Titaniq Thermobarometry of Fabric Development in the Strafford Dome, Vermont: Linking Microstructures to Orogenic Processes

Abstract Geochemical, microstructural and petrological analyses were conducted on metapelites from the Strafford Dome, Vermont. Samples record metamorphic conditions from biotite to peak kyanite/staurolite grade and preserve microstructures related to two Acadian nappe emplacement events. The purpose of this study was to test the validity and application of the Ti-in-quartz (“TitaniQ”) thermobarometer to constraining pressure-temperature-timing-deformation (P-T-t-D) paths in metamorphic tectonites. Due to the nearly ubiquitous presence of quartz in continental rocks, the ability to apply this method would have significant implications for improving our ability to resolve tectonic histories. Cathodoluminescence (CL) imaging on quartz was conducted to qualitatively assess the distribution of Ti in a single grain and/or compare neighboring crystals. X-ray mapping of garnet porphyroblasts was conducted to estimate P-T conditions during garnet growth to provide a framework for included quartz grains. P-T-X contour diagrams (used in P-T calculations for garnet growth) were constructed from data obtained by X-ray fluorescence analysis on bulk-rock chemistries. Secondary ion mass spectrometry analysis was conducted to constrain Ti concentrations in quartz due to the low [Ti] present in the Strafford samples (\u3c10 ppm). Analysis of the samples revealed [Ti] in zoned quartz grains that can be grouped and associated with certain P-T-D conditions. A majority of quartz grains have dark cores in CL images with low [Ti] (~2.5–3.5 ppm) in both matrix quartz and inclusions. Quartz inclusions in garnets that grew syn-tectonically with D2 have bright rims ~5.5 ppm. Matrix quartz, on the other hand, has rims with much higher [Ti] (~7.5–9.5 ppm). Comparing these Ti concentrations to summary P-T paths from previous studies suggests: quartz inclusions have rims recrystallized during the end of D1 deformation, matrix grains have rims re-equilibrated at peak P-T conditions post-D2 deformation, and the dark cores observed in CL images must be from early prograde or relics of the protolith. The evaluation of the TitaniQ thermobarometer’s application to constrain P-T-t-D histories has highlighted some potential problems and significant benefits. To use the thermobarometer, either T or P must be independently constrained, which is often difficult to do given the many microstructural contexts of quartz in a single sample. This study capitalized on the ability to determine the relative timing of quartz (re)crystallization relative to garnet growth. Using another trace element thermobarometer would be ideal (e.g. Zr-in-rutile) for greater precision, although the relevant accessory phases may not be present and constraining the timing of re-equilibration is challenging. The abundance of quartz in continental rocks and the various microstructural occurrences of quartz in a single metamorphic tectonite provides additional opportunities to constrain points on the P-T-D path than conventional thermobarometers. The TitaniQ thermobarometer has the potential to yield deeper insights into the tectonic history of crustal rocks than previously available. These findings further elucidate the potential of the method for use in studies of metamorphic tectonites, continental tectonics and rheology

Multiple sediment incorporation events in a continental magmatic arc: Insight from the metasedimentary rocks of the northern North Cascades, Washington (USA)

The rheology and composition of arc crust and the overall evolution of continental magmatic arcs can be affected by sediment incorporation events. The exhumed Cretaceous–Eocene North Cascades arc exposes abundant meta­ sedimentary rocks that were incorporated into the arc during multiple events. This study uses field relationships, detrital zircon geochronology, bulk rock geo­ chemistry, geothermometry, and quartz­in­garnet geobarometry to distinguish approximate contacts and emplacement depths for different metasedimentary units to better understand their protolith incorporation history and impact on the arc. The Skagit Gneiss Complex is one of the main deep crustal units of the North Cascades arc. It includes metasedimentary rocks with distinct detrital zircon signatures: Proterozoic–Cretaceous (Group 1) or Triassic–Cretaceous (Group 2) zircon populations. Both metasedimentary groups achieved near­ peak metamorphic conditions of 640–800 °C and 5.5–7.9 kbar; several Group 2 samples reveal the higher pressures. A third group of metasedimentary rocks, which was previously interpreted as metamorphosed equivalents of backarc sediments (Group 3), exhibited unimodal Triassic or bimodal Late Jurassic– Early Cretaceous detrital zircon signatures and achieved near­peak conditions of 570–700 °C and 8.7–10.5 kbar. The combined field and analytical data indi­ cate that protoliths of Group 1 and Group 2 metasedimentary rocks were successively deposited in a forearc basin and underthrusted into the arc as a relatively coherent body. Group 3 backarc sediments were incorporated into the arc along a transpressional step­over zone. The incorporation of both forearc and backarc sediments was likely facilitated by arc magmatism that weakened arc crust in combination with regional transpression

Tectonic Transport Directions, Shear Senses and Deformation Temperatures Indicated by Quartz c‐Axis Fabrics and Microstructures in a NW‐SE Transect across the Moine and Sgurr Beag Thrust Sheets, Caledonian Orogen of Northern Scotland

Moine metasedimentary rocks of northern Scotland are characterized by arcuate map patterns of mineral lineations that swing progressively clockwise from orogen‐perpendicular E‐trend-ing lineations in greenschist facies mylonites above the Moine thrust on the foreland edge of the Caledonian Orogen, to S‐trending lineations at higher structural levels and metamorphic grades in the hinterland. Quartz c‐axis fabrics measured on a west to east coast transect demonstrate that the lineations developed parallel to the maximum principal extension direction and therefore track the local tectonic transport direction. Microstructures and c‐axis fabrics document a progressive change from top to the N shearing in the hinterland to top to the W shearing on the foreland edge. Field relationships indicate that the domain of top to the N shearing was at least 55 km wide before later horizontal shortening on km‐scale W‐vergent folds that detach on the underlying Moine thrust. Previously published data from the Moine thrust mylonites demonstrate that top to the W shearing had largely ceased by 430 Ma, while preliminary isotopic age data suggest top to the N shearing occurred at ~470–450 Ma. In addition, data from the east coast end of our transect indicate normal-sense top down‐SE shearing at close to peak temperatures at ~420 Ma that may be related to the closing stages of Scandian deformation, metamorphism and cooling/exhumation

The Distinct Metamorphic Stages and Structural Styles of the 1.94–1.86 Ga Snowbird Orogen, Northwest Territories, Canada

Palaeoproterozoic orogenesis within the Archean southeastern Rae craton is related to the initial amalgamation of Laurentia. Characterizing the accompanying tectonic processes during this time has been complicated due to polymetamorphism, which results in the obscuring of the age record of the terranes involved. To improve the knowledge of the tectonic evolution of the South Rae Craton, petrologic and structural analyses are applied in conjunction with in situ trace element chemistry, inclusion barometry, U–Pb monazite and titanite, and Lu–Hf garnet chronology. The data robustly constrain Palaeoproterozoic pressure–temperature–time paths of major deformational events along the southeastern Rae craton margin. D1 occurred between 1.94 and 1.93 Ga in the Dodge-Snowbird domain, which included prograde burial of metasedimentary rocks, deposited at 2.2–2.0 Ga, and the development of migmatitic layering and east-southeast trending folds (S1, F1). Peak metamorphism is recorded in metasedimentary units at c. 1.93 Ga when rocks reached conditions of 9.0–10.5 kbar and 810–830°C. Within the Dodge-Snowbird domain, D2 imparted north-northeast trending open folds and associated axial planar cleavage (S2, F2) between 1.93 and 1.90 Ga during east-west compression that appears to have been synchronous with cooling and exhumation. Later D2 deformation, localized within the Wholdaia Lake shear zone (WLsz; ST1), developed in the footwall of this thrust-sense structure at 1,873 ± 5 Ma at conditions of 9.5–11.0 kbar and 820–850°C. The hangingwall Dodge-Snowbird domain had already cooled to below 300°C by then, indicating a significant structural and metamorphic break across the domain\u27s western boundary. A new phase of unroofing (D3) involved pervasive amphibolite- to greenschist facies extensional shearing (ST2) within the WLsz, which overprinted ST1 foliations between 1.87 and 1.86 Ga. Continued greenschist facies shearing younger than 1.86 Ga likely ended by c. 1.83 Ga when lamprophyre dykes cut the structure, which was followed by cooling until c. 1.80 Ga. This work highlights the utility and application of multiple chronometers (zircon, monazite, titanite, garnet) along with structural and petrologic analysis that together can resolve precise orogenic cycles in polymetamorphic terranes that may otherwise be undetected. The time-resolved P–T–D histories derived here enable more robust interpretations regarding the nature and evolution of 1.9 Ga tectonism along the southeast Rae craton margin, which may be used to refine models for Laurentian terrane amalgamation

De novo mutations in PURA are associated with hypotonia and developmental delay

PURA is the leading candidate gene responsible for the developmental phenotype in the 5q31.3 microdeletion syndrome. De novo mutations in PURA were recently reported in 15 individuals with developmental features similar to the 5q31.3 microdeletion syndrome. Here we describe six unrelated children who were identified by clinical whole-exome sequencing (WES) to have novel de novo variants in PURA with a similar phenotype of hypotonia and developmental delay and frequently associated with seizures. The protein Puralpha (encoded by PURA) is involved in neuronal proliferation, dendrite maturation, and the transport of mRNA to translation sites during neuronal development. Mutations in PURA may alter normal brain development and impair neuronal function, leading to developmental delay and the seizures observed in patients with mutations in PURA

Structure of the γ-D-glutamyl-L-diamino acid endopeptidase YkfC from Bacillus cereus in complex with L-Ala-γ-D-Glu: insights into substrate recognition by NlpC/P60 cysteine peptidases.

Dipeptidyl-peptidase VI from Bacillus sphaericus and YkfC from Bacillus subtilis have both previously been characterized as highly specific γ-D-glutamyl-L-diamino acid endopeptidases. The crystal structure of a YkfC ortholog from Bacillus cereus (BcYkfC) at 1.8 Å resolution revealed that it contains two N-terminal bacterial SH3 (SH3b) domains in addition to the C-terminal catalytic NlpC/P60 domain that is ubiquitous in the very large family of cell-wall-related cysteine peptidases. A bound reaction product (L-Ala-γ-D-Glu) enabled the identification of conserved sequence and structural signatures for recognition of L-Ala and γ-D-Glu and, therefore, provides a clear framework for understanding the substrate specificity observed in dipeptidyl-peptidase VI, YkfC and other NlpC/P60 domains in general. The first SH3b domain plays an important role in defining substrate specificity by contributing to the formation of the active site, such that only murein peptides with a free N-terminal alanine are allowed. A conserved tyrosine in the SH3b domain of the YkfC subfamily is correlated with the presence of a conserved acidic residue in the NlpC/P60 domain and both residues interact with the free amine group of the alanine. This structural feature allows the definition of a subfamily of NlpC/P60 enzymes with the same N-terminal substrate requirements, including a previously characterized cyanobacterial L-alanine-γ-D-glutamate endopeptidase that contains the two key components (an NlpC/P60 domain attached to an SH3b domain) for assembly of a YkfC-like active site

The structure of BVU2987 from Bacteroides vulgatus reveals a superfamily of bacterial periplasmic proteins with possible inhibitory function.

Proteins that contain the DUF2874 domain constitute a new Pfam family PF11396. Members of this family have predominantly been identified in microbes found in the human gut and oral cavity. The crystal structure of one member of this family, BVU2987 from Bacteroides vulgatus, has been determined, revealing a β-lactamase inhibitor protein-like structure with a tandem repeat of domains. Sequence analysis and structural comparisons reveal that BVU2987 and other DUF2874 proteins are related to β-lactamase inhibitor protein, PepSY and SmpA_OmlA proteins and hence are likely to function as inhibitory proteins

TIC 378898110: A Bright, Short-Period AM CVn Binary in TESS

AM CVn-type systems are ultracompact, helium-accreting binary systems which are evolutionarily linked to the progenitors of thermonuclear supernovae and are expected to be strong Galactic sources of gravitational waves detectable to upcoming space-based interferometers. AM CVn binaries with orbital periods $\lesssim$ 20--23 min exist in a constant high state with a permanently ionised accretion disc. We present the discovery of TIC 378898110, a bright ($G=14.3$ mag), nearby ($309.3 \pm 1.8$ pc), high-state AM CVn binary discovered in TESS two-minute-cadence photometry. At optical wavelengths this is the third-brightest AM CVn binary known. The photometry of the system shows a 23.07172(6) min periodicity, which is likely to be the `superhump' period and implies an orbital period in the range 22--23 min. There is no detectable spectroscopic variability. The system underwent an unusual, year-long brightening event during which the dominant photometric period changed to a shorter period (constrained to $20.5 \pm 2.0$ min), which we suggest may be evidence for the onset of disc-edge eclipses. The estimated mass transfer rate, $\log (\dot{M} / \mathrm{M_\odot} \mathrm{yr}^{-1}) = -6.8 \pm 1.0$, is unusually high and may suggest a high-mass or thermally inflated donor. The binary is detected as an X-ray source, with a flux of $9.2 ^{+4.2}_{-1.8} \times 10^{-13}$ erg cm$^{-2}$ s$^{-1}$ in the 0.3--10 keV range. TIC 378898110 is the shortest-period binary system discovered with TESS, and its large predicted gravitational-wave amplitude makes it a compelling verification binary for future space-based gravitational wave detectors.Comment: 15 pages, 14 figures. Accepted to MNRA

The clustering of galaxies in the SDSS-III Baryon Oscillation Spectroscopic Survey: Baryon Acoustic Oscillations in the Data Release 9 Spectroscopic Galaxy Sample

We present measurements of galaxy clustering from the Baryon Oscillation Spectroscopic Survey (BOSS), which is part of the Sloan Digital Sky Survey III (SDSS-III). These use the Data Release 9 (DR9) CMASS sample, which contains 264,283 massive galaxies covering 3275 square degrees with an effective redshift z=0.57 and redshift range 0.43 < z < 0.7. Assuming a concordance Lambda-CDM cosmological model, this sample covers an effective volume of 2.2 Gpc^3, and represents the largest sample of the Universe ever surveyed at this density, n = 3 x 10^-4 h^-3 Mpc^3. We measure the angle-averaged galaxy correlation function and power spectrum, including density-field reconstruction of the baryon acoustic oscillation (BAO) feature. The acoustic features are detected at a significance of 5\sigma in both the correlation function and power spectrum. Combining with the SDSS-II Luminous Red Galaxy Sample, the detection significance increases to 6.7\sigma. Fitting for the position of the acoustic features measures the distance to z=0.57 relative to the sound horizon DV /rs = 13.67 +/- 0.22 at z=0.57. Assuming a fiducial sound horizon of 153.19 Mpc, which matches cosmic microwave background constraints, this corresponds to a distance DV(z=0.57) = 2094 +/- 34 Mpc. At 1.7 per cent, this is the most precise distance constraint ever obtained from a galaxy survey. We place this result alongside previous BAO measurements in a cosmological distance ladder and find excellent agreement with the current supernova measurements. We use these distance measurements to constrain various cosmological models, finding continuing support for a flat Universe with a cosmological constant.Comment: 33 page

Volume 05

Introduction from Dean Dr. Charles Ross The Tallis House as an Extension of Emily Tallis in McEwan\u27s Atonement by Ian Karamarkovich Graphic Design by Jessica Cox Graphic Design by Kyle Fowlkes Graphic Design by Allison Pawlowski Incorporating Original Research in The Classroom: A Case Study Analyzing the Influence of the Chesapeake Bay on Local Temperatures by Kaitlin Major, Carrie Dunham and Dr. Kelsey Scheitlin Graphic Design by Kathryn Grayson Graphic Design by Ashley Johnson Facing the Music: Environmental Impact Assessment of Building A Concert Hall on North Campus by Jennifer Nehrt, Kelsey Stolzenbach And Dr. Kelsey Scheitlin Art by Kristin McQuarrie Art by Sara Nelson Art by Melisa Michelle Prosocial Behavior as a Result of Prosocial Music by Jessica Sudlow Graphic Design by Perry Bason Graphic Design by Danielle Dmuchawski Graphic Design by Mariah Asbell Graphic Design by Matthew Sakach Identifying Pathogenic Salmonella Serotypes Isolated from Prince Edward County, VA Waterways via Mutiplex PCR Analysis by Timothy Smith, Jr. Art by Annaliese Troxell Art by T. Dane Summerell Development of Salicylidene Anilines for Application in the High School Laboratory by Sarah Ganrude Graphic Design by Malina Rutherford Graphic Design by Hannah Hopper, and Matthew Sakach Because That\u27s What Daddies Do: Effects of Fathering Patterns on Son\u27s Self and Gender Identities by John Berry, Jr. Graphic Design by James Early Graphic Design by Colleen Festa The Influence of Tropical Cyclones on Chesapeake Bay Dead Zones by Chelsea D. Taylor and Dr. Kelsey Scheitlin Graphic Design by Michelle Maddox Graphic Design by Kaitlyn Smith Graphic Design by Sarah Schu Graphic Design by Perry Bason, Cabell Edmunds, Katherine Grayson, Matthew Sakach, and Kayla Torna