experiment

We have investigated the hole dynamics at copper surfaces by high-resolution angle-resolved photoemission experiments and many-body quasiparticle GW calculations. Large deviations from a free-electron-like picture are observed both in the magnitude and the energy dependence of the lifetimes, with a clear indication that holes exhibit longer lifetimes than electrons with the same excitation energy. Our calculations show that the small overlap of d- and sp-states below the Fermi level is responsible for the observed enhancement. Although there is qualitative good agreement of our theoretical predictions and the measured lifetimes, there still exist some discrepancies pointing to the need of a better description of the actual band structure of the solid.Comment: 15 pages, 7 figures, 1 table, to appear in Phys. Rev.

Hole dynamics in noble metals

We present a detailed analysis of hole dynamics in noble metals (Cu and Au), by means of first-principles many-body calculations. While holes in a free-electron gas are known to live shorter than electrons with the same excitation energy, our results indicate that d-holes in noble metals exhibit longer inelastic lifetimes than excited sp-electrons, in agreement with experiment. The density of states available for d-hole decay is larger than that for the decay of excited electrons; however, the small overlap between d- and sp-states below the Fermi level increases the d-hole lifetime. The impact of d-hole dynamics on electron-hole correlation effects, which are of relevance in the analysis of time-resolved two-photon photoemission experiments, is also addressed.Comment: 4 pages, 2 figures, to appear in Phys. Rev. Let

Responsive Giant Vesicles filled with Poly(N-isopropylacrylamide) Sols or Gels

4 pagesInternational audienceWe prepared giant unilamellar vesicles (GUVs) enclosing solutions or covalent gels of Poly(Nisopropylacrylamide) (PolyNipam). Concentrated suspensions of GUVs were prepared by applying an alternative field on a lipid film hydrated by a monomer solution containing N-isopropylacrylamide, crosslinker (N,N-methylene-bis-acrylamide), initiator and sucrose. Vesicle inner medium was polymerised and crosslinked by UV irradiation of the suspension, yielding viscous vesicles enclosing a solution of linear PolyNipam chains (when no bisacrylamide was used) or elastic vesicles filled with a covalent PolyNipam gel. We show that gel-filled vesicles are responsive systems triggered by the temperature: they shrink, reducing by a factor eight their volume below the critical temperature (32 ◦C in water, lower in glucose solution) and re-swell in a reversible and reproducible way upon decreasing temperature. In both cases, we show that the vesicle lipid membrane interacts with the internal polymer, resulting in an strong resistance of the vesicles to external mechanical stresses (enhanced tension of lysis)

Anomalous Quasiparticle Lifetime in Graphite: Band Structure Effects

We report ab initio calculation of quasiparticle lifetimes in graphite, as determined from the imaginary part of the self-energy operator within the GW aproximation. The inverse lifetime in the energy range from 0.5 to 3.5 eV above the Fermi level presents significant deviations from the quadratic behavior naively expected from Fermi liquid theory. The deviations are explained in terms of the unique features of the band structure of this material. We also discuss the experimental results from different groups and make some predictions for future experiments.Comment: 4 pages, 4 figures, submitted PR

Toward Forecasting Volcanic Eruptions using Seismic Noise

During inter-eruption periods, magma pressurization yields subtle changes of the elastic properties of volcanic edifices. We use the reproducibility properties of the ambient seismic noise recorded on the Piton de la Fournaise volcano to measure relative seismic velocity variations of less than 0.1 % with a temporal resolution of one day. Our results show that five studied volcanic eruptions were preceded by clearly detectable seismic velocity decreases within the zone of magma injection. These precursors reflect the edifice dilatation induced by magma pressurization and can be useful indicators to improve the forecasting of volcanic eruptions.Comment: Supplementary information: http://www-lgit.obs.ujf-grenoble.fr/~fbrengui/brenguier_SI.pdf Supplementary video: http://www-lgit.obs.ujf-grenoble.fr/~fbrengui/brenguierMovieVolcano.av

Surface plasmon toy-model of a rotating black hole

Recently introduced surface plasmon toy black hole model has been extended in order to emulate a rotating black hole (Kerr metric). Physical realization of this model involves a droplet of an optically active liquid on the metal surface which supports propagation of surface plasmons. Such droplets are shown to exhibit giant optical activity in the frequency range near the surface plasmon resonance of a metal-liquid interface.Comment: 4 pages, 4 figure

Tomography of the Alpine region from observations of seismic ambient noise

We use correlations of the ambient seismic noise to study the crust in western Europe. Cross correlation of 1 year of noise recorded at 150 three components broadband stations yields more than 3 000 Rayleigh wave group velocity measurements. These measurements are used to construct Rayleigh group velocity maps of the Alpine region and surrounding area in the 5-80 s period band. In the 5-10 s period band, the seismic noise recorded in Europe is dominated by surface waves originating from the Northern Atlantic ocean. This anisotropy of the noise and the uneven station distribution affect the azimuthal distribution of the paths where we obtain reliable group velocity measurements. As a consequence our group velocity models have better resolution in the northeast direction than in the southwest direction. Finally we invert the resulting Rayleigh wave group velocity maps to determine the Moho depth. Our results are in good agreement with the result of the numerous active experiments in the Alps and provide a continuous image of the Alpine structur

Blue luminescence of Au nanoclusters embedded in silica matrix

Photoluminescence study using the 325 nm He-Cd excitation is reported for the Au nanoclusters embedded in SiO2 matrix. Au clusters are grown by ion beam mixing with 100 KeV Ar+ irradiation on Au [40 nm]/SiO2 at various fluences and subsequent annealing at high temperature. The blue bands above ~3 eV match closely with reported values for colloidal Au nanoclusters and supported Au nanoislands. Radiative recombination of sp electrons above Fermi level to occupied d-band holes are assigned for observed luminescence peaks. Peaks at 3.1 eV and 3.4 eV are correlated to energy gaps at the X- and L-symmetry points, respectively, with possible involvement of relaxation mechanism. The blue shift of peak positions at 3.4 eV with decreasing cluster size is reported to be due to the compressive strain in small clusters. A first principle calculation based on density functional theory using the full potential linear augmented plane wave plus local orbitals (FP-LAPW+LO) formalism with generalized gradient approximation (GGA) for the exchange correlation energy is used to estimate the band gaps at the X- and L-symmetry points by calculating the band structures and joint density of states (JDOS) for different strain values in order to explain the blueshift of ~0.1 eV with decreasing cluster size around L-symmetry point.Comment: 13 pages, 7 Figures Only in PDF format; To be published in J. of Chem. Phys. (Tentative issue of publication 8th December 2004

Garnet-clinopyroxene bearing assemblages in the 'upper catazonal unit' of the Cabo Ortega! Complex (NW Spain)

[Resumen] Se han estudiado los siguientes materiales de la 'unidad catazonal superior' del Complejo del Cabo Ortegal conteniendo asociaciones con granate-clinopiroxeno: eclogitas, granulitas básicas, intercalaciones gneísicas en las granulitas, piroxenitas con granate, gneises de la aureola de contacto de las rocas ultramáficas, metabasitas de la 'formación Candelaria' y 'carbonatitas'. Los datos termobarométricos obtenidos sugieren que, mientras que los minerales de algunos de estos materiales han sufrido importantes reajustes composicionales durante los procesos de retromorfosis (e. g. granulitas con distena, intercalaciones gneísicas en granulitas, -intercalaciones u1tramáficas en gneises, etc.), otros han conservado elementos mineralógicos con la composición alcanzada durante el episodio metamórfico que originó la formación de las asociaciones con granate-clinopiroxeno. Este segundo grupo de materiales puede subdividirse en dos categorías: 1) aquellos materiales en los que la asociación granate-clinopiroxeno se formó en torno a los 800 oC y 15 ± 1. 5 kbar (eclogitas 'tipo-I', granulitas de la 'formación Bracariza', piroxenitas con granate de los macizos de rocas u1tramáficas 'carbonatitas'), y, 11) aquellos en los que dicha asociaci6n se formó a unos 700 oC y la misma P aproximadamente (eclogitas y granulitas intercaladas en las formaciones gneísicas). Aunque las diferencias no son muy importantes, es posible que los dos conjuntos litológicos representen dos gradientes metamórficos distintos y, por tanto, la existencia en dicha 'unidad' de materiales con diferentes historias tectono-metamórficas.[Abstract] The following materials from the 'uper' catazonal unit' of the Cabo Ortegal Complex, containing garnet-clinopyroxene assemblages, have been studied: eclogites, basic granulites, gneissic intercalations within granulites, garnetbearing pyroxenites, gneisses from the contact aureole of the ultramafic rocks, metabasites from the 'Candelaria formation' and 'carbonatites'. The thermobarometric data obtained from this study suggest that the minerals from several of those materials underwent strong compositional readjustements during the subsequent retromorphic events (e. g. the kyanite-bearing granulites, the gneissic intercalations in granulites, the u1tramafic intercalations in gneisses, etc.). The remaining materials have preserved mineral compositions attained during the metamorphic episode that produced the garnetclinopyroxene assemblages; these materials may be classified as follows: 1) those in which the garnet-clinopyroxene assemblage formed at ca. 800 oC and 15 ± ± 1,5 kbar ('type-I' eclogites, granulites from the 'Bacariza formation', garnetbearing pyroxenites from the ultramafic massifs and 'carbonatites'), and, 11) those where the same association developed at ca 700 oC and more or less the same P conditions (eclogites and granulites intercaled in gneisses). Although these differences in P and Tare not very important, it is possible that these two groups represent two different metamorphic gradients, and therefore the existence in this 'unit' of the Complex of two lithological sub-units with different tectono-metamorphic histories