Investigation of optical and electrical properties of Cobalt-doped Ge-Sb-S thin film

Amorphous Germanium Antimony Sulphide (Ge-Sb-S) doped with Cobalt (Co) have been deposited on glass substrates by thermal evaporation technique on a glass substrate. The films deposited onto glass substrates are characterized by Energy Dispersive X-ray Fluorescence Spectrometer, UV–VIS spectrophotometer, Raman spectroscopy, and Capacitance-Voltage Keithley meter. The optical band gap was calculated from the UV–Visible spectrum and found to be 2.05 eV. Raman spectroscopy measurements reveal that a wide band spectrum from 300 to 410 cm−1 centered at 355 cm−1. The Raman shift peaks at 325 cm−1 and 350 cm−1 are as-signed to the bond stretching mode Sb-S and Ge-S, respectively. In addition, from the obtained Raman spectra it is concluded that the presence of Co doped with Ge-Sb-S. The capacitance and conductance versus voltage measurements were performed at different temperatures. The results show a slight increase in the capacitance with temperature and it reaches a maximum value around 150 °C, and eventually it becomes negative. This behavior is interpreted in terms of the nucleation growth process and the thermally activated conduction process with measured activation energy of 0.79 eV.This work is funded by the University Program for Advanced Research - United Arab Emirates University , (project no. 31S313 ).Scopu

The utilization of sodium lignosulphonate extracted from Egyptian rice straw in leather tanning process

Massive quantities of rice straw are burned annually in Egypt and caused environmental hazards. The present study investigated the utilization of rice straw to produce sodium lignosulphonate (SLS) as a water-soluble derivative of lignin in leather tanning and evaluate its usage as a tanning or re-tanning material as well as its effect on leather quality. The results of testing SLS as a leather tanning agent were unsatisfactory due to its slight effect on shrinkage temperature of leathers, unlike its use as a re-tanning material. Four concentrations of SLS (0%, 5%, 10%, and 20%) were used in re-tanning forty of sheep wet-blues. The results showed that using SLS as a re-tanning agent with concentration till 10% from pelts weight enhances some organoleptic properties, such as fullness and general appearance together with slight improvement in physical properties of leathers. Moreover, the addition of SLS with concentration 20% led to an excessive swelling in the collagen fibers as shown from depicted scanning electron micrographs and decreased trends of physical properties

TOXICOLOGICAL AND PHARMACOLOGICAL ASSESSMENT OF GOLD NANORODS IN NORMAL RATS

Objective: assessment of acute, subchronic and chronic toxicity of pegylated gold nanorods (PEG-gold NRs) in Wistar rats of both sex in three routes of administration {intravenous (IV), intramuscular (IM) and subcutaneous (SC)}.Methods: in the acute toxicity study; PEG-gold NRs were injected once by three different routes, blood and tissue samples were collected after 14 d. In the subchronic and chronic studies; PEG-gold NRs were injected via three different routes, at 0.225, 0.45 and 0.9 mg/kg, once daily for 5 consecutive days, followed by a 23-day recovery period, for three and six months in the subchronic and chronic toxicity studies, respectively. Hematology, urinalysis, biochemical and histopathological examinations were conducted at the end of each study.Results: acute toxicity showed a significant decrease in serum triglycerides and cholesterol levels after single IV, IM and SC injection of PEG-gold NRs, while serum creatinine was significantly increased after IV and IM injection. Subchronic results revealed a significant decrease in serum triglycerides and cholesterol levels. The chronic study showed a significant decrease in serum triglycerides, sodium levels, total leukocytes count and significant increase in serum creatinine after IV injection. IM injection resulted in significant decrease in serum alkaline phosphatase, triglycerides, cholesterol, sodium levels and total leukocytes count. SC injection resulted in significant decrease in serum triglycerides, glucose, red blood cell count with increased creatinine and hematocrit.Conclusion: PEG-gold NRs at the three examined doses is apparently safe since no serious signs of toxicity were detected. IM and SC routes of injection were irritating, so we recommend the IV route.Â

Introduced marine macroflora of Lebanon and its distribution on the Levantine coast

The marine macroflora introduced into Lebanon was studied through an analysis of historical data and field studies carried out since 1991. A total of 29 introduced species have been listed: 3 Chromobionta, 13 Rhodobionta, 12 Chlorobionta and 1 Streptobionta. Among them, Caulerpa taxifolia var. distichophylla, Spatoglossum variabile and Womersleyella setacea are recorded for the first time from Lebanon. Among them, Asparagopsis taxiformis, C. taxifolia var. distichophylla, Cladophora patentiramea, Codium arabicum, Codium parvulum, Galaxaura rugosa, Halophila stipulacea, Hypnea cornuta, Laurencia cf. chondrioides, Lophocladia lallemandii, Stypopodium schimperi, Ulva lactuca and Womersleyella setacea are potentially invasive species, and several of them already occupy extensive stretches of the Lebanese coast. The distribution of species on the Levantine coast, their dynamics and the current status of their populations are discussed.The surveys in 2012, 2013 and 2016 were conducted within the framework of the MedMPAnet Project, implemented by UNEP/MAP-RAC/SPA and funded by RAC/SPA, the European Commission (EC), the Spanish Agency for International Cooperation for Development (AECID), and the French Global Environment Facility (FFEM)

The utilization of sodium lignosulphonate extracted from Egyptian rice straw in leather tanning process

Massive quantities of rice straw are burned annually in Egypt and caused environmental hazards. The present study investigated the utilization of rice straw to produce sodium lignosulphonate (SLS) as a water-soluble derivative of lignin in leather tanning and evaluate its usage as a tanning or re-tanning material as well as its effect on leather quality. The results of testing SLS as a leather tanning agent were unsatisfactory due to its slight effect on shrinkage temperature of leathers, unlike its use as a re-tanning material. Four concentrations of SLS (0%, 5%, 10%, and 20%) were used in re-tanning forty of sheep wet-blues. The results showed that using SLS as a re-tanning agent with concentration till 10% from pelts weight enhances some organoleptic properties, such as fullness and general appearance together with slight improvement in physical properties of leathers. Moreover, the addition of SLS with concentration 20% led to an excessive swelling in the collagen fibers as shown from depicted scanning electron micrographs and decreased trends of physical properties

Physiotherapeutic protocol and ZnO nanoparticles: a combined novel treatment program against bacterial pyomyositis

Myositis tropicans or pyomyositis is a muscle inflammation resulting from a bacterial infection of skeletal muscle (commonly caused by Staphylococcus aureus) that usually leads to hematogenous muscle seeding. The present study was designed to estimate the role of ZnO-NPs and a physiotherapeutic program in the management of induced biceps femoris atrophy in rats through histological, biochemical, and radiological examinations at different time intervals. At the beginning, several bacterial strains were evaluated through a proteolytic enzyme activity assay and the highest activity was recorded with the Staphylococcus aureus strain. ZnO-NPs were synthesized with the arc discharge method with an average size of 19.4 nm. The antibacterial activity of ZnO-NPs was investigated and it was revealed that the prepared ZnO-NPs showed a minimum inhibitory concentration of 8 µg/mL against the tested bacterium. The cytotoxicity of the prepared ZnO-NPs was tested in C2C12 myoblast cells, and it was elaborated that CC50 was 344.16 µg/mL. Biceps femoris pyomyositis was induced with a potent strain (Staphylococcus aureus); then, a physiotherapeutic program combined with the prepared ZnO-NPs treatment protocol was applied and evaluated. The combined program claimed antibacterial properties, preventing muscle atrophy, and resulted in the most comparable value of muscle mass

The Promise of Molecular and Genomic Techniques for Biodiversity Research and DNA Barcoding of the Arabian Peninsula Flora

The Arabian Peninsula is known to have a comprehensive and rich endowment of unique and genetically diverse plant genetic resources. Analysis and conservation of biological diversity is a crucial issue to the whole Arabian Peninsula. The rapid and accurate delimitation and identification of a species is crucial to genetic diversity analysis and the first critical step in the assessment of distribution, population abundance and threats related to a particular target species. During the last two decades, classical strategies of evaluating genetic variability, such as morphology and physiology, have been greatly complemented by phylogenetic, taxonomic, genetic diversity and breeding research molecular studies. At present, initiatives are taking place around the world to generate DNA barcode libraries for vascular plant flora and to make these data available in order to better understand, conserve and utilize biodiversity. The number of herbarium collection-based plant evolutionary genetics and genomics studies being conducted has been increasing worldwide. The herbaria provide a rich resource of already preserved and identified material, and these as well as freshly collected samples from the wild can be used for creating a reference DNA barcode library for the vascular plant flora of a region. This review discusses the main molecular and genomic techniques used in plant identification and biodiversity analysis. Hence, we highlight studies emphasizing various molecular techniques undertaken during the last 10 years to study the plant biodiversity of the Arabian Peninsula. Special emphasis on the role of DNA barcoding as a powerful tool for plant biodiversity analysis is provided, along with the crucial role of herbaria in creating a DNA barcode library

Reflecting on Hybrid Events: Learning from a Year of Hybrid Experiences

The COVID-19 pandemic led to a sudden shift to virtual work and events, with the last two years enabling an appropriated and rather simulated togetherness - the hybrid mode. As we return to in-person events, it is important to reflect on not only what we learned about technologies and social justice, but about the types of events we desire, and how to re-design them accordingly. This SIG aims to reflect on hybrid events and their execution: scaling them across sectors, communities, and industries; considering trade-offs when choosing technologies; studying best practices and defining measures of "success"for hybrid events; and finally, identifying and charting the wider social, ethical, and legal implications of hybrid formats. This SIG will consolidate these topics by inviting participants to collaboratively reflect on previous hybrid experiences and what can be learned from them

SiC polytypes and doping nature effects on electrical properties of ZnO-SiC Schottky diodes

Electrical properties of ZnO/SiC Schottky diodes with two SiC polytypes and N and P doping are investigated. Characterization was performed through I–V and C–V–f measurements. Schottky barrier height (Φb), ideality factor (n), and series resistance (Rs) were extracted from forward I–V characteristics. (Φb), carrier’s concentrations (Nd-Na) and (Rs) frequency dependence were extracted from C–V–f characteristics. The extracted n values suggest that current transport is dominated by interface generation-recombination and/or barrier tunneling mechanisms. When changing SiC polytypes, the rectifying ratio of ZnO/n-4HSiC is found to be twice that of ZnO/n-6HSiC. A change in doping nature gave a leakage current ratio of 40 between ZnO/p-4HSiC and ZnO/n- 4HSiC. These results indicate that ZnO/p-4HSiC diodes have a complex current transport compared to diodes on n-type SiC. From I-V measurements, barrier height values are 0.63eV, 0.65eV and 0.71 eV for heterojunction grown on n-6HSiC, n-4HSiC and p-4HSiC, respectively. C-V measurements gave higher values indicating the importance of interface density of states. Nss values at 1MHz frequency are 4.54×1011 eV-1 cm-2, 3×1012 eV-1 cm-2 and 8.13×1010 eV-1 cm-2 for ZnO/n-6HSiC, ZnO/n-4HSiC and ZnO/p-4HSiC, respectively. Results indicate the importance of SiC polytypes and its doping natur