Dynamics of suspended sediment transport and yield in a large agricultural catchment, southwest France

The dynamics of suspended sediment transport were monitored continuously in a large agricultural catchment in southwest France from January 2007 to March 2009. The objective of this paper is to analyse the temporal variability in suspended sediment transport and yield in that catchment. Analyses were also undertaken to assess the relationships between precipitation, discharge and suspended sediment transport, and to interpret sediment delivery processes using suspended sediment-discharge hysteresis patterns. During the study period, we analysed 17 fl ood events, with high resolution suspended sediment data derived from continuous turbidity and automatic sampling. The results revealed strong seasonal, annual and inter-annual variability in suspended sediment transport. Sediment was strongly transported during spring, when frequent fl ood events of high magnitude and intensity occurred. Annual sediment transport in 2007 yielded 16 614 tonnes, representing 15 t km−2 (85% of annual load transport during fl oods for 16% of annual duration), while the 2008 sediment yield was 77 960 tonnes, representing 70 t km−2 (95% of annual load transport during fl oods for 20% of annual duration). Analysis of the relationships between precipitation, discharge and suspended sediment transport showed that there were signifi cant correlations between total precipitation, peak discharge, total water yield, fl ood intensity and sediment variables during the fl ood events, but no relationship with antecedent conditions. Flood events were classifi ed in relation to suspended sediment concentration (SSC)–discharge hysteretic loops, complemented with temporal dynamics of SSC–discharge ranges during rising and falling fl ow. The hysteretic shapes obtained for all flood events refl ected the distribution of probable sediment sources throughout the catchment. Regarding the sediment transport during all fl ood events, clockwise hysteretic loops represented 68% from river deposited sediments and nearby source areas, anticlockwise 29% from distant source areas, and simultaneity of SSC and discharge 3%

Observations in a sediment-laden flow by use of laser-doppler velocimetry

The laser-Doppler velocimetry technique was adapted for use in sediment-laden flows. The developed instrumentation was used to make one-dimensional, instantaneous measurements of both fluid and sediment grain velocities throughout the water column in such a flow. The velocimetry results were obtained in a steady, uniform flow over a natural sediment bed in the high-transport, flat bed regime. Laser-Doppler velocimetry is particularly attractive for use in sediment-laden flows as no calibration is required and no probe is introduced into the flow field. Measurements of the fluid velocity and the occurrence and velocity of individual sediment grains are possible with the instrumentation developed in this study. The major difficulties encountered are the possible conditional sampling, hence possible biasing, of the fluid velocity data and the failure of the instrumentation to record or resolve individual sediment grains at higher sediment transport rates. The instrumentation employed in this study is still in the developmental stages and suggestions for its improvement are given. Despite the difficulties encountered, the data obtained in this study give some insights into the mechanics of suspension and entrainment of sediment during transport by water. The longitudinal turbulence intensity does not seem to be significantly affected by the presence of suspended sediment; the turbulence intensities observed in the sediment-laden flow of this study do not differ greatly from the values reported by previous investigators for clear fluid flows. The mean and standard deviation of the sediment grain velocity were observed to be less than those for the fluid velocity in the lower portion of the flow, but respectively greater near the water surface. The data demonstrate the shortcoming of the continuum approach to the mechanics of the suspension on sediment. The length (or time) scales of the fluid turbulence are smaller than the length (or time) scale of a set of sediment grains required to define suspended sediment concentration. Near the water surface, where the velocimeter acts as a grain counter, the probability density functions of the sediment grain inter-arrival times, the time between the detection of successive sediment grains, were observed to be negative exponentials. The transport of individual sediment grains might be modeled as a Poisson process. This work is the foundation of an ongoing experimental program of direct measurements of the fine-scale, time-fluctuating characteristics of sediment-laden flows. This study developed and implemented instrumentation capable of making such measurements and established a conceptual framework for the subsequent interpretation of the data obtained. Two-dimensional measurements, with improved instrumentation, will give additional insights into the mechanics of sediment transport

The in vitro influence of the burrowing polychaete Nereis diversicolor on the fate of petroleum hydrocarbons in marine sediments

The in vitro fate of the saturated hydrocarbon fraction (SF) of Arabian Light crude oil has been studied in PVC cores filled with a coastal marine sediment defaunated by sieving. Experiments were conducted in absence or presence of polychaetes Nereis diversicolor. The luminophore tracer technique was used to quantify the mixing of sediment by worms. Presence of crude oil reduced the building of burrows by polychaetes. This work demonstrates the ability of infaunal organisms to stimulate both downard and outward transfers of hydrocarbons from sediment reservoirs. In non-bioturbated sediment hydrocarbons were confined to the sediment surface. Introduction of polychaetes in sediment (1) induced the burying of SF in sediment (2.5 % and 13.5 % of the initial surface input after 15 and 45 days, respectively); (2) enhanced the exportation of SF in the overlying water (plus 59 % and 23.5 % compared to defaunated control sediment after 15 and 45 days, respectively). Buried hydrocarbons were submitted to biodegradation, from 2 cm to 10 cm depth in polychaete burrows, after 45 days

Application and evaluation of sediment fingerprinting techniques in the Manawatu River catchment, New Zealand : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Geography at Massey University, Palmerston North, New Zealand

Suspended sediment is an important component of the fluvial environment, contributing not only to the physical form, but also the chemical and ecological character of river channels and adjacent floodplains. Fluvial sediment flux reflects erosion of the contributing catchment, which when enhanced can lead to a reduction in agricultural productivity, effect morphological changes in the riparian environment and alter aquatic ecosystems by elevating turbidity levels and degrading water quality. It is therefore important to identify catchment-scale erosion processes and understand rates of sediment delivery, transport and deposition into the fluvial system to be able to mitigate such adverse effects. Sediment fingerprinting is a well-used tool for evaluating sediment sources, capable of directly quantifying sediment supply through differentiating sediment sources based on their inherent geochemical signatures and statistical modelling. Confluence-based sediment fingerprinting has achieved broad scale geochemical discrimination within the 5870 km2 Manawatu catchment, which drains terrain comprising soft-rock Tertiary and Quaternary sandstones, mudstones, limestones and more indurated greywacke. Multiple sediment samples were taken upstream and downstream of major river confluences, sieved to 40 and > 35 respectively. The revised mixing model estimated Mudstone terrain to contribute 59.3 % and 61.8 %, with significant contributions estimated from Mountain Range (12.0 % and 11.4 %) and Hill Surface (11.5 % and 11.3 %) respectively, indicating that Tm, Ni, Cu, Ca, P, Mn and Cr have an influence on these sediment source estimations

Analytical model for flux saturation in sediment transport

The transport of sediment by a fluid along the surface is responsible for dune formation, dust entrainment and for a rich diversity of patterns on the bottom of oceans, rivers, and planetary surfaces. Most previous models of sediment transport have focused on the equilibrium (or saturated) particle flux. However, the morphodynamics of sediment landscapes emerging due to surface transport of sediment is controlled by situations out-of-equilibrium. In particular, it is controlled by the saturation length characterizing the distance it takes for the particle flux to reach a new equilibrium after a change in flow conditions. The saturation of mass density of particles entrained into transport and the relaxation of particle and fluid velocities constitute the main relevant relaxation mechanisms leading to saturation of the sediment flux. Here we present a theoretical model for sediment transport which, for the first time, accounts for both these relaxation mechanisms and for the different types of sediment entrainment prevailing under different environmental conditions. Our analytical treatment allows us to derive a closed expression for the saturation length of sediment flux, which is general and can thus be applied under different physical conditions

Bioavailability of pesticides in freshwater sediments

In ecological risk assessment standardized sediment toxicity tests are used to predict the hazard of chemicals for sediment-living organisms. Feeding is a prerequisite in these long-term tests to avoid starvation of test organisms. Therefore, added food particles may act as vectors for the test compound. The importance of food particles as vectors, however, is dependent on several factors, for example, sorption and major uptake routes. In this thesis, laboratory experiments on the importance of pesticide sorption and uptake routes for the bioavailability to the midge Chironomus riparius in sediment toxicity test setups were performed. A feeding selectivity study showed that larvae almost exclusively fed on added food particles, and highly neglected sediment particles. Additionally, experiments on the sorption of the insecticide lindane, showed that food and peat particles (used in artificial sediment) efficiently sorbed lindane (>95% after 48 h). The binding strength of lindane was weak, facilitating particulate uptake. However, the uptake from dissolved lindane was higher than the uptake from particles. From this we concluded that toxicity may be underestimated in spiked-sediment scenarios, where hydrophobic pesticides sorb to the sediment and larvae to a large extent feed on uncontaminated food particles. Conversely, in a spiked-water scenario, the food particles may act as vector, resulting in a facilitated particulate uptake, in addition to the uptake from water. Sediment organic matter affects sorption, and thus bioavailability of pesticides. Pyrethroid toxicity was much higher in artificial sediment than in a natural sediment, indicating the simplicity and shortcomings of using artificial sediments. Interestingly, the sediment quality highly affected bioavailability in spiked-water. For example, C. riparus larvae in sediments with low organic matter content and exposed to spiked-water pyrethroids, showed lower survival, slower development, and increased adult size, than those in sediments with higher organic matter. The pyrethroid deltamethrin, showed an LC50-value (28 d) for C. riparius larvae in artificial sediment of 16 pg/L and 11 µg/kg for water- and sediment exposures, respectively, i.e. toxic effects occurred at concentrations lower than the detection limits for high-tech analytical methods. This thesis contributes to a wider understanding of processes affecting bioavailability in freshwater sediments, and in particular in standardized sediments used in toxicity testing. The understanding of test compound sorption and bioavailability is crucial for sound interpretations of toxicity tests and for the general credibility of such tests

Soil carbon and nitrogen erosion in forested catchments: Implications for erosion-induced terrestrial carbon sequestration

Lateral movement of organic matter (OM) due to erosion is now considered an important flux term in terrestrial carbon (C) and nitrogen (N) budgets, yet most published studies on the role of erosion focus on agricultural or grassland ecosystems. To date, little information is available on the rate and nature of OM eroded from forest ecosystems. We present annual sediment composition and yield, for water years 2005-2011, from eight catchments in the southern part of the Sierra Nevada, California. Sediment was compared to soil at three different landform positions from the source slopes to determine if there is selective transport of organic matter or different mineral particle size classes. Sediment export varied from 0.4 to 177 kg ha-1, while export of C in sediment was between 0.025 and 4.2 kg C ha-1 and export of N in sediment was between 0.001 and 0.04 kg N ha-1. Sediment yield and composition showed high interannual variation. In our study catchments, erosion laterally mobilized OM-rich litter material and topsoil, some of which enters streams owing to the catchment topography where steep slopes border stream channels. Annual lateral sediment export was positively and strongly correlated with stream discharge, while C and N concentrations were both negatively correlated with stream discharge; hence, C: N ratios were not strongly correlated to sediment yield. Our results suggest that stream discharge, more than sediment source, is a primary factor controlling the magnitude of C and N export from upland forest catchments. The OM-rich nature of eroded sediment raises important questions about the fate of the eroded OM. If a large fraction of the soil organic matter (SOM) eroded from forest ecosystems is lost during transport or after deposition, the contribution of forest ecosystems to the erosion-induced C sink is likely to be small (compared to croplands and grasslands)

Formation of siliceous sediments in brandy after diatomite filtration

Brandy is quite a stable spirit but sometimes light sediment appears. This sediment was separated and analysed by IR and SEM-EDX. It was revealed that the sediment is composed mostly of silica and residual organic matter. Silica was present as an amorphous phase and as microparticles. In an attempt to reproduce the formation of the sediment, a diatomite extract was prepared with an ethanol/water mixture (36% vol.) and a calcined diatomite similar to that used in brandy filtration. This extract was added to unfiltered brandy in different amounts. After 1 month, the Si concentration decreased in all samples and sediments with similar compositions and features to those found in the unstable brandy appeared. The amounts of sediment obtained were directly related to the decrease in Si concentration in solution. Consequently, it can be concluded that siliceous sediment in brandy originates from Si released during diatomite filtration