836 research outputs found

    CO-PrOx over nano-Au/TiO2: Monolithic catalyst performance and empirical kinetic model fitting

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    In this work, the performance of ceramic monoliths washcoated with Au/TiO2 is studied on CO preferential oxidation (CO-PrOx) reaction in H2-rich environments under a wide range of operating conditions of practical interest. The parameter estimation of a nonlinear kinetic empirical model representing this system is made via genetic algorithms by fitting the model predictions against our laboratory observations. Parameter uncertainty leading to inaccurate predictions is often present when kinetic models with nonlinear rate equations are considered. Here, after the fitting was concluded, a statistical study was conducted to determine the accuracy of the parameter estimation. Activation energies of ca. 30 kJ/mol and 55 kJ/mol were adjusted for CO and H2 oxidations, respectively. The catalyst showed appropriate activity and selectivity values on the CO oxidation on a H2-rich environment. After ca. 45 h on stream the catalyst showed no deactivation. Results show that the model is suitable for reproducing the behavior of the CO-PrOx reactions and it can be used in the design of reactors for hydrogen purification.Peer ReviewedPostprint (author's final draft

    Micromamíferos vallesienses del yacimiento La Salle en las Arcillas Rojas de Teruel

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    El hallazgo de unos restos de micromamiferos en las proximidades del Colegio La Salle de Teruel permite datar la formación de las arcillas rojas conocida con 10s nombres de "Los Monotos", "Formación de Los Tejares" y "Pera1 Formation". La ausencia casi total de fósiles ha hecho que la edad de esa formación fuera largamente discutida. Los fósiles recientemente encontrados permiten atribuirle una edad vallesiense (MN 10 basal). La fauna recogida comprende: Galerix (Parasorex) socialis, Crusafontina excultus, Hispanomys peralensis, Progonomys hispanicus, P. cathalai y Prolagus crusafonti, que se Gade a la de Tetralophodon longirostris, e Hippmion sp

    Sic1 plays a role in timing and oscillatory behaviour of B-type cyclins

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    Budding yeast cell cycle oscillates between states of low and high cyclin-dependent kinase activity, driven by association of Cdk1 with B-type (Clb) cyclins. Various Cdk1-Clb complexes are activated and inactivated in a fixed, temporally regulated sequence, inducing the behaviour known as "waves of cyclins". The transition from low to high Clb activity is triggered by degradation of Sic1, the inhibitor of Cdk1-Clb complexes, at the entry to S phase. The G(1) phase is characterized by low Clb activity and high Sic1 levels. High Clb activity and Sic1 proteolysis are found from the beginning of the S phase until the end of mitosis. The mechanism regulating the appearance on schedule of Cdk1-Clb complexes is currently unknown. Here, we analyse oscillations of Clbs, focusing on the role of their inhibitor Sic1. We compare mathematical networks differing in interactions that Sic1 may establish with Cdk1-Clb complexes. Our analysis suggests that the wave-like cyclins pattern derives from the binding of Sic1 to all Clb pairs rather than from Clb degradation. These predictions are experimentally validated, showing that Sic1 indeed interacts and coexists in time with Clbs. Intriguingly, a sic1Delta strain looses cell cycle-regulated periodicity of Clbs, which is observed in the wild type, whether a SIC1-0P strain delays the formation of Clb waves. Our results highlight an additional role for Sic1 in regulating Cdk1-Clb complexes, coordinating their appearance

    Are T Tauri stars gamma-ray emitters?

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    T Tauri stars are young, low mass, pre-main sequence stars surrounded by an accretion disk. These objects present strong magnetic activity and powerful magnetic reconnection events. Strong shocks are likely associated with fast reconnection in the stellar magnetosphere. Such shocks can accelerate particles up to relativistic energies. We aim at developing a simple model to calculate the radiation produced by non-thermal relativistic particles in the environment of T Tauri stars. We want to establish whether this emission is detectable at high energies with the available or forthcoming gamma-ray telescopes. We assume that particles (protons and electrons) pre-accelerated in reconnection events are accelerated at shocks through Fermi mechanism and we study the high-energy emission produced by the dominant radiative processes. We calculate the spectral energy distribution of T Tauri stars up to high-energies and we compare the integrated flux obtained with that from a specific Fermi source, 1FGL J1625.8-2429c, that we tentatively associate with this kind of young stellar objects (YSOs). We suggest that under reasonable general conditions nearby T Tauri stars might be detected at high energies and be responsible for some unidentified Fermi sources on the Galactic plane.Comment: 7 pages, 10 figure

    Binaries with the eyes of CTA

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    The binary systems that have been detected in gamma rays have proven very useful to study high-energy processes, in particular particle acceleration, emission and radiation reprocessing, and the dynamics of the underlying magnetized flows. Binary systems, either detected or potential gamma-ray emitters, can be grouped in different subclasses depending on the nature of the binary components or the origin of the particle acceleration: the interaction of the winds of either a pulsar and a massive star or two massive stars; accretion onto a compact object and jet formation; and interaction of a relativistic outflow with the external medium. We evaluate the potentialities of an instrument like the Cherenkov telescope array (CTA) to study the non-thermal physics of gamma-ray binaries, which requires the observation of high-energy phenomena at different time and spatial scales. We analyze the capability of CTA, under different configurations, to probe the spectral, temporal and spatial behavior of gamma-ray binaries in the context of the known or expected physics of these sources. CTA will be able to probe with high spectral, temporal and spatial resolution the physical processes behind the gamma-ray emission in binaries, significantly increasing as well the number of known sources. This will allow the derivation of information on the particle acceleration and emission sites qualitatively better than what is currently available.Comment: 23 pages, 13 figures, accepted for publication in Astroparticle Physics, special issue on Physics with the Cherenkov Telescope Arra
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